Aluminum cell having aluminum wettable cathode surface

• US 4,544,469 A
• Filed: 07/22/1982
• Issued: 10/01/1985
• Est. Priority Date: 07/22/1982
• Status: Expired due to Term

• Current Assignee: Comalco Aluminium Limited (Rio Tinto Limited)
• Original Assignee: Commonwealth Aluminum Corp (Commonwealth Industries, Inc.)
• Inventors: Townsend, Douglas W., Cooke, Arthur V., Nagle, Dennis C., Boxall, Larry G., Buchta, William M.
• Primary Examiner(s): Valentine, Donald R.
• Application Number:
  US06/400,762
• Time in Patent Office: 1,167 Days
• Field of Search: 204/255, 204/67, 204/294, 204/296, 204/243 R, 204/244-247, 204/290 R
• US Class Current: 204/247.3
• CPC Class Codes: C04B 35/5611 based on titanium carbides
• CPC Class Codes: C04B 35/5622 based on zirconium or hafnium carbides
• CPC Class Codes: C04B 35/58071 based on titanium borides
• CPC Class Codes: C04B 35/58078 based on zirconium or hafnium borides
• CPC Class Codes: C04B 35/6303 Inorganic additives
• CPC Class Codes: C04B 35/632 Organic additives
• CPC Class Codes: C04B 35/634 Polymers C04B35/636 takes precedence
• CPC Class Codes: C04B 35/63452 Polyepoxides
• CPC Class Codes: C04B 35/6346 Polyesters
• CPC Class Codes: C04B 35/63476 Phenol-formaldehyde condensation polymers
• CPC Class Codes: C04B 41/507 Borides
• CPC Class Codes: C04B 41/87 Ceramics
• CPC Class Codes: C25C 3/08 Cell construction, e.g. bottoms, walls, cathodes

Abstract

Aluminum cells may be produced having cathode surfaces which are wetted by aluminum, said surfaces comprising Refractory Hard Materials in a non-graphitized carbon matrix. Such cells may utilize inclined or drained cathodes as well as non-consumable anodes.

Claims

1. In a cell for the electrolytic reduction of alumina to aluminum, said cell comprising a receptacle, at least one anodic surface, a cathodic surface, means for providing electrical power, means for the introduction of bath materials and alumina, and means for the removal of product aluminum, the improvement wherein said cathodic surface comprises a Refractory Hard Material in a carbonaceous matrix comprising carbonaceous filler having a particle size less than about 100 mesh and carbonaceous additive having a particle size greater than about 100 mesh, bonded by non-graphitized amorphous carbon, said matrix having a rate of ablation essentially equal to the rate of wear and dissolution of said Refractory Hard Material in the operating environment of said cell.

2. In a cell as set forth in claim 1, the improvement wherein said Refractory Hard Material comprises from about 10 to about 90 percent by weight of said cathode surface coating layer.

3. In a cell as set forth in claim 2, the improvement wherein said Refractory Hard Material is selected from the group consisting of titanium diboride, titanium carbide, zirconium diboride, zirconium carbide, and alloys thereof.

4. In a cell as set forth in claim 2, the improvement wherein said Refractory Hard Material is titanium diboride.

5. In a cell for the electrolytic reduction of alumina to aluminum, said cell having a cathode comprising a cathode substrate and an aluminum wettable surface layer bonded thereto, the improvement wherein said surface layer comprises a coating composition consisting of Refractory Hard Material, thermosetting resinous binder, mix liquid, carbonaceous filler and carbonaceous additive, which coating after curing and carbonization comprises a Refractory Hard Material in a non-graphitized carbon matrix and exhibits an expansion between 800°

C. and 1000°

C. of less than 0.2 percent, said matrix having a rate of ablation essentially equal to the combined rate of wear and dissolution of said Refractory Hard Material in the operating environment of said cell.

6. In a cell as set forth in claim 5, the improvement wherein said Refractory Hard Material is selected from the group consisting of titanium diboride, titanium carbide, zirconium diboride, zirconium carbide, and alloys thereof.

