Production of bipolar membranes

• US 4,670,125 A
• Filed: 02/26/1986
• Issued: 06/02/1987
• Est. Priority Date: 03/08/1985
• Status: Expired due to Fees

• Current Assignee: BASF AG (BASF SE)
• Original Assignee: BASF AG (BASF SE)
• Inventors: Mueller, Hans, Puetter, Hermann
• Primary Examiner(s): NOT, DEFINED
• Assistant Examiner(s): Chapman, Terryence
• Application Number:
  US06/833,911
• Time in Patent Office: 461 Days
• Field of Search: 156/308.6, 156/334, 204/182.4, 204/296
• US Class Current: 204/631
• CPC Class Codes: C08J 2339/02 Homopolymers or copolymers of vinylamine
• CPC Class Codes: C08J 5/2275 Heterogeneous membranes

Abstract

A bipolar membrane is produced by fastening an anion exchange membrane to a cation exchange membrane with the aid of an ion-permeable adhesive, by a process in which an aqueous solution of a polyvinylamine is used as the adhesive, and the bipolar membrane, which consists of two ion exchange membranes and the film-like adhesive, is subjected to electrodialysis.

Claims

1. In a process for the production of a bipolar membrane by bonding an anion exchange membrane to a cation exchange membrane with the aid of an ion-permeable adhesive in a layer adjoining the two membranes, the improvement which comprises:

forming the adhesive bonding layer by applying to at least one membrane surface a 0.5-70% strength by weight aqeuous soltuion of a polyvinylamine having a molecular weight of from 10⁴ to 10⁶ ; and

subjecting the resulting prepared bipolar membrane to an electrodialysis treatment sufficient to strengthen thea dhesive bonding of the two membranes.

2. A process as claimed in claim 1, wherein the adhesive used in an aqueous polyvinylamine solution obtained by hydrolyzing a 1-50% strength aqeuous polyvinylformamide solution with hydrochloric acid at from 60°

to 100°

C.

3. A process as claimed in claim 1, wherein in the electrodialysis, the preprepared bipolar membrane is arranged so that the anion exchange membrane faces the anode, and the cation exchange membrane faces the cathode.

4. A process as claimed in claim 1, wherein electrodialysis is carried out at a current density of from 0.1 to 10 A/dm² and at from 10°

to 80°

C.

5. A process as claimed in claim 1 wherein the adhesvie bonding layer is formed in a thickness of from 0.001 to 0.5 mm.

6. The bipolar membrane obtained in the process of claim 1.

7. The bipolar membrane obtained in the process of claim 5.

8. A bipolar membrane comprising an anion exchange membrane and a cation exchange membrane joined by an adhesive layer consisting essentially of a polyvinylamine having a molecular weight of from 10⁴ to 10⁶.

9. A bipolar membrane as claimed in claim 8 wherein said adhesvie layer has a thickness of about 0.001 to 0.05 mm.