Whisker resistant tin coatings and baths and methods for making such coatings

• US 4,749,626 A
• Filed: 07/03/1986
• Issued: 06/07/1988
• Est. Priority Date: 08/05/1985
• Status: Expired due to Fees

• Current Assignee: OLIN Corporation
• Original Assignee: OLIN Corporation
• Inventors: Parthasarathi, Arvind, Kadija, Igor V., Fister, Julius C., Winter, Joseph
• Primary Examiner(s): Kaplan, G. L.
• Application Number:
  US06/879,118
• Time in Patent Office: 705 Days
• Field of Search: 420/557, 428/646, 428/647, 428/648, 204/44.6, 204/44.4, 106/1.15, 106/1.19, 106/1.23, 106/1.24, 106/1.28, 106/1.21, 106/1.22, 427/436, 427/437
• US Class Current: 428/647
• CPC Class Codes: C23C 18/48 Coating with alloys
• CPC Class Codes: C25D 1/04 Wires; Strips; Foils
• CPC Class Codes: C25D 21/10 Agitating of electrolytes; Moving of racks
• CPC Class Codes: C25D 3/60 containing more than 50% by weight of tin
• CPC Class Codes: H05K 3/244 Finish plating of conductors, especially of copper conductors, e.g. for pads or lands selective plating methods H05K3/243; finish plating of conductors made by printing techniques H05K3/246; solder as finish H05K3/3457, e.g. by plating H05K3/3473
• CPC Class Codes: Y10T 428/12708 Sn-base component
• CPC Class Codes: Y10T 428/12715 Next to Group IB metal-base component
• CPC Class Codes: Y10T 428/12722 Next to Group VIII metal-base component

Abstract

The present invention relates to an addition to tin coating solutions for inhibiting the growth of tin whiskers. The addition comprises a concentration of a metal salt selected from the group consisting of palladium salt, silver salt, nickel salt, iron salt, cadmium salt, platinum salt, gold salt, indium salt, ruthenium salt and cobalt salt. In a preferred embodiment, the metal salt addition is either a palladium salt such as palladium chloride or a silver salt such as silver sulfate.

Claims

1. A method for inhibiting tin whisker growth on a substrate material having a tin containing coating, said method comprising:

preparing a tin coating solution containing a metal salt selected from the group consisting of palladium salts, silver salts, nickel salts, iron salts, cadmium salts, platinum salts, gold salts, indium salts, ruthenium salts, and cobalt salts; and

said preparing step comprising providing an initial tin containing solution and adding said metal salt to said initial solution in a concentration above the saturation point of the initial solution to form a metal salt saturated solution; and

applying said tin coating solution to said substrate material.

2. The method of claim 1 further comprising:

diluting said metal salt saturated solution by adding said metal salt saturated solution to an additional quantity of said initial solution, said diluted solution forming said tin coating solution.

3. The method of claim 2 wherein said salt adding step comprises:

adding a sufficient amount of palladium salt to said initial solution so that said tin coating solution contains a concentration of palladium in the range of from about 5 ppm to about 10,000 ppm.

4. The method of claim 2 wherein said salt adding step comprises:

adding a sufficient amount of palladium salt to said initial solution so that said tin coating solution contains a concentration of palladium in the range of from about 20 ppm to about 1000 ppm.

5. The method of claim 2 wherein said metal salt adding step comprises:

adding a sufficient amount of a silver salt to said initial solution so that said tin coating solution contains silver in a concentration in the range of from about 50 ppm to about 50,000 ppm.

6. The method of claim 2 wherein said metal salt adding step comprises:

adding a sufficient amount of a silver salt to said initial solution so that said tin coating solution contains silver in a concentration in the range of from about 500 ppm to about 5000 ppm.

7. The method of claim 1 wherein said applying step comprises immersing said substrate material in said tin coating solution.

8. The method of claim 1 wherein said applying step comprises electrolessly depositing the tin containing coating from said tin coating solution onto said substrate material.

9. The method of claim 1 wherein said applying step comprises electrodepositing the tin containing coating from said tin coating solution onto said substrate material.

10. The method of claim 1 wherein said applying step comprises applying said coating solution to said substrate material at a mixing rate in the range of from about 2 cm/sec to about 100 cm/sec.

11. The method of claim 1 wherein said applying step comprises applying said coating solution to said substrate material at a mixing rate in the range of from about 5 cm/sec to about 30 cm/sec.

12. A tin coating solution for imparting tin whisker formation resistance to a substrate material coated with a tin containing material, said solution comprising a tin containing solution having a concentration of a palladium salt, the palladium being present in an amount greater than about 50 ppm.

13. The tin coating solution of claim 12 wherein said palladium concentration is in the range of from about 50 ppm to about 1000 ppm.

14. A composite structure for use in electrical and electronic applications comprising:

a metal or metal alloy substrate;

a whisker resistant tin coating on at least one surface of said substrate, said tin coating consisting essentially of from about 0.1 w/o to about 20 w/o palladium for inhibiting tin whisker growth and the balance essentially tin; and

said tin coating having an essentially smooth surface and a relatively fine grain structure of less than about 1 micron with said substrate being formed from copper or a copper base alloy.

15. A composite structure for use in electrical and electronic applications comprising:

a metal or metal alloy substrate; and

a whisker resistant tin coating on at least one surface of said substrate, said tin coating consisting of from about 0.1 w/o to about 20 w/o palladium for inhibiting tin whisker growth and the balance essentially tin.

16. The composite structure of claim 15 further comprising:

said coating consisting of from about 0.5 w/o to about 10 w/o palladium and the balance essentially tin.

17. The composite structure of claim 15 further comprising:

said coating consisting of from about 1 w/o to about 5 w/o palladium and the balance essentially tin.

18. The composite structure of claim 15 further comprising:

said substrate being formed from copper or a copper base alloy.