Method for protecting carbonyl iron powder and compositions therefrom

• US 4,731,191 A
• Filed: 12/31/1985
• Issued: 03/15/1988
• Est. Priority Date: 12/31/1985
• Status: Expired due to Fees

• Current Assignee: Dow, Inc.
• Original Assignee: Dow, Inc.
• Inventors: Swihart, Terence J.
• Primary Examiner(s): LAWRENCE, EVAN
• Application Number:
  US06/815,417
• Time in Patent Office: 805 Days
• Field of Search: 428/405, 427/216, 427/127, 427/221, 427/128, 252/62.54, 252/62.55
• US Class Current: 252/62.54
• CPC Class Codes: H01F 1/26 by macromolecular organic substances

Abstract

Carbonyl iron powder (CIP) can be protected from extensive atmospheric oxidation by mixing and heating it with a silicon compound having one or more reactive groups. The resulting CIP is more readily accepted by a silicone binder when preparing mixtures thereof.

Claims

1. A method for preparing a composition containing carbonyl iron powder and a silicone binder, said method comprising heating and mixing the carbonyl iron powder with an amount of a silicon compound which contains one or more reactive silicon-bonded radicals, said amount being sufficient to reduce the atmospheric oxidation of the carbonyl iron powder, and then mixing the resulting carbonyl iron powder with the binder.

2. A method according to claim 1 wherein the silicon compound is a liquid copolymeric organopolysiloxane containing SiO_4/2 siloxane units, SiH sites and SiOH sites which has been prepared by (A) forming an acidic homogeneous mixture comprising (a) an organic solvent solution of a resinous copolymeric siloxane containing silicon-bonded hydroxyl radicals and consisting essentially of R₃ SiO_1/2 siloxane units and SiO_4/2 siloxane units wherein the ratio of the former to the latter, on a molar basis, has a value of from 0.6/1 to 0.9/1 and each R denotes, independently, a monovalent hydrocarbon radical;

and (b) a liquid organohydrogenpolysiloxane wherein each organic radical is, independently, a monovalent hydrocarbon radical, there being an average of at least one silicon-bonded hydrogen atom per molecule of said organohydrogenpolysiloxane; and

, (B) heating the homogenous mixture to remove substantially all of the organic solvent therefrom.

3. A method according to claim 2 wherein the silicon compound is a liquid copolymeric organopolysiloxane containing SiO_4/2 siloxane units, SiH sites and SiOH sites which has been prepared by (A) forming an acidic homogeneous mixture comprising (a) an organic solvent solution of from 40 to 60 parts by weight of a resinous copolymeric siloxane containing silicon-bonded hydroxyl radicals and consisting essentially of (CH.sub. 3)₃ SiO_1/2 siloxane units and SiO_4/2 siloxane units wherein the ratio of the former to the latter, on a molar basis, has a value of from 0.6/1 to 0.9/1, and (b) 40 to 60 parts by weight of a methylhydrogenpolysiloxane having the formula Me₃ SiO(Me₂ SiO)_x SiMe₃ wherein Me denotes the methyl radical and x has a value of from 35 to 70;

and (B) heating the homogenous mixture to remove substantially all of the organic solvent therefrom.

4. A method according to claim 1 wherein the silicon compound is an alkoxysilane.

5. A method according to claim 4 wherein the alkoxysilane is methyltrimethoxysilane.

6. A method according to claim 1 wherein the carbonyl iron powder is heated to a temperature of 150°

C. in the presence of the silicon compound.

7. A method according to claim 1 wherein the binder is a silicone binder comprising a liquid copolymeric organopolysiloxane containing SiO_4/2 siloxane units, SiH sites and SiOH sites which has been prepared by (A) forming an acidic homogeneous mixture comprising (a) an organic solvent solution of a resinous copolymeric siloxane containing silicon-bonded hydroxyl radicals and consisting essentially of R₃ SiO_1/2 siloxane units and SiO_4/2 siloxane units wherein the ratio of the former to the latter, on a molar basis, has a value of from 0.6/1 to 0.9/1 and each R denotes, independently, a monovalent hydrocarbon radical;

and (b) a liquid organohydrogenpolysiloxane wherein each organic radical is, independently, a monovalent hydrocarbon radical, there being an average of at least one silicon-bonded hydrogen atom per molecule of said organohydrogenpolysiloxane; and

, (B) heating the homogenous mixture to remove substantially all of the organic solvent therefrom.

8. A method according to claim 7 wherein the binder is a silicone binder comprising a liquid copolymeric organopolysiloxane containing SiO_4/2 siloxane units, SiH sites and SiOH sites which has been prepared by (A) forming an acidic homogeneous mixture comprising (a) an organic solvent solution of from 40 to 60 parts by weight of a resinous copolymeric siloxane containing silicon-bonded hydroxyl radicals and consisting essentially of (CH₃)₃ SiO_1/2 siloxane units and SiO_4/2 siloxane units wherein the ratio of the former to the latter, on a molar basis, has a value of from 0.6/1 to 0.9/1, and (b) 40 to 60 parts by weight of a methylhydrogenpolysiloxane having the formula Me₃ SiO(Me₂ SiO)_x SiMe₃ wherein Me denotes the methyl radical and x has a value of from 35 to 70;

and (B) heating the homogenous mixture to remove substantially all of the organic solvent therefrom.

9. The composition produced by the method of claim 1.