Non-iridescent glass structures
First Claim
1. A transparent glass product substantially free of iridescent appearance, having a glass substrate bearing a coating which is substantially uniform across the surface area thereof, said coating consisting of(a) a lower coating zone comprising a material formed of at least two components which is characterized by a gradual change from a first composition proximate to said substrate having a relatively large proportion of a second component;
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wherein said lower coating zone is substantially linear with respect to its molecular proporation of said first component, as a function of distance from the glass substrate;
wherein said first component is SiO2, said second component is SnO2, and said upper coating zone is fluorine-doped tin oxide and wherein said material forming said lower coating zone contains tin oxide in a quantity below 40 percent at the interface of said lower coating zone which is closest to said glass substrate.
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Abstract
This disclosure describes transparent glass window structures of the type bearing a first coating of infra-red reflective material which is advantageously less than about 0.85 microns in thickness and wherein the observance of iridescence resulting from such a first coating is markedly reduced by provision of a layer of continuously varying refractive index between the glass and the coating, such that the refractive index increases continuously from the glass to the first coating, thereby preventing the observation of iridescence. The invention also encompasses simple processes for providing such windows. A particular advantage of the invention is its efficacy with clear and lightly tinted glasses wherein the problem of iridescent color has had its greatest commercial impact.
94 Citations
8 Claims
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1. A transparent glass product substantially free of iridescent appearance, having a glass substrate bearing a coating which is substantially uniform across the surface area thereof, said coating consisting of
(a) a lower coating zone comprising a material formed of at least two components which is characterized by a gradual change from a first composition proximate to said substrate having a relatively large proportion of a second component; - and
(b) an upper coating zone having a refractive index substantially the same as that of said second component;
wherein said lower coating zone is substantially linear with respect to its molecular proporation of said first component, as a function of distance from the glass substrate;
wherein said first component is SiO2, said second component is SnO2, and said upper coating zone is fluorine-doped tin oxide and wherein said material forming said lower coating zone contains tin oxide in a quantity below 40 percent at the interface of said lower coating zone which is closest to said glass substrate. - View Dependent Claims (2, 3, 4, 5, 6)
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7. A transparent glass product substantially free of iridescent appearance, having a glass substrate bearing a coating which is substantially uniform across the surface area thereof, said coating consisting of
(a) a lower coating zone comprising a material formed of at least two components which is characterized by a gradual change from a first composition proximate to said substrate having a relatively large proportion of a second component; - and
(b) an upper coating zone having a refractive index substantially the same as that of said second component;
wherein said lower coating zone is substantially linear with respect to its molecular proporation of said first component, as a function of distance from the glass substrate;
wherein said first component is SiO2, said second component is SnO2, and said upper coating zone is fluorine-doped tin oxide and wherein the refractive index of the glass substrate is with ±
0.04 refractive index units of the refractive index of the coating material of said lower zone. - View Dependent Claims (8)
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Specification