Polyether polyols modified with amino alcohol-epoxy resin adducts

• US 4,609,685 A
• Filed: 05/06/1985
• Issued: 09/02/1986
• Est. Priority Date: 05/06/1985
• Status: Expired due to Term

• Current Assignee: The Dow Chemical Company (Dow, Inc.)
• Original Assignee: Texaco Incorporated (Chevron Corp.)
• Inventors: Cuscurida, Michael, Waddill, Harold G.
• Primary Examiner(s): WELSH JR, MAURICE
• Application Number:
  US06/731,196
• Time in Patent Office: 484 Days
• Field of Search: 521/167, 525/504, 528/88, 528/111, 528/361, 528/407
• US Class Current: 521/167
• CPC Class Codes: C08G 18/5033 containing carbocyclic groups C08G18/5024 takes precedence
• CPC Class Codes: C08G 18/5069 prepared from polyepoxy compounds
• CPC Class Codes: C08G 59/64 Amino alcohols
• CPC Class Codes: C08G 65/26 from cyclic ethers and other compounds

Abstract

Polyether polyols are modified by reaction with alkylene oxides and amino alcohol-epoxy resin adducts. The adducts are the reaction product of an epoxy resin and amino alcohol of the formula: ##STR1## wherein: x ranges from 1 to 4,

y ranges from 1 to 40, and

R is an alkyl of from 1 to 4 carbon atoms.

These polyether polyols are used to prepare flexible polyurethane foams.

Claims

1. A modified amino polyol for use in preparing flexible polyurethane foams, the modified polyol produced by reacting:

(1) an initiator having an active hydrogen functionality of from 3 to 4,

(2) one or more alkylene oxides,

(3) an amino alcohol adduct in such a manner that the adduct is added internally along the length of the polyol chain, the amino alcohol adduct being the reaction product of;

(a) an epoxy resin and

(b) an amino alcohol of the formula;

##STR4## wherein;

x ranges from about 1 to 4,

y ranges from about 1 to 40, and

R is an alkyl radical of from 1 to 4 carbon atoms.

2. The modified amino polyol of claim 1 wherein in the amino alcohol adduct the mole ratio of amino alcohol/epoxy resin ranges from about 4/1 to 1/1.

3. The modified amino polyol of claim 1 wherein the amino alcohol adduct comprises about 0.5 wt % to 10.0 wt % of the modified amino polyol.

4. The modified amino polyol of claim 1 wherein the sum of the molecular weights of the initiator, alkylene oxides and amino alcohol adduct is about 2000 to 7000.

5. The modified amino polyol of claim 1 wherein the alkylene oxides are a mixture of ethylene oxide and propylene oxide.

6. The modified amino polyol of claim 1 wherein in the amino alcohol, x is about 1.

7. The modified amino polyol of claim 1 wherein in the amino alcohol, y is about 1 to 10.

8. The modified amino polyol of claim 1 wherein R is methyl.

9. The modified amino polyol of claim 1 wherein in the amino alcohol, x is about 1, y is about 1 to 10 and R is methyl.

10. The modified amino polyol of claim 1 wherein the initiator is glycerol.

11. A method for producing a flexible polyurethane foam which comprises:

A. making a modified polyol by reacting;

(1) an initiator having an active hydrogen functionality of from 3 to 4,

(2) one or more alkylene oxides,

(3) an amino alcohol adduct in such a manner that the adduct is added internally along the length of the polyol chain, the amino alcohol adduct being the reaction product of;

(a) an epoxy resin and

(b) an amino alcohol of the formula;

##STR5## wherein;

x ranges from about 1 to 4,

y ranges from about 1 to 40, and

R is an alkyl radical of from 1 to 4 carbon atoms; and

B. reacting said modified polyol with an organic polyisocyanate and one or more suitable foam catalysts in the presence of a blowing agent.

12. The method of claim 11 wherein in the amino alcohol adduct the mole ratio of amino alcohol/epoxy resin ranges from about 4/1 to 1/1.

13. The method of claim 11 wherein the amino alcohol adduct comprises about 0.5 wt % to 10.0 wt % of the modified amino polyol.

14. The method of claim 11 wherein the sum of the molecular weights of the initiator and the alkylene oxides is about 2000 to 7000.

15. The method of claim 11 wherein the alkylene oxides are a mixture of ethylene oxide and propylene oxide.

16. The method of claim 11 wherein in the amino alcohol, x is about 1.

17. The method of claim 11 wherein in the amino alcohol, y is about 1 to 10.

18. The method of claim 11 wherein in the amino alcohol, R is methyl.

19. The method of claim 11 wherein in the amino alcohol, x is about 1, y is about 1 to 10 and R is methyl.

20. The method of claim 11 wherein the initiator is glycerol.