Alcohol-soluble polyamides and printing inks

• US 4,571,267 A
• Filed: 11/10/1983
• Issued: 02/18/1986
• Est. Priority Date: 11/26/1982
• Status: Expired due to Fees

• Current Assignee: Witco GmbH
• Original Assignee: Schering Ag (Merck & Co., Inc.)
• Inventors: Krase, Horst, Drawert, Manfred
• Primary Examiner(s): Trousof, Natalie
• Assistant Examiner(s): NOT, DEFINED
• Application Number:
  US06/550,225
• Time in Patent Office: 831 Days
• Field of Search: 260/404.5 R, 260/404.5 PA, 106/20, 106/22, 106/23, 106/25, 106/26, 106/27, 106/28, 106/30, 106/29, 106/31
• US Class Current: 106/31.43
• CPC Class Codes: C08G 69/34 using polymerised unsaturated fatty acids
• CPC Class Codes: C09D 11/102 containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
• CPC Class Codes: Y10S 260/38 Ink

Abstract

Polyamides which are alcohol-soluble at room temperature, are useful in formulating printing inks, and which comprise dimerized fatty acids, at least one aliphatic unbranched monocarboxylic acid and at least one aliphatic branched monocarboxylic acid as the acid component, and ethylenediamine and hexamethylenediamine as the amine component, and printing inks formulated therefrom.

Claims

1. A polyamide, alcohol soluble at room temperature, prepared by the condensation of an acid component comprising

(A) dimerized fatty acids having from 16 to 44 carbon atoms with

(B1) at least one aliphatic linear monocarboxylic acid having 3 to 6 carbon atoms, and

(B2) at least one aliphatic branched monocarboxylic acid having 4 to 9 carbon atoms, the equivalence ratio between components (A) and (B) ranging from 0.73:

0.27 to 0.6;

0.4, and each of the components (B1) and (B2) being present in an amount of at least 0.1 equivalent, based on unit total acid equivalent, and an amine component comprising

(C) ethylenediamine and

(D) hexamethylenediamine, the equivalence ratio between component (C) and (D) ranging from 0.7;

0.3 to 0.4;

0.6.

2. A polyamide as in claim 1 comprising a single aliphatic linear monocarboxylic acid as component (B1) and a single aliphatic branched monocarboxylic acid as component (B2).

3. A polyamide as in claim 1 wherein the equivalence ratio between components (A) and (B) is 0.7:

0.3.

4. A polyamide as in claim 1 wherein said monocarboxylic acid (B1) is at least one member selected from the group consisting of propionic acid, n-valeric acid, and n-caproic acid.

5. A polyamide as in claim 1 wherein said monocarboxylic acid (B1) is butyric acid.

6. A polyamide as in claim 1 wherein said monocarboxylic acid (B2) is at least one member selected from the group consisting of 3-methylbutyric acid and 2-ethylhexanoic acid.

7. A polyamide as in claim 1 wherein each of said components (B1) and (B2) is present in an amount of at least 0.1 equivalent, based on unit total acid equivalent.

8. A printing ink comprising an alcohol solvent, a polyamide as in claim 1 as the binder, and a pigment or soluble dye.

9. A printing ink as in claim 8, adaptable to gravure or flexographic printing, wherein said solvent is an aliphatic alcohol having from 2 to 4 carbon atoms and said printing ink has a solids content of about 20 to 50 percent, corresponding to a runout time of 15 to 30 seconds (DIN 4 mm cup).

10. A printing ink as in claim 9 wherein said solvent is ethanol and the solids content of said printing ink is from 25 to 35 percent, corresponding to a runout time of 18 to 25 seconds.