Method for hardening form substances of building materials containing binding agents and autoclave for the execution of the method

• US 4,560,346 A
• Filed: 07/20/1984
• Issued: 12/24/1985
• Est. Priority Date: 07/22/1983
• Status: Expired due to Term

• Current Assignee: Sicowa Verfahrenstechnik fur Baustoffe GmbH & Co. KG.
• Original Assignee: Sicowa Verfahrenstechnik fur Baustoffe GmbH & Co. KG.
• Inventors: Schulz, Eckhard
• Primary Examiner(s): Camby, John J.
• Application Number:
  US06/632,766
• Time in Patent Office: 522 Days
• Field of Search: 34/22, 34/26, 34/30, 34/51, 34/15, 34/179, 432/12, 432/18, 432/24, 432/26, 432/148, 432/209
• US Class Current: 432/24
• CPC Class Codes: C04B 28/02 containing hydraulic cements other than calcium sulfates
• CPC Class Codes: C04B 40/024 Steam hardening, e.g. in an autoclave

Abstract

The method relates to the hardening of form substances made of building materials and containing binding agents in a pressure chamber of an autoclave to which is conveyed a gaseous heating medium, the temperature of which is increased during a heating-up phase up to a given upper limit value. During a holding phase, the temperature is maintained at least until a given equalization temperature is reached on the inside of the form substances. Subsequently, during a cooling-down phase, the temperature is reduced by reducing the pressure to the expulsion temperature. Porous light building materials in a conventional process would absorb a high amount of water through the condensation of water resulting from steam having been conveyed into the autoclave for the purpose of hardening. However, in order to produce form substances of a low water content economically, according to the present invention, on the one hand, steam is replaced by gas which is maintained below the evaporation temperature of water through sufficient increase in pressure, and, on the other hand, as a replacement or complement, heat is conveyed to the inside of the pressure chamber before the cooling-down phase and an increase in the temperature of the steam beyond the given limit value is prevented by blowing off steam, thereby attaining an integrated drying process.

Claims

1. A method for hardening form substance of building material containing binding agents inside a pressure chamber of an autoclave, comprising conveying a gaseous heating medium to said autoclave, increasing the temperature of the building materials in said autoclave to a given upper limit during a heating-up phase, increasing the pressure within said autoclave above atmospheric pressure and at a pressure which precludes evaporation of water during said heating phase such as to prevent exposure of the form substances in the autoclave to evaporated wet vapor during the heating-up phase, maintaining the temperature in the autoclave at least until a given equalization temperature is reached on the inside of the form substances during a holding phase, maintaining the pressure within said autoclave above atmospheric pressure and at a pressure which precludes evaporation of the water during said holding phase such as to prevent exposure of the form substance in the autoclave to evaporated vapor during the holding phase, said steps of increasing the temperature and the pressure and maintaining the temperature and the pressure resulting in producing in said autoclave a temperature/pressure condition which precludes evaporation of water within the autoclave during said heating-up phase and said holding phase, subsequently reducing the temperature during a cooling-down phase to an expulsion temperature, and reducing the pressure in said autoclave during said cooling-down phase to atmospheric pressure, whereby the form substances are precluded from being exposed to evaported water vapor during the hardening thereof in the autoclave.

2. A method according to claim 1, comprising essentially conveying air to the autoclave as a heating medium.

3. A method according to claim 1, comprising placing the heating medium under increased pressure before the heating.

4. A method according to claim 1, comprising retaining the heating medium enclosed in the autoclave, and heating the heating medium inside the autoclave by means of a heating apparatus.

5. A method according to claim 1, comprising conducting the heating medium in a closed circulation path outside of the autoclave to a heat exchanger.

6. A method according to claim 1, comprising heating the heating medium by means of a heating apparatus connected with a supply line.

7. A method according to claim 1 further comprising heating said heating medium during said holding phase to compensate for heat losses.

8. A method according to claim 7 further comprising blowing off water vapor containing heating medium from said autoclave during said holding phase, and thereby precluding an increase in temperature of said heating medium above said upper limit.

