Corrosion-resistant silver mirror

• US 4,645,714 A
• Filed: 12/24/1984
• Issued: 02/24/1987
• Est. Priority Date: 12/24/1984
• Status: Expired due to Term

• Current Assignee: 3M Company
• Original Assignee: 3M Company
• Inventors: Tiers, George V. D., Roche, John L.
• Primary Examiner(s): Buffalow, Edith
• Application Number:
  US06/685,545
• Time in Patent Office: 792 Days
• Field of Search: 428/480, 428/458, 428/40, 428/461, 428/463, 350/642, 350/641
• US Class Current: 428/458
• CPC Class Codes: F24S 2025/601 by bonding, e.g. by using adhesives
• CPC Class Codes: F24S 23/82 characterised by the material or the construction of the reflector
• CPC Class Codes: F24S 40/40 Preventing corrosion; Protecting against dirt or contamination
• CPC Class Codes: G02B 5/0808 having a single reflecting layer G02B5/0883, G02B5/0891 take precedence
• CPC Class Codes: H01J 61/35 provided with coatings on the walls thereof; Selection of materials for the coatings using coloured coatings H01J61/40; using luminescent coatings H01J61/42
• CPC Class Codes: Y02E 10/40 Solar thermal energy, e.g. solar towers
• CPC Class Codes: Y10T 428/31681 Next to polyester, polyamide or polyimide [e.g., alkyd, glue, or nylon, etc.]
• CPC Class Codes: Y10T 428/31692 Next to addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31699 Ester, halide or nitrile of addition polymer
• CPC Class Codes: Y10T 428/31786 Of polyester [e.g., alkyd, etc.]

Abstract

Durable, specularly reflective mirrors for solar reflectors or fluorescent lamp fixtures are formed by vapor-depositing silver on a polyester film and protectively covering it with a coating of transparent acrylate polymer containing a silver corrosion inhibitor such as glycol dimercaptoacetate. In a preferred embodiment a pressure-sensitive mounting adhesive is applied to the opposite face of the polyester film. Degradation of the polyester, and consequent bubbling of the adhesive, is reduced or eliminated by incorporating UV absorber in acrylate polymer that is applied as a second protective coating.

Claims

1. A highly reflective and corrosion-resistant mirror comprising in combination:

a. a polymeric substrate,

b. a thin, specularly reflective layer of silver overlying said substrate and bonded thereto,

c. at the surface of the silver layer that is distal to said substrate, sufficient bound mercaptide-type sulfur to bond with a substantial fraction of the available silver atoms, and

d. a thin protective layer of film-forming polymer overlying said distal surface and firmly adherently bonded thereto,

at least one of said substrate and said film-forming polymer being transparent to visible light so that the specular surface of the silver can be seen therethrough.

2. The mirror of claim 1 wherein the substrate is a polymeric film.

3. The mirror of claim 2 wherein the film consists essentially of biaxially oriented polyethylene terephthalate.

4. The mirror of claim 3 wherein the film consists of a first lamina containing conventional slip agents and a second lamina containing no slip agent, the silver being bonded to the second lamina.

5. The mirror of claim 1 wherein the film-forming polymer is transparent to visible light.

6. The mirror of claim 5 wherein a stable mercaptan is dissolved in the layer immediately contacting the distal surface of the silver.

7. The mirror of claim 6 wherein the surface of the mercaptide-bonded silver shows a spreading drop area of at least about 6 mm².

8. The mirror of claim 7 wherein the surface of the mercaptide-bonded silver shows a spreading drop area of at least about 8 mm².

9. The mirror of claim 6 wherein the layer immediately contacting the distal surface of the silver is the film-forming polymer.

10. The mirror of claim 9 wherein the film-forming polymer contains glycol dimercaptoacetate.

11. The mirror of claim 10 wherein the film-forming polymer is an acrylate interpolymer.

12. The mirror of claim 11 wherein the film-forming polymer is a polymer formed from acrylate monomers selected from lower acrylates and lower methacrylates.

13. The mirror of claim 1 wherein the film-forming polymer is formed from monomers consisting essentially of (a) about 50 to 70% methyl methacrylate, ethyl methacrylate, or both and (b) correspondingly about 50 to 30% monomers selected from the class consisting of butyl acrylate, butyl methacrylate, and 2-ethyl hexyl acrylate.

14. The mirror of claim 10 wherein the substrate is biaxially oriented polyethylene terephthalate having an adhesive on the surface opposite that on which the silver is applied.

15. The mirror of claim 14 wherein the adhesive is a normally tacky and pressure-sensitive adhesive.

16. The mirror of claim 15 wherein a second film-forming polymer containing UV absorber is applied over the first film-forming polymer.

17. The mirror of claim 16 wherein the UV absorber comprises approximately equal parts of 2-[2'"'"'-hydroxy-3'"'"',5'"'"'-di-(alpha,alpha-dimethylbenzyl)phenyl]-benzotriazole and 2-(2'"'"'-hydroxy-3'"'"',5'"'"'-di-tertiaryamylphenyl)-benzotriazole.

18. The mirror of claim 17 wherein a premask film of polypropylene protectively covers the outer acrylate polymer layer to afford protection prior to installation.