Catalytic metal of reduced particle size

• US 4,652,311 A
• Filed: 01/16/1985
• Issued: 03/24/1987
• Est. Priority Date: 05/07/1984
• Status: Expired due to Fees

• Current Assignee: Shipley Company, Inc.
• Original Assignee: Shipley Company, Inc.
• Inventors: Dutkewych, Oleh B., Gulla, Michael, Bladon, John J.
• Primary Examiner(s): Hayes, Lorenzo B.
• Application Number:
  US06/691,880
• Time in Patent Office: 797 Days
• Field of Search: 106/1.05, 106/1.11, 252/313.1, 524/434, 524/439
• US Class Current: 106/1.11
• CPC Class Codes: C23C 18/28 Sensitising or activating
• CPC Class Codes: C23C 18/30 Activating or accelerating or sensitising with palladium or other noble metal

Abstract

A catalytic adsorbate suspended in an aqueous solution comprising reduced catalytic metal on an organic suspending agent where the reduced catalytic metal has a maximum dimension not exceeding 500 angstroms and the organic suspending agent is one capable of complexing with ions of the catalytic metal. The catalytic adsorbate is useful for the electroless metal deposition of substrates that are non-catalytic to electroless metal deposition.

Claims

1. A functional catalytic adsorbate for electroless metal deposition consisting essentially of a reduced platinum family metal complexed with a water soluble or dispersible polymer where the reduced platinum family metal is characterized by an average maximum dimension not exceeding 500 Angstroms and the polymer is one that complexes with the ions of the catalytic metal prior to reduction and formation of the catalytic adsorbate, said catalytic adsorbate being suspended in an aqueous medium consisting essentially of water.

2. The adsorbate of claim 1 where the reduced platinum family metal is palladium.

3. The adsorbate of claim 2 suspended in water.

4. The adsorbate of claim 3 where the aqueous medium has a pH not exceeding 5.5.

5. The adsorbate of claim 3 where the aqueous medium has a pH of at least 8.0.

6. The adsorbate of claim 4 where pH of the aqueous medium varies between 1.5 and 3.6.

7. The adsorbate of claim 2 where the average maximum dimension of the reduced palladium does not exceed 300 Angstroms.

8. The adsorbate of claim 2 where the concentration of reduced palladium varies between 10 and 2,000 parts per million parts of solution.

9. The adsorbate of claim 8 where the concentration varies between 300 and 1,500 parts per million parts of solution.

10. The adsorbate of claim 2 where the solution contains a hydroxy substituted compound in an amount varying between 10 and 250 ml per liter and sufficient to stabilize the suspension of the catalytic adsorbate against aggregation and precipitation.

11. The adsorbate of claim 10 where the hydroxy substituted compound is selected from the group of alcohols and glycols.

12. The adsorbate of claim 11 where the hydroxy substituted compound is propylene glycol methyl ether.

13. The adsorbate of claim 2 where the polymer is selected from the group of polyacrylamides, polyethylene glycol, polyvinyl alcohol, polyvinyl pyrrolidone and surfactants with polymer adducts.

14. The adsorbate of claim 13 where the polymer is polyvinyl pyrrolidone.

15. The adsorbate of claim 2 where the concentration of the polymer in solution varies between 10 and 100,000 parts per million parts of solution.

16. The adsorbate of claim 15 where the concentration varies between 20 and 10,000 parts per million parts of solution.

17. A functional catalytic adsorbate for electroless metal deposition consisting essentially of reduced palladium complexed with polyvinyl pyrrolidone where the reduced palladium is characterized by an average maximum dimension not exceeding 500 Angstroms, the suspension has a pH not exceeding 5.5 and the concentration of palladium varies between 10 and 2,000 parts per million parts of solution, said catalytic adsorbate being suspended in an aqueous medium consisting essentially of water.

18. The suspension of claim 17 where the average maximum dimension of the reduced palladium does not exceed 300 Angstroms.

19. The suspension of claim 18 where the palladium content varies between 10 and 200 parts per million parts of solution.

20. The suspension of claim 17 as a dried redispersible product.

21. The suspension of claim 17 containing a hydroxy substituted compound in an amount varying between 10 and 250 mls per liter of solution and sufficient to stabilize the adsorbate against aggregation, precipitation and oxidative dissolution.

22. The suspension of claim 21 where the hydroxy compound is propylene glycol methyl ether in an amount varying between 25 and 100 mls per liter of solution.

23. The suspension of claim 17 where the concentration of the polyvinyl pyrrolidone varies between 10 and 100,000 parts per million parts of solution.

24. The suspension of claim 23 where the concentration varies between 20 and 10,000 parts per million parts of solution.