9. A method according to claim 8, comprising regulating the blowing off of water vapor containing heating medium so that pressure on the inside of the autoclave is maintained at a constant value which corresponds to the saturation pressure of the given upper limit value of the temperature of the steam.

10. A method according to claim 8, wherein after reaching the equalization temperature on the inside of the form substances by blowing off water vapor containing heating medium out of the inside of the pressure chamber, the pressure of the steam is reduced during an intermediate phase which is subsequent to the holding phase, and which precedes the cooling-down phase, step-by-step or continuously at the most to a value which corresponds to the saturation pressure at a steam temperature of the value of the equalization temperature.

11. A method according to claim 8, comprising conveying heat to the inner chamber of the pressure chamber exclusively by means of heating.

12. A method according to claim 11, comprising supplying a small amount of water for the initial formation of steam by heating at or before the beginning of the heating-up phase.

13. A method according to claim 1, wherein said form substances are selected from the group consisting of porous silicate and concrete.

14. A method according to claim 1, wherein said from substances to be hardened have a water content of over 5% to 20% by volume and after hardening have a water content of from 3 to 5% by volume.

15. A method according to claim 1, wherein during said heating-up phase, said autoclave is heated to a temperature of at least 156°

C., and during said holding phase said autoclave is maintained at a temperature of at least 156°

C.

16. A method according to claim 1, wherein during said heating-up phase, said autoclave is pressurized to a pressure of at least 5.8 bars.

17. A method according to claim 1, wherein during said heating-up phase, said autoclave is pressurized to a pressure of from 5.8 to 16.5 bars.

18. A method according to claim 1, wherein during said heating-up phase, said autoclave is heated to a temperature of from 250°

to 300°

C. and during said holding phase, the temperature of the autoclave is maintained at a temperature from 156°

C. to 203°

C.

19. A method according to claim 1, wherein said heating-up phase occurs over a period of about 4 to 5 hours.

20. A method according to claim 1, wherein said holding phase is maintained for about 90 minutes.

21. A method according to claim 1, wherein said cooling-down phase occurs over a period of about 90 minutes.

22. Apparatus for hardening form substances of building materials containing binding agents, comprising an autoclave having a pressure chamber for receiving said form substances, conduit means for conveying a gaseous medium to said pressure chamber, heating/pressurizing means for heating said autoclave to a given upper limit and to pressurize said autoclave to a pressure above atmospheric pressure to a pressure which precludes evaporation of water during a heating-up phase such as to prevent exposure of the form substances in the autoclave to evaporated wet vapor during said heating-up phase, said heating/pressurizing means being operable to maintain the temperature and pressure within said autoclave at a temperature/pressure condition which precludes evaporation of water in the autoclave during a holding phase, said heating/pressurizing means maintaining said temperature/pressure condition until an equalization temperature is reached on the inside of said form substances, and reducing means for reducing the temperature and pressure within the autoclave to ambient conditions during a cooling-down phase, whereby the form substances are precluded from being exposed to evaporated water during the hardening thereof in the autoclave.

23. An autoclave according to claim 22, wherein said pressure chamber has at least partial double casing chambers, said double casing chambers defining a space therebetween for the flow-through of a heat carrying medium.

24. An autoclave according to claim 22, wherein said heating/pressurizing means comprises a tube coil heating apparatus.

25. An autoclave according to claim 24, wherein said autoclave comprises a single cased pressure chamber, said tube coil heating apparatus being positioned directly in said single cased pressure chamber, and insulating means insulating said pressure chamber against the environment.

26. An autoclave accoridng to claim 22 further comprising a blowing-off conduit connected to said pressure chamber and a regulation valve in said conduit for controlling the blow-off of steam from said pressure chamber.

27. An autoclave according to claim 22 comprising a closure means for closing off said pressure chamber after loading with said form substances, said conduit means comprising a gas supply line connecting said pressure chamber with a gas pressure pump.

28. An autoclave according to claim 27, wherein said heating/pressurizing means comprises a heating device to which said gas supply line is connected.

29. An autoclave according to claim 28, wherein said heating device is connected with said gas supply line which leads out of said pressure chamber and which forms a closed circulation path with said gas supply line.

30. An autoclave according to claim 29, further comprising a circulation pump in said closed circulation path.