Method of producing a thermoplastics material

• US 4,590,027 A
• Filed: 05/17/1984
• Issued: 05/20/1986
• Est. Priority Date: 06/10/1976
• Status: Expired due to Fees

• Current Assignee: British Technology Group Ltd.
• Original Assignee: National Research Development Corporation
• Inventors: Murphy, David J., Phillips, Leslie N.
• Primary Examiner(s): Czaja, Donald
• Assistant Examiner(s): Fischbach, V.
• Application Number:
  US06/611,380
• Time in Patent Office: 733 Days
• Field of Search: 264/258, 264/134, 264/135, 264/136, 264/137, 428/236, 428/239, 428/245, 428/246, 428/247, 428/261, 428/268, 428/301, 428/302, 428/288, 428/289, 428/290, 428/286, 428/287, 428/911, 428/902
• US Class Current: 264/135
• CPC Class Codes: B29B 15/105 of reinforcement of definite length with a matrix in solid form, e.g. powder, fibre or sheet form calendering B29C70/506
• CPC Class Codes: B29C 70/086 and with one or more layers of pure plastics material, e.g. foam layers applying a non-preformed coating, e.g. a gel-coat, B29C37/0025; with foam blocks B29C70/86
• CPC Class Codes: B29C 70/28 Shaping operations therefor
• CPC Class Codes: B29C 70/465 and impregnating by melting a solid material, e.g. sheets, powders of fibres
• CPC Class Codes: B32B 19/045 of synthetic resin
• CPC Class Codes: B32B 19/08 comprising asbestos
• CPC Class Codes: B32B 2262/0269 Aromatic polyamide fibres
• CPC Class Codes: B32B 2262/101 Glass fibres
• CPC Class Codes: B32B 2262/106 Carbon fibres, e.g. graphite fibres
• CPC Class Codes: B32B 23/10 next to a fibrous or filamentary layer
• CPC Class Codes: B32B 2315/12 Asbestos
• CPC Class Codes: B32B 2323/04 Polyethylene
• CPC Class Codes: B32B 2323/10 Polypropylene
• CPC Class Codes: B32B 2325/00 Polymers of vinyl-aromatic compounds, e.g. polystyrene
• CPC Class Codes: B32B 2327/06 PVC, i.e. polyvinylchloride
• CPC Class Codes: B32B 2367/00 Polyesters, e.g. PET, i.e. polyethylene terephthalate
• CPC Class Codes: B32B 2369/00 Polycarbonates
• CPC Class Codes: B32B 2377/00 Polyamides
• CPC Class Codes: B32B 2379/08 Polyimides
• CPC Class Codes: B32B 27/12 next to a fibrous or filamentary layer
• CPC Class Codes: B32B 27/281 : comprising polyimides
• CPC Class Codes: B32B 27/286 : comprising polysulphones; polysulfides
• CPC Class Codes: B32B 27/302 : comprising aromatic vinyl (co)polymers, e.g. styrenic (co)polymers
• CPC Class Codes: B32B 27/304 : comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
• CPC Class Codes: B32B 27/306 : comprising vinyl acetate or vinyl alcohol (co)polymers
• CPC Class Codes: B32B 27/32 : comprising polyolefins comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30
• CPC Class Codes: B32B 27/34 : comprising polyamides
• CPC Class Codes: B32B 27/36 : comprising polyesters
• CPC Class Codes: B32B 27/365 : comprising polycarbonates

Abstract

A method is described of producing a laminated structural material which includes the steps of stacking alternately layers of thermoplastics sheet material and one or more layers of material to be laminated, the material having been impregnated with a second thermoplastics material prior to stacking, placing the stack in a pre-heated mould or press and subjecting the stack to heat and pressure for a time sufficient to cause the thermoplastics material to flow and bond together the layers of structural material to be laminated and allowing the mould or press to cool sufficiently to avoid distortion of the moulded part before removal from the mould or press.

