Inverse emulsion polymerization with sorbitan fatty acid esters and ethoxylated alcohol

• US 4,764,574 A
• Filed: 12/09/1986
• Issued: 08/16/1988
• Est. Priority Date: 12/09/1986
• Status: Expired due to Fees

• Current Assignee: Phillips Petroleum Company (ConocoPhillips)
• Original Assignee: Phillips Petroleum Company (ConocoPhillips)
• Inventors: Clark, Earl Jr.
• Primary Examiner(s): HENDERSON JR, CHRISTOPHER A
• Application Number:
  US06/939,641
• Time in Patent Office: 616 Days
• Field of Search: 526/206, 526/207
• US Class Current: 526/207
• CPC Class Codes: C08F 2/32 Polymerisation in water-in-oil emulsions
• CPC Class Codes: C08F 220/56 Acrylamide; Methacrylamide
• CPC Class Codes: C08F 220/585 and containing other heteroatoms, e.g. 2-acrylamido-2-methylpropane sulfonic acid [AMPS]
• CPC Class Codes: C08F 226/10 N-Vinyl-pyrrolidone
• CPC Class Codes: Y10S 526/911 Emulsifying agents

Abstract

In an inverse emulsion polymerization system for producing water-soluble polymers from a monomer system comprising an N-vinyl lactam and/or a vinyl-containing sulfonic acid or salt thereof utilizing a surfactant system having (1) a surfactant with a bulky lipophilic portion and an OH-containing hydrophilic portion and (2) a generally straight-chain nonionic surfactant having a lipophilic hydrocarbon group and an OH-terminated hydrophilic group, i.e. an alcohol. Such a system having both the right HLB and the right chemical combination results in a stable emulsion for the polymerization of these particular water-soluble monomers.

Claims

1. A water-in-oil emulsion polymerization process for making a water-soluble polymer from a monomer system comprising at least one of an N-vinyl lactam and a vinyl-containing sulfonate or the corresponding acid, comprising:

combining an aqueous component, a hydrocarbon component, said monomer system, an initiator, and a surfactant system, wherein said surfactant system comprises

(1) a first surfactant composition consisting essentially of a blend of a sorbitan fatty acid ester and a polyethoxylated sorbitan fatty acid ester, said first surfactant composition having an HLB within the range of about 7 to about 9;

(2) a second surfactant composition consisting essentially of an ethoxylated alcohol of the formula

space="preserve" listing-type="equation">R.sup.2 (OCH.sub.2 CH.sub.2).sub.4 OH

where R² is a straight chain hydrocarbon group having 16 to 18 carbon atoms, said second surfactant composition having an HLB within the range of about 7 to about 9;

agitating the resulting inverse emulsion and maintaining said inverse emulsion under polymerization conditions for a time sufficient to form said polymer.

2. A method according to claim 1 wherein said lactam is N-vinyl pyrrolidone and said vinyl-containing sulfonate is 2-acrylamido-2-methylpropane sulfonate, sodium salt.

3. A method according to claim 1 wherein said monomer system comprises at least two monomers selected from said N-vinyl lactam, said vinyl-containing sulfonate, and an unsaturated amide.

4. A method according to claim 3 wherein said polymer is a copolymer selected from one of the following monomer combinations:

N-vinylpyrrolidone/acrylamide;

2-acrylamido-2-methylpropane sulfonate, sodium salt/acrylamide; and

N-vinylpyrrolidone/2-acrylamido-2-methylpropane sulfonate, sodium salt.

5. A method according to claim 4 wherein said monomer combination is said

N-vinylpyrrolidone/2-acrylamido-2-methylpropane sulfonate, sodium salt and wherein said monomer are present in a weight ratio within the range of 10:

90 to 90;

10.

6. A method according to claim 4 wherein said monomer combination is said N-vinylpyrrolidone/acrylamide and wherein said monomers are present in a weight ratio within the range of 10:

90 to 90;

10.

7. A method according to claim 4 wherein said monomer combination is said 2-acrylamido-2-methylpropane sulfonate, sodium salt/acrylamide and wherein said monomers are present in a weight ratio within the range of 10:

90 to 90;

10.

8. A method according to claim 1 wherein said polymer is a terpolymer of the following monomer combination:

N-vinylpyrrolidone/acrylamide/2-acrylamido-2-methylpropane sulfonate, sodium salt.

9. A method according to claim 8 wherein said monomers are present in a weight percent ratio of about 20 to 40 N-vinylpyrrolidone/ 10 to 20 acrylamide/ and 40 to 65 2-acrylamido-2-methylpropane sulfonate sodium salt.

10. A method according to claim 9 wherein said weight ratio is about 30/15/55.

11. A method according to claim 1 wherein said sorbitan fatty acid ester is selected from the group consisting of sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan tristearate, sorbitan monooleate, and sorbitan trioleate, and wherein said polyethoxylated sorbitan fatty acid ester is selected from the group consisting of polyoxyethylene sorbitan monolaurate, polyoxyethylene sorbitan monopalmitate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan tristearate, polyoxyethylene sorbitan monooleate and polyoxyethylene sorbitan trioleate.

12. A method according to claim 11 wherein said first surfactant composition has an HLB of about 8, and wherein said second surfactant composition has an HLB of about 8.

13. A method according to claim 12 wherein said monomer system comprises N-vinylpyrrolidone and 2-acrylamido-2-methylpropane sulfonate, sodium salt, and wherein said sorbitan fatty acid ester is sorbitan monooleate present in an amount of about 9 parts by weight per 100 parts by weight of said monomer system, wherein said polyethoxylated sorbitan fatty acid ester is polyoxyethylene sorbitan triooleate in an amount of about 11 parts by weight per 100 parts per weight of said monomer system, wherein said ethoxylated alcohol is present in an amount of about 12 parts by weight per 100 parts by weight of said monomer system, wherein said aqueous component is present in an amount of about 100 to 150 parts by weight per 100 parts by weight of monomer, and wherein said hydrocarbon component is present in an amount within the range of about 80 to 100 parts by weight per 100 parts by weight of monomer.

14. A method according to claim 12 wherein said initiator includes p-menthane hydroperoxide in combination with FeSO₄.7H₂ O, tetrasodium salt of ethylene diamine tetracetic acid, and sodium formaldehyde sulfoxylate.

15. A method according to claim 1 wherein said aqueous component is present in the amount of about 80 to 120 parts by weight per 100 parts by weight of said monomer system, and wherein said hydrocarbon component is present in the amount of about 80 to 100 parts by weight per hundred parts by weight of said monomer system.

16. A method according to claim 12 wherein said monomer system comprises the combination of a vinyl-containing sulfonate and an unsaturated amide.

17. A method according to claim 16 wherein said vinyl-containing sulfonate is sodium 2-acrylamido-2-methylpropane sulfonate and said unsaturated amide is acrylamide.