7. In a cell as set forth in claim 5, the improvement wherein said Refractory Hard Material comprises titanium diboride.

8. In a cell as set forth in claim 7, the improvement wherein said surface layer comprises a cured and carbonized coating composition, said composition comprising from about 10 to about 90 percent titanium diboride, from about 1 to about 40 percent resinous binder, from about 2 to about 40 mix liquid, from about 1 to about 60 percent carbonaceous filler, up to about 70 percent carbonaceous additive, and effective amounts of curing agent and gas release agent.

9. In a cell as set forth in claim 8, the improvement wherein said carbonaceous additive includes carbon fiber.

10. In a cell as set forth in claim 7, the improvement wherein said coating further exhibits an overall contraction of less than 1 percent when cycled from 20°

C. to 1000°

C. and back to 20°

C.

11. In a cell as set forth in claim 7, the improvement wherein the coating composition comprises from about 20 to about 70 percent by weight titanium diboride, from about 0.5 to about 15 percent resinous binder, from about 2 to about 40 percent mix liquid, from about 1 to about 60 percent carbonaceous filler, up to about 70 percent carbonaceous aggregate having a particle size between -4 and +100 mesh, from about 0.5 to about 1.0 percent carbon fiber, and effective amounts of curing agent and gas release agent.

12. In a cell as set forth in claim 7, the improvement wherein said coating composition comprises from about 35 to about 60 percent titanium diboride, from about 2.5 to about 8 percent resinous binder, from about 4 to about 20 percent mix liquid, from about 10 to about 40 percent carbonaceous filler, from about 5 to about 15 percent carbonaceous aggregate having a particle size between -4 and +100 mesh, and from about 0.05 to about 0.5 percent carbon fiber.

13. In a cell as set forth in claim 5, the improvement wherein said Refractory Hard Material is selected from the group consisting of single crystal, bicrystal, and open clusters of single crystal Refractory Hard Material.

14. An aluminum reduction cell having cathode and anode surfaces inclined from the horizontal, wherein said cathode surface comprises Refractory Hard Material in a non-graphitized carbon matrix exhibiting a rate of ablation such that said carbon matrix and said Refractory Hard Material are removed at essentially the same rate, said cathode surface consisting of an aluminum wettable cured and carbonized coating composition comprising titanium diboride refractory hard material, a thermosetting resinous binder system exhibiting a char yield greater than 50 percent, carbonaceous filler, and carbonaceous additive, said coating composition exhibiting a percentage of expansion between 800°

C. and 1000°

C. less than 0.2 different from the percentage of expansion exhibited by the cathode substrate to which said coating is applied.

15. A cell as set forth in claim 14, wherein said coating composition further exhibits an overall contraction of less than 1 percent when cycled from 20°

C. to 1000°

C. and back to 20°

C.

16. A cell as set forth in claim 14, wherein said coating composition comprises from about 20 to about 70 percent by weight titanium diboride, from about 0.5 to about 15 percent resinous binder, from about 2 to about 40 percent mix liquid, from about 1 to about 60 percent carbonaceous filler, up to about 70 percent carbonaceous aggregate having a particle size between -4 and +100 mesh, from about 0.5 to about 1.0 percent carbon fiber, and effective amounts of curing agent and gas release agent.

17. A cell as set forth in claim 14, wherein said coating composition comprises from about 35 to about 60 percent titanium diboride, from about 2.5 to about 8 percent resinous binder, from about 4 to about 20 percent mix liquid, from about 10 to about 40 carbonaceous filler, from about 5 to about 15 percent carbonaceous aggregate having a particle size between -4 and +100 mesh, and from about 0.05 to about 0.5 percent carbon fiber.

18. A cell as set forth in claim 14, wherein said Refractory Hard Material is selected from the group consisting of single crystal, bicrystal, and open clusters of single crystal Refractory Hard Material.