Method for producing rare earth alloy

• US 4,769,063 A
• Filed: 02/26/1986
• Issued: 09/06/1988
• Est. Priority Date: 03/06/1986
• Status: Expired due to Term

• Current Assignee: Sumitomo Seika Chemicals Company Limited
• Original Assignee: Sumitomo Seika Chemicals Company Limited
• Inventors: Ishigaki, Naoyuki, Fujimura, Setsuo, Hamada, Takaki
• Primary Examiner(s): Sheehan, John P.
• Application Number:
  US06/832,890
• Time in Patent Office: 923 Days
• Field of Search: 75/0.5 BA, 148/301, 148/302, 148/331, 420/83, 420/121, 420/455, 420/581
• US Class Current: 75/349
• CPC Class Codes: B22F 9/20 starting from solid metal compounds
• CPC Class Codes: C22B 5/04 by aluminium, other metals or silicon
• CPC Class Codes: C22B 59/00 Obtaining rare earth metals
• CPC Class Codes: C22C 1/0441 Alloys based on intermetallic compounds of the type rare earth - Co, Ni
• CPC Class Codes: H01F 1/0573 obtained by reduction or by hydrogen decrepitation or embrittlement
• CPC Class Codes: H01F 1/0577 sintered
• CPC Class Codes: H01F 1/06 in the form of particles, e.g. powder H01F1/047 takes precedence ; record carriers G11B5/70605

Abstract

A rare earth alloy for producing permanent magnet comprised of: 15-65 atomic % R₁, 35-83 atomic % Fe, and 0-15 atomic % B, where R₁ represents at least one of heavy rare earth elements Gd, Tb, Dy, Ho, Er, Tm and Yb. This alloy is produced by reducing a mixture of correspoding rare earth oxides, Fe, and a boron containing material by Ca, contacting the reduced mass with water, and treating the resultant slurry with water. Using this alloy, Fe-B-R base magnets wherein R₁ is substituted for part of R (R representing lanthanide and/or Y) having a high performance are produced with a reduced cost.

Claims

1. A method for producing a rare earth alloy which comprises:

preparing a mixed raw material powder comprising at least one of the oxides of rare earth elements R.sub. 1, an iron powder and a boron containing powder selected from the group consisting of boron, ferroboron and boron oxide in a manner such that the resultant alloy product consists essentially of;

15-65 atomic % R₁,

35-83 atomic % Fe, and

0-15 atomic % B,

in which R₁ represents at least one of heavy rare earth elements selected from the group consisting of Gd, Tb, Dy, Ho, Er, Tm and Yb;

said mixed raw material powder further comprising metallic Ca and/or Ca hydride in an amount of 1.2-3.5 times by weight of the amount stoichiometrically required for reducing oxygen in said raw material powder and at least one of the oxides of said rare earth elements R₁, and 1-15 % by weight of calcium chloride based on the oxides of said rare earth elements R₁ ;

compacting the resultant mixture;

subjecting the resultant compacted mixture to reduction-diffusion treatment under a nonoxidizing atmosphere at a temperature of 950°

-1200°

C.;

bringing the reduced mass to a particle size of 8 mesh to 35 mesh;

contacting the resultant reduced mass with water to form a slurry-like substance; and

treating said slurry-like substance with water by stirring the slurry and removing water to recover the resultant alloy powder;

whereby said alloy powder has an oxygen content of at most 7000 ppm, and a carbon content of at most 1000 ppm.

2. The method according to claim 1, in which said mixed raw material powder is prepared so that said alloy product consists essentially of:

25-40 atomic % R₁,

50-71 atomic % Fe, and

4-10 atomic % B.

3. The method according to claim 1, wherein the treating with water is effected until the amount of Ca becomes no more than 2000 ppm in the resultant alloy powder.

4. The method according to claim 1, wherein the reduction-diffusion treatment is effected at a temperature ranging from 950°

to 1100°

C.

5. The method according to claim 1, wherein the method further comprises consolidation of the resultant alloy powder.