Cell for electric double layer capacitors and process for manufacturing such a cell

• US 4,731,705 A
• Filed: 06/24/1986
• Issued: 03/15/1988
• Est. Priority Date: 06/25/1985
• Status: Expired due to Fees

• Current Assignee: Compagnie Europeenne de Composants Electroniques L.C.C.
• Original Assignee: Compagnie Europeenne de Composants Electroniques L.C.C.
• Inventors: Colomban, Philippe, Pham, Thi M., Velasco, Gonzal, Adet, Philippe
• Primary Examiner(s): Griffin, Donald A.
• Application Number:
  US06/877,867
• Time in Patent Office: 630 Days
• Field of Search: 252/62.2, 361/433, 29/25.42, 29/570
• US Class Current: 361/502
• CPC Class Codes: H01G 11/52 Separators
• CPC Class Codes: H01G 11/56 Solid electrolytes, e.g. gels; Additives therein
• CPC Class Codes: Y02E 60/13 Energy storage using capacitors
• CPC Class Codes: Y10T 29/43 Electric condenser making

Abstract

A method for forming a cell and a cell for an electric double layer capacitor includes a membrane formed from a solid protronic conducting electrolyte separating two electrodes. Each electrode is a composite electrode formed by a mixture of at least one electronic conductor and a solid electrolyte. Preferably, the solid electrolyte of the composite electrodes and the membrane is chosen from a group consisting of uranyl phosphate H₃ O UO₂ PO₄ 3H₂), zirconium phosphate Zr(HPO₄)₂ nH₂ O, or derivatives of these compounds.

Claims

1. A cell for an electric double layer capacitor, comprising:

a membrane formed of a solid protonic conducting electrolyte separating two electrodes; and

two electrodes each comprising a composite electrode including a mixture of predetermined proportions of at least one electronic conductor and at least one solid electrolyte, said solid electrolyte of said composite electrode comprising a protonic conductor chosen from a group consisting of uranyl phosphate H₃ OUO₂ PO₄.3H₂ O, zirconium phosphate Zr(HOP₄)₂ nH₂ O, derivatives of these compounds and protonic conductors with high protonic conductivity having a low electronic conductivity.

2. The cell as claimed in claim 1, wherein said solid protonic conducting electrolyle of said membrane comprises a protonic conductor chosen from a group consisting of uranyl phosphate H₃ OUO₂ PO₄.3H₂ O, zirconium phosphate Zr (HPO₄)₂ nH₂ O, derivatives of these compounds and protonic conductors with high protonic conductivity having a low electronic conductivity.

3. The cell as claimed in claim 2, wherein the H₃ O⁺ ions are substituted wholly or partially by a cation.

4. The cell as claimed in claim 3, wherein the cation is chosen from the group consiting of Na⁺, Li⁺, K⁺, Ca²⁺, Ag⁺.

5. The cell as claimed in claim 1, wherein the electronic conductor comprises one of activated carbon black, acetylene black or a mixture of different carbon blacks and/or acetylene black.

6. The cell as claimed in any one of claims 1 to 5, wherein said solid protonic conducting electrolyte forming the membrane is of a nature different from the solid electrolyte comprising the mixture in the electrodes.

7. The cell as claimed in any one of claims 1 to 6, wherein said membrane, comprises an organic protonated species exchanging membrane.

8. The cell as claimed in any one of claims 1 to 7, wherein said membrane comprises a porous structure imbibed with an electrolyte.

9. The cell as claimed in any one of claims 1 to 8, further including first and second metal terminators respectively mounted on the two electrodes.

10. The cell as claimed in any one of claims 1 to 9, encapsulated in an insulating material.

11. A method of manufacturing a cell for an electric double layer capacitor, comprising the following steps:

forming a composite electrode powder comprising an electronic conductor and a solid electrolyte;

forming a membrane powder including a solid protonic conducting electrolyte;

preforming a membrane by pressing said membrane powder;

simulteanously sintering two electrodes having said composite electrode powder, and said membrane;

positioning two metal terminators on said electrodes, respectively; and

encapsulating said cell.

12. The method as claimed in claim 11, wherein said step forming the composite electrode powder includes the step of forming a mixture by dispersing the electronic conductor in an aqueous solution of solid electrolyte constituents, and agitating said mixture at a predetermined temperature for a predetermined time so as to obtain an electrolyte precipitate enclosing the electronic conductor.

13. The method as claimed in claim 12, wherein said step of forming said composite powder includes the step of forming said solid electrolyte and said electronic conductor in predetermined proportions to obtain a composite powder with a lowest resistivity and a highest capacity.

14. The method as claimed in claim 12, wherein said step of forming said composite powder includes the step of forming said composite powder using a powdered electronic conductor which has been previously heat treated.

15. The method as claimed in any one of claims 11 to 14, wherein said step of forming said composite powder includes the step of forming a precipitate comprising said electronic conductor and said solid electrolyte, and the steps of washing, filtering, drying and crushing said precipitate.

16. The method as claimed in claim 11, further including the step of forming both said solid electrolyte and said solid protonic conducting electrolyte with H₃ OUO₂ PO₄.3H₂ O, the H₃ OUO₂ PO₄.3H₂ O powder by causing an equimolar mixture of 2 solutions of uranyl nitrate and phosphoric acid to precipitate at ambient temperature, in an aqueous medium, with permanent agitation for a period of 2 to 10 hours.

17. A cell for an electric double layer capacitor comprising:

a membrane formed of a solid protonic conducting electrolyte separating two electrodes, said solid protonic conducting electrolyte of said membrane comprising a protonic conductor chosen from a group consisting of uranyl phosphate H₃ OUO₂ PO₄.3H₂ O, zirconium phosphate Zr(HPO₄)₂ nH₂ O, derivatives of these compounds and protonic conductors with high protonic conductivity having a low electronic conductivity; and

two electrodes each comprising a composite electrode including a mixture of predetermined proportions of at least one electronic conductor and at least one solid electrolyte.

18. A cell as claimed in claim 17, wherein said solid electrolyte of said composite electrode comprises a protonic conductor chosen from a group consisting of uranyl phosphate H₃ OUO₂ PO₄.3H₂ O, zirconium phosphate Zr(HOP₄)₂ nH₂ O, derivatives of these compounds and protonic conductors with high protonic conductivity having a low electronic conductivity.

19. The cell as claimed in claim 17, wherein the H₃ O⁺ ions are substituted wholly or partially by a cation.

20. The cell as claimed in claim 19, wherein the cation is chosen from the group consisting of Na⁺, Li⁺, K⁺, Ca²⁺, Ag⁺.

21. The cell as claimed in claim 17 wherein the electronic conductor comprises one of activated carbon black, acetylene black, or a mixture of different carbon blacks and/or acetylene black.

22. The cell as claimed in claim 17 wherein said solid protonic conducting electrolyte forming the membrane is of a nature different from the solid electrolyte comprising the mixture in the electrodes.

23. The cell as claimed in claim 17 wherein said membrane comprises an organic protonated species exchanging membrane.

24. The cell as claimed in claim 17 wherein said membrane comprises a porous structure imbibed with an electrolyte.