Water reducible coating compositions

• US 4,661,540 A
• Filed: 12/04/1985
• Issued: 04/28/1987
• Est. Priority Date: 12/06/1984
• Status: Expired due to Fees

• Current Assignee: Berger Jenson & Nicholson Limited
• Original Assignee: Berger Jenson & Nicholson Limited
• Inventors: Le, Minh V., Hawkett, Brian S., Elliott, William T.
• Primary Examiner(s): Michl, Paul R.
• Application Number:
  US06/805,383
• Time in Patent Office: 510 Days
• Field of Search: 523/408, 523/409, 523/412
• US Class Current: 523/409
• CPC Class Codes: C08G 59/64 Amino alcohols
• CPC Class Codes: C08J 2363/00 Characterised by the use of epoxy resins; Derivatives of epoxy resins
• CPC Class Codes: C08J 3/03 in aqueous media
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 2666/14 Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
• CPC Class Codes: C08L 63/00 Compositions of epoxy resins; Compositions of derivatives of epoxy resins
• CPC Class Codes: C09D 125/08 Copolymers of styrene C09D129/08, C09D135/06, C09D155/02 take precedence
• CPC Class Codes: C09D 133/08 Homopolymers or copolymers of acrylic acid esters
• CPC Class Codes: C09D 163/00 Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins

Abstract

An aqueous dispersion of a tertiary amine terminated polyether and a carboxylic acid functional polymer. The tertiary amine terminated polyether is the product of the reaction of the epoxy group of an epoxy resin with the hydroxy group of a hydroxy functional tertiary amine and the carboxylic acid functional polymer is present in an amount sufficient to render the combination water dispersible.

A process for producing the aqueous dispersion is also described, together with coating compositions based on the dispersion. These coating compositions are particularly useful in the lining of metal containers for food and beverages.

Claims

1. An aqueous dispersion of a tertiary amine terminated polyether and a carboxylic acid functional polymer wherein the tertiary amine terminated polyether is the product of the reaction of the epoxy group of an epoxy resin with the hydroxy group of a hydroxy functional tertiary amine and the carboxylic acid functional polymer is present in an amount sufficient to render the combination water dispersible.

2. An aqueous dispersion according to claim 1 in which the amine terminated polyether is formed from a Bisphenol A type epoxy resin.

3. An aqueous dispersion according to claim 2 in which the molecular weight of the Bisphenol A type epoxy resin is increased by further reaction with Bisphenol A.

4. An aqueous dispersion according to claim 1 in which the epoxy equivalent weight of the epoxy resin is greater than 5000.

5. An aqueous dispersion according to claim 1 in which the hydroxy functional tertiary amine is a mono hydroxy tertiary amine.

6. An aqueous dispersion according to claim 1 in which the hydroxy functional tertiary amine is N,N-dimethylethanolamine (DMEA).

7. An aqueous dispersion according to claim 1 in which the hydroxy functional tertiary amine is triethanolamine.

8. An aqueous dispersion according to claim 1 in which the carboxylic acid functional polymer is a polymer containing acrylic and/or methacrylic acid and/or crotonic acid.

9. An aqueous dispersion according to claim 1 in which the carboxylic acid functional polymer is a copolymer containing hydrophobic monomers such as styrene, butyl acrylate, ethyl acrylate, methyl methacrylate and butyl methacrylate.

10. An aqueous dispersion according to claim 1 in which the carboxylic acid functional polymer is a copolymer containing hydrophilic monomers such as hydroxy ethyl acrylate and hydroxy propyl methacrylate.

11. An aqueous dispersion according to claim 1 in which the carboxylic acid functional polymer contains acrylamide.

12. An aqueous dispersion according to claim 1 in which the carboxylic acid functional polymer is polymerised separately from the amine terminated polyether, and later mixed with said polyether.

13. An aqueous dispersion according to claim 1 in which the carboxylic acid functional polymer is polymerised in the presence of the amine terminated polyether.

17. A coating composition comprising the aqueous dispersion of claim 1.

14. A process for producing an aqueous dispersion of a tertiary amine terminated polyether and a carboxylic acid functional polymer which comprises:

(a) reacting the epoxide groups of an epoxy resin with a hydroxy functional tertiary amine to form a tertiary amine terminated polyether, and

(b) dispersing the tertiary amine terminated polyether in water with the aid of a carboxylic acid functional polymer in an amount sufficient to render the combination dispersible.

15. A process as claimed in claim 14, wherein the tertiary amine terminated polyether is formed under substantially anhydrous reaction conditions.

16. A process as claimed in claim 14, wherein the carboxylic acid functional polymer is dissolved in water prior to being used to disperse the tertiary amine terminated polyether.

18. A coating composition comprising a stable dispersion in water of:

(i) a tertiary amine terminated polyether which is in ionic association with

(ii) a polymer derived, at least in part, from carboxylic acid functional monomers, and

(iii) a crosslinking agent.

19. A coating composition as claimed in claim 18, formulated for use in the lining of metal containers for food and beverages.