Clark cell with hydrophylic polymer layer

• US 4,492,622 A
• Filed: 09/02/1983
• Issued: 01/08/1985
• Est. Priority Date: 09/02/1983
• Status: Expired due to Fees

• Current Assignee: Drager Nederland BV
• Original Assignee: Honeywell Incorporated (Honeywell International Inc.)
• Inventors: Kuypers, Martinus H.
• Primary Examiner(s): Kaplan, G. L.
• Application Number:
  US06/529,183
• Time in Patent Office: 494 Days
• Field of Search: 204/415, 204/1 P, 204/403, 204/416, 128/635, 29/592 R
• US Class Current: 204/403.07
• CPC Class Codes: G01N 27/404 Cells with anode, cathode and cell electrolyte on the same side of a permeable membrane which separates them from the sample fluid , e.g. Clark-type oxygen sensors

Abstract

An electro-chemical cell for determining a particular property or component of a fluid includes a cathode electrode, an anode electrode spaced from the cathode, an electrolyte filling a space containing the cathode and anode electrodes, a selectively permeable membrane separating the electrodes and the electrolyte from the fluid to be analyzed and a layer of a hydrophylic polymer provided between a membrane and the electrodes and covering at least the cathode wherein the membrane has at least one hole in it for allowing electrolytic component of the fluid to enter the hydrophylic polymer layer and that the distance between the holes and the membrane and the cathode is relatively large as compared to the width of the cathode.

Claims

1. Electro-chemical cell for determining a particular property or component of a fluid comprising a cathode electrode (1) and spaced therefrom an anode electrode (3), whereat a space engaging said electrodes is adapted for being filled with an electrolyte,

and comprising a selectively permeable membrane (5) separating said electrodes and said space from the fluid characterized in that a thin layer (7) of hydrophylic polymer is provided between said membrane (5) and said electrodes (3, 4) covering at least the cathode (4);

that the membrane (5) has at least one hole (6) in it for allowing an electrolytic component of the fluid to enter said hydrophylic polymer layer (7);

and that the distance (d) between the hole(s) (6) and the cathode (1) is larger than the width (w) of the cathode (1).

2. A cell according to claim 1, characterized in that both the cathode (1) and the anode (3) are covered with a layer (7) of hydrophylic polymer.

3. A cell according to claim 1, characterized in that the hydrophylic polymer layer (7) comprises a hydrogel taken from the group consisting of polyvinyl alcohol, polyvinyl pyrrolidone, polyacrylamide, hydroxyethylmetacrylate and derivatives of these compounds.

4. A cell according to claim 1, characterized in that the membrane (5) is made of hydrophobic polymer.

5. Cell according to claim 1, characterized in that it is an oxygen sensor.

6. A cell according to claim 1 characterized by an ion-selective membrane between said electrodes and said layer of hydrophylic polymer to form an ion-selective sensor.

7. A cell according to claim 1, characterized in that the hydrophylic polymer layer (7) is less than 4μ

thick.

8. A cell according to claim 1, characterized by an insulating substrate (2) supporting the electrodes (1,3) made of a material taken from the group consisting of silicon, glass and ceramics.

9. A cell as set forth in claim 1 wherein the distance between said holes and said cathode is at least five times larger than the width of said cathode.