Claims

1. A method of producing a substantially void-free and substantially stiff laminated structural material which material includes thermoplastics matrix material and a fibrous reinforcement material in the form of a woven fabric, a non-woven fabric, a felt or a paper, said method consisting essentially of the successive steps of:

(a) impregnating said fibrous material throughout with a first thermoplastics material which is soluble in a solvent and is applied in a solvent solution, the solvent of said solution being allowed to evaporate after impregnation, the amount of the first thermoplastics material with which the said fibrous material is impregnated being at least sufficient for thorough impregnation of the fibers, but insufficient for the matrix of the desired structural material;

(b) stacking at least two layers of thus impregnated fibrous material, in alternate sequence with interleaving layers of a second thermoplastic material in sheet form, the amount of the second thermoplastics material included in the stack being such that the total amount of thermoplastics matrix material present in the stack is sufficient to enable the desired substantially stiff laminated structural material to be produced;

(c) subjecting the thus formed stack to heat and pressure in a preheated mould or press for sufficient time, in excess of 10 minutes, to cause the first and second thermoplastics material to soften and flow and to cause said thermoplastics materials to bond together and to bond to the fibrous material in a substantially void-free manner and to cause the stack to conform to a desired intermediate stock form or final product form, whereby a substantially stiff laminated structural material is produced having a flexural strength of at least 250 MPA; and

thereafter

(d) allowing the mould or press to cool sufficiently to avoid distortion of the laminated structural material thus produced before removal of said laminated structural material from the mould or press.

2. A method as claimed in claim 1, wherein the duration of the heat and pressure step (c) is between 10 and 30 minutes.

3. A method as claimed in claim 2, wherein the duration of the heat and pressure step (c) is about 30 minutes.

4. A method as claimed in claim 1, wherein the first and second thermoplastics material are the same or different and are each selected from the group consisting of cellulose acetate, cellulose acetatebutyrate, ethyl cellulose, polystyrene, vinyl chloride vinyl acetate copolymer, polypropylene, polyethylene, polycarbonate, polyamides, polyesters, polysulphone, polyethersulphone and polyimides.

5. A method as claimed in claim 1, wherein the ordered fibrous material is in the form of a woven or non-woven fabric.

6. A method as claimed in claim 5, wherein the fibers of the ordered fibrous material are selected from the group consisting of carbon fibers, glass fibers, asbestos fibers and aramid fibers.

7. A method as claimed in claim 5, wherein the ordered fibrous material is a woven fabric in which the warp and weft threads are multifilament.

8. A method as claimed in claim 7, wherein the woven fabric is selected from the group consisting of carbon fiber cloth, carbon fiber tape, hybrid glass fiber/carbon fiber cloth and hybrid glass fiber/carbon fiber tape.

9. A method as claimed in claim 1, wherein the thermoplastics material of the outer layers is selected from the group consisting of polycarbonate, polysulphone and polyethersulphone.

10. A method as claimed in claim 1, wherein the fibrous material is impregnated with a weak solvent solution of the first thermoplastics material said solution having a concentration of between about 7.5 percent and about 20 percent by weight of thermoplastics material.

11. A method as claimed in claim 10, wherein said solvent solution has a concentration of about 7.5 percent by weight of thermoplastics material.

12. A method as claimed in claim 1, wherein during the heat and pressure step (c) the stack is heated and pressed in a mould of such a shape as to produce from said stack an article which is suitable for use on an aircraft.

13. A method as claimed in claim 12 wherein during the heat and pressure step the stack is heated and pressed in a mould having a shape of an aircraft radome.

14. A method as claimed in claim 12, wherein said article comprises as its outer surface thermoplastics material selected from the group consisting of polycarbonate, polysulphone and polyethersulphone.

15. A method as claimed in claim 1, wherein the amount of thermoplastics material with which the ordered fibrous material is impregnated is about 20% by weight.

16. A method as claimed in claim 1, wherein the amount of thermoplastics material with which the ordered fibrous material is impregnated is about 16% by weight.

17. A method as claimed in claim 1 wherein the stack incorporates outer covering layers of a thermoplastic material.