Removal of quinoline insolubles from coal derived fractions

• US 4,405,439 A
• Filed: 03/13/1981
• Issued: 09/20/1983
• Est. Priority Date: 07/25/1979
• Status: Expired due to Fees

• Current Assignee: The Lummus Company
• Original Assignee: The Lummus Company
• Inventors: Simone, Andre A.
• Primary Examiner(s): Gantz, Delbert E.
• Assistant Examiner(s): Maull, Helane E.
• Application Number:
  US06/243,484
• Time in Patent Office: 921 Days
• Field of Search: 208/45
• US Class Current: 208/45
• CPC Class Codes: C10B 55/00 Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material cracking oils C10G
• CPC Class Codes: C10C 1/18 by extraction with selective solvents preparation of hydrocarbon oils from tar oils C10G21/00
• CPC Class Codes: C10G 1/002 in combination with oil conversion- or refining processes

Abstract

Coal tar pitch is contacted with a promoter liquid having a 5 volume percent distillation temperature of at least 250° F. and a 95 volume percent distillation temperature of at least 350° F. and no greater than about 750° F. with the liquid having a characterization factor of at least 9.75 to promote the separation of quinoline insolubles from the pitch. A coat tar pitch fraction essentially free of quinoline insolubles is then subjected to coking to produce a needle coke. The process is also applicable to separation of quinoline insolubles from coal tar derived binder pitch.

Claims

1. A process for reducing the quinoline insoluble content of a coal derived binder pitch, comprising:

contacting a coal tar derived binder pitch feed with a liquid promoter which enhances and promotes the separation of quinoline insolubles, said liquid promoter being a hydrocarbon liquid having a 5-volume percent distillation temperature of at least about 250°

F. and a 95-volume percent distillation temperature of at least about 350°

F. and no greater than about 750°

F., said liquid having a characterization factor of at least 9.75, said liquid promoter being added in an amount to provide a promoter liquid to binder pitch weight ratio of from 0.2;

1 to 0.5;

1 which is sufficient to recover by gravity settling an overflow stream containing a coal derived binder pitch having less than 0.5 weight percent of quinoline insolubles and in excess of 65% of the non-distillable quinoline soluble components present in the binder pitch feed;

recovering by gravity settling as an overflow stream a mixture of promoter liquid and a coal tar derived binder pitch fraction having less than 0.5 weight percent of quinoline insolubles and in excess of 65% of the non-distillable quinoline soluble components present in the binder pitch feed; and

separating said coal tar derived binder pitch fraction from the promoter liquid.

5. The process of claim 1 wherein the contacting is effected at a temperature of from 230°

C. to 315°

C.

2. The process of claim 2 wherein the promoter liquid is at least one member selected from the group consisting of kerosene, kerosene fractions, middle distillates, light gas oils, gas oil fractions, heavy napthas, white oils and white oil fractions from crude oils.

3. The process of claim 2 wherein the said promoter liquid has a characterization factor of less than 12.

4. The process of claim 3 wherein the said promoter liquid has a characterization factor of from 10.5 to 11.0.