Process for removing of heavy metal from water in particular from waste water

• US 4,764,284 A
• Filed: 05/08/1986
• Issued: 08/16/1988
• Est. Priority Date: 10/17/1983
• Status: Expired due to Term

• Current Assignee: DHV Raadgevend Ingenieursbureau BV LAAN 1914 NR 35 3818 EX Amersfoort The Netherlands
• Original Assignee: DHV Raadgevend Ingenieursbureau BV
• Inventors: Jansen, Cornelis W.
• Primary Examiner(s): Hruskoci, Peter
• Application Number:
  US06/860,063
• Time in Patent Office: 831 Days
• Field of Search: 210/714, 210/715, 210/717, 210/724, 210/912, 210/914, 423/35, 423/92, 423/105, 423/144, 423/165, 423/419 R, 423/433, 423/434, 23/305 R, 23/305 F
• US Class Current: 210/715
• CPC Class Codes: B01J 8/20 with liquid as a fluidising medium
• CPC Class Codes: C02F 1/5236 using inorganic agents
• CPC Class Codes: C02F 1/5281 Installations for water purification using chemical agents
• CPC Class Codes: C02F 1/687 Devices for dosing solid compounds
• CPC Class Codes: C02F 2101/20 Heavy metals or heavy metal compounds
• CPC Class Codes: C02F 2209/44 Time
• CPC Class Codes: C02F 9/00 Multistage treatment of water, waste water or sewage
• CPC Class Codes: Y10S 210/912 Heavy metal
• CPC Class Codes: Y10S 210/914 Mercury

Abstract

Process for removing Sr and heavy metals from water in particular from waste water by throughly mixing it with a solution of an alkali metal carbonate and/or hydrogen carbonate in a reactor containing a fluidized bed of suitable bed material. The obtained heavy metal carbonate crystals crystallize onto said bed material and the obtained heavy metal carbonate crystals in granular form are removed from the reactor from time to time.

The heavy metals which may be removed are Ni, Zn, Cu, Fe, Ag, Pb, Cd or Hg.

Claims

1. A process for the removal of metals selected from the group consisting of heavy metals and Sr from a metal containing water, thoroughly mixing the metal containing water with an effective amount of an aqueous solution of a carbonate selected from the group consisting of alkali metal carbonate, and alkali metal hydrogen carbonate in a reactor with a fluidized bed of a suitable bed material, upon which material the metal crystallizes exclusively in the form of metal carbonate or metal hydroxy carbonate crystals built into the crystal lattice of the bed material and said crystals grow in substantially pure form on the bed material to form granules having a water content of 0.5% or less, separating a purified water from said reactor, and recovering said granules from said bed.

2. A process according to claim 1, comprising using as said alkali metal carbonate or hydrogen carbonate, sodium carbonate or sodium hydrogen carbonate.

3. A process according to claim 1, comprising using as said alkali metal carbonate or alkali metal hydrogen carbonate, potassium carbonate or potassium hydrogen carbonate.

4. A process according to claims 1, 2 or 3 comprising using as said bed material, metal carbonate of the metal to be removed.

5. A process according to claims 1, 2 or 3 comprising using as said bed material, sand.

6. A process according to claims 1, 2 or 3 wherein said heavy metal is selected from the group consisting of Ni, Zn, Cu, Fe, Ag, Pb. Cd and Hg.

7. A process as claimed in claim 4, wherein said heavy metal is selected from the group consisting of Ni, Zn, Cu, Fe, Ag, Pb, Cd or Hg.

8. A process as claimed in claim 5, wherein said heavy metal is selected from the group consisting of Ni, Zn, Cu, Fe, Ag, Pb, Cd or Hg.