Iridium oxide coated electrodes for neural stimulation

• US 4,717,581 A
• Filed: 11/13/1986
• Issued: 01/05/1988
• Est. Priority Date: 02/06/1986
• Status: Expired due to Fees

• Current Assignee: EIC Laboratories, Inc.
• Original Assignee: EIC Laboratories, Inc.
• Inventors: Robblee, Lois S.
• Primary Examiner(s): Silverberg, Sam
• Application Number:
  US06/929,778
• Time in Patent Office: 418 Days
• Field of Search: 427/2, 427/126.5
• US Class Current: 427/2.12
• CPC Class Codes: A61N 1/05 for implantation or insertion into the body, e.g. heart electrode A61N1/06 takes precedence

Abstract

A metallic electrode made of platinum, platinum iridium alloy, stainless steel, stainless steel alloys, titanium, titanium alloys, tantalum or tantalum alloys is coated with iridium oxide. Ir(III) trichloride is heated in 5.5M HCl until 75-80% of the solution is evaporated. Isopropyl or ethyl alcohol is added to the evaporated solution to restore the solution to its original volume. This restored acid/alcohol solution is aged for 1-2 weeks. The metallic electrode is soaked in the aged acid/alcohol solution for 16 hours, dried for one hour at room temperature and annealed in air at 320° C. for 80-90 minutes.

Claims

1. The method of making a neural stimulator having an iridium oxide coated electrode which method includes the steps of,

forming an acid/alcohol solution containing at least one dissolved iridium complex by heating Ir(III) trichloride in hydrochloric acid until more than half the solution is evaporated to convert the Ir(III) trichloride to a hexachloroiridate ion, [IrCl₆ ]^2-,

adding alcohol to the solution following evaportion to restore the solution to its original volume,

aging the restored acid/alcohol solution to slowly convert the hexachloroiridate ion to a chloroiridate-alcohol complex of Ir(IV),

soaking said metallic electrode in the aged acid/alcohol solution for a prolonged period of time so that the electrode metallic surface becomes completely covered with the iridium complexes in the aged acid/alcohol,

removing the covered metallic electrode from the aged acid/alcohol solution and drying the latter in air at room temperature,

and annealing the dried coated electrode at a temperature sufficiently high for sufficient time to convert the chloroiridate-alcohol complexes deposited on the electrode surface to an oxide of iridium.

2. The method of claim 1 wherein said hydrochloric acid is 5.5M HCl (ca. 4% wt/vol) and the acid/alcohol solution is heated until 75-80% of the solution is evaporated.

3. A process in accordance with claim 1 wherein said alcohol is an alcohol from the group consisting of isopropyl alcohol and ethyl alcohol and said period of aging is of the order of 1-2 weeks.

4. A method in accordance with claim 1 wherein said prolonged period of time is of the order of 16 hours, the annealing temperature is of the order of 320°

C. and the time of annealing is of the order of 80-90 minutes.

5. A method in accordance with claim 1 and further including the steps of adding successive layers by soaking the oxide-coated electrode in the aged acid/alcohol solution for of the order of 16-24 hours followed by annealing at of the order of 320°

C. for of the order of 3-6 hours after each soaking.

6. A method in accordance with claim 1 and further including the step of etching the metallic electrode before immersion in said aged acid/alcohol solution to enhance the adhesion of the formed iridium oxide film.