Resonant spectrophone system noise elimination

• US 4,412,445 A
• Filed: 08/27/1981
• Issued: 11/01/1983
• Est. Priority Date: 08/27/1981
• Status: Expired due to Fees

• Current Assignee: Optimetrics, Inc (DCS Corporation)
• Original Assignee: Optimetrics, Inc (DCS Corporation)
• Inventors: Spellicy, Robert L.
• Primary Examiner(s): Ciarlante, Anthony V.
• Application Number:
  US06/296,774
• Time in Patent Office: 796 Days
• Field of Search: 73/24, 73/579
• US Class Current: 73/24.02
• CPC Class Codes: G01N 2021/1704 in gases
• CPC Class Codes: G01N 21/1702 with opto-acoustic detection, e.g. for gases or analysing solids
• CPC Class Codes: G01N 2291/015 Attenuation, scattering
• CPC Class Codes: G01N 2291/0421 Longitudinal waves
• CPC Class Codes: G01N 2291/103 one emitter, two or more receivers
• CPC Class Codes: G01N 29/036 by measuring frequency or resonance of acoustic waves
• CPC Class Codes: G01N 29/223 Supports, positioning or alignment in fixed situation mounting transducers per se G10K11/004
• CPC Class Codes: G01N 29/2425 optoacoustic fluid cells therefor
• CPC Class Codes: G01N 29/46 by spectral analysis, e.g. Fourier analysis or wavelet analysis spectral signal processing per se G06F17/14

Abstract

A resonant spectrophone system has a laser arranged to direct a laser beam into a chamber containing gas to be analyzed wherein absorption data relative to the gas constituents is obtained by detecting pressure variations within the chamber. The laser is operated such that the laser beam passing through the chamber generates a resonant wave therein. Pressure variations within the chamber are monitored at locations corresponding to nodal and/or peak points of the resonant wave. The nodal point signals represent background noise and are subtracted from the peak point signals to remove noise components from the peak point signals or out-of-phase nodal signals are subtracted to perform this function and thereby yield signals which more accurately represent the absorption data relative to the gas constituents.

Claims

1. In a spectrophone system wherein radiant energy from a radiant energy source is directed into a chamber containing a fluent sample with respect to which certain absorption data is to be obtained in the presence of background noise by detecting pressure variations within the chamber and generating a signal containing both absorption data and noise components, the radiant energy having a component corresponding to an absorption characteristic of the fluent sample which is being investigated and said chamber having a geometry allowing a resonant wave to be established in the chamber, the improvement for significantly attenuating the noise component relative to the absorption data component which comprises means of creating a resonant wave in the chamber by excitation from the radiant energy source, means for monitoring pressure variations at a location within the chamber corresponding to a peak of the resonant wave to develop a corresponding peak signal containing both true absorption data and noise components, means for monitoring pressure variations at a location within the chamber corresponding to a nodal point of the resonant wave and generating a corresponding nodal signal representing background noise, and means for modifying the peak signal by the nodal signal to remove the noise component from the peak signal and yield a true absorption data signal.

2. The improvement set forth in claim 1 wherein said chamber is cylindrical in shape, the radiant energy is directed longitudinally through the cylindrical chamber, said means for monitoring pressure variations at a location within the chamber corresponding to a peak of the resonant wave created therein comprises microphonic means disposed at a location spaced from the longitudinal ends of the chamber, and said means for monitoring pressure variations at a location within the chamber corresponding to a nodal point of the resonant wave comprises microphonic means disposed at or near at least one of the longitudinal ends of the chamber.

3. The improvement set forth in claim 2 wherein said means for creating a resonant wave in the chamber comprises means for operating a laser source so as to generate a resonant wave at the fundamental resonant frequency of the chamber in the longitudinal direction and wherein said first-mentioned microphonic means is disposed at the longitudinal midpoint of the chamber.

4. The improvement set forth in claim 2 wherein each microphonic means comprises a plurality of individual microphones which are circumferentially arranged about the circumference of the chamber.

5. The improvement set forth in claim 4 wherein the active areas of the individual microphones are substantially flush with the inner wall surface of the chamber so as not to intrude significantly into the otherwise cylindrical interior of the chamber.

6. In a spectrophone system wherein radiant energy from a radiant energy source is directed into a chamber containing a fluent sample with respect to which certain absorption data is to be obtained in the presence of background noise by detecting pressure variations within the chamber and generating a signal containing both absorption data and noise components, the radiant energy having a component corresponding to an absorption characteristic of the fluent sample which is being investigated and said chamber having a geometry allowing a resonant wave to be established in the chamber, an improved method for significantly attenuating the noise component relative to the absorption data component which comprises creating a resonant wave in the chamber, monitoring pressure variations at a location within the chamber corresponding to a peak of the resonant wave to develop a corresponding peak signal containing both true absorption data and noise components, monitoring pressure variations at a location within the chamber corresponding to a nodal point of the resonant wave and generating a corresponding nodal signal representing background noise, and modifying the peak signal by the nodal signal to remove the noise component from the peak signal and yield a true absorption data signal.

7. In a spectrophone system wherein radiant energy from a radiant energy source is directed into a chamber containing a fluent sample with respect to which certain absorption data is to be obtained in the presence of background noise by detecting pressure variations within the chamber and generating signals containing both absorption data and noise components, the radiant energy having a component corresponding to an absorption characteristic of the fluent sample which is being investigated and said chamber having a geometry allowing a resonant wave to be established in the chamber, the improvement for significantly attenuating the noise component relative to the absorption data component so as to yield a true absorption data signal comprising means creating a state of resonance in the chamber by excitation from the radiant energy source wherein a half wave or integral multiple thereof is established in the chamber, means for monitoring pressure variations at a location within the chamber corresponding to a peak point of the resonant half wave or multiple thereof and generating a peak signal containing absorption data and noise components, means for monitoring pressure variations at another location within the chamber corresponding to a point of the half wave or multiple thereof where the resultant signal when processed with the peak signal will yield a true absorption data signal, and means for processing said resultant signal with said peak signal to yield such a true absorption data signal.

8. In a spectrophone system wherein radiant energy from a radiant energy source is directed into a chamber containing a fluent sample with respect to which certain absorption data is to be obtained in the presence of background noise by detecting pressure variations within the chamber and generating signals containing both absorption data and noise components, the radiant energy having a component corresponding to an absorption characteristic of the fluent sample which is being investigated and said chamber having a geometry allowing a resonant wave to be established in the chamber, an improved method for significantly attenuating the noise component relative to the absorption data component so as to yield a true absorption data signal comprising creating a state of resonance in the chamber by excitation from the radiant energy source wherein a half wave or integral multiple thereof is established in the chamber, monitoring pressure variations at a location within the chamber corresponding to a peak point of the resonant half wave or multiple thereof and generating a peak signal containing absorption data and noise components, monitoring pressure variations at another location within the chamber corresponding to a point of the half wave or multiple thereof where the resultant signal when processed with the peak signal will yield a true absorption data signal, and processing said resultant signal with said peak signal to yield such a true absorption data signal.