Magnetic materials and permanent magnets
DCFirst Claim
1. An anisotropic magnetic material having a mean crystal grain size of at least about 1 micron, an intrinsic coercivity of at least 1 kOe and having a maximum energy product of at least 10 MGOe upon sintering, said material consisting essentially of, by atomic percent, 12-20 percent R wherein R is at least one element selected from the group consisting of Nd, Pr, La, Ce Tb, Dy, Ho, Er, Eu, Sm, Gd, Pm, Tm, Yb, Lu and Y and wherein at least 50% of R consists of Nd and/or Pr, 4-24 percent B and the balance being at least 56 percent Fe, in which at least 50 vol % of the entire material is occupied by a ferromagnetic compound having a Fe--B--R type tetragonal crystal structure.
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Abstract
Magnetic materials comprising Fe, B and R (rare earth elements) having a major phase of Fe--B--R intermetallic compound(s) of tetragonal system, and sintered anisotropic permanent magnets consisting essentially of, by atomic percent, 8-30% R (at least one of rare earth elements inclusive of Y), 2-28% B and the balance being Fe with impurities. Those may contain additional elements M (Ti, Ni, Bi, V, Nb, Ta, Cr, Mo, W, Mn, Al, Sb, Ge, Sn, Zr, Hf) providing Fe--B--R--M type materials and magnets.
171 Citations
35 Claims
- 1. An anisotropic magnetic material having a mean crystal grain size of at least about 1 micron, an intrinsic coercivity of at least 1 kOe and having a maximum energy product of at least 10 MGOe upon sintering, said material consisting essentially of, by atomic percent, 12-20 percent R wherein R is at least one element selected from the group consisting of Nd, Pr, La, Ce Tb, Dy, Ho, Er, Eu, Sm, Gd, Pm, Tm, Yb, Lu and Y and wherein at least 50% of R consists of Nd and/or Pr, 4-24 percent B and the balance being at least 56 percent Fe, in which at least 50 vol % of the entire material is occupied by a ferromagnetic compound having a Fe--B--R type tetragonal crystal structure.
- 2. A sintered anisotropic permanent magnet having maximum energy product of at least 10 MGOe and consisting essentially of, by atomic percent, 12-20 percent R wherein R is at least one element selected from the group consisting of Nd, Pr, La, Ce, Tb, Dy, Ho, Er, Eu, Sm, Gd, Pm, Tm, Yb, Lu and Y and wherein at least 50% of R consists of Nd and/or Pr, 4-24 percent B and the balance being at least 56 percent Fe.
- 3. A sintered anisotropic permanent magnet having a mean crystal grain size of at least about 1 micron and consisting essentially of, by atomic percent 12-20 percent R wherein R is at least one element selected from the group consisting of Nd, Pr, La, Ce, Tb, Dy, Ho, Er, Eu, Sm, Gd, Pm, Tm, Yb, Lu and Y and wherein at least 50% of R consists of Nd and/or Pr, 4-24 percent B and the balance being at least 56 percent Fe, in which at least 50 vol % of the entire magnet is occupied by a ferromagnetic compound having a Fe--B--R type tetragonal crystal structure, said magnet having a maximum energy product of at least 10 MGOe.
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12. An anisotropic magnetic material having a mean crystal grain size of at least about 1 micron and an intrinsic coercivity of at least 1 kOe and having a maximum energy product of at least 10 MGOe upon sintering, said material consisting essentially of, by atomic percent, 12-20 percent R wherein R is at least one element selected from the group consisting of Nd, Pr, La, Ce, Tb, Dy, Ho, Er, Eu, Sm, Gd, Pm, Tm, Yb, Lu and Y and wherein at least 50% of R consists of Nd and/or Pr, 4-24 percent B, at least one additional element M selected from the group given below in the amounts of no more than the atomic percentages specified below wherein the sum of M is no more than the maximum value of any one of the values specified below for M actually added and the balance being at least 56 percent Fe, in which a crystal phase of a ferromagnetic compound having a Fe--B--R type tetragonal crystal structure occupies at least 50 vol % of the entire material:
space="preserve" listing-type="tabular">______________________________________ 3.3% Ti, 4.5% Ni, 5.0% Bi, 6.6% V, 10.0% Nb, 8.4% Ta, 5.6% Cr, 6.2% Mo, 5.9% W, 3.5% Mn, 6.4% Al, 1.4% Sb, 4.5% Ge, 1.8% Sn, 3.7% Zr, and 3.7% Hf. ______________________________________
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13. A sintered anisotropic permanent magnet having a maximum energy product of at least 10 MGOe and consisting essentially of, by atomic percent, 12-20 percent R wherein R is at leat one element selected from the group consisting of Nd, Pr, La, Ce, Tb, Dy, Ho, Er, Eu, Sm, Gd, Pm, Tm, Yb, Lu and Y and wherein at least 50% of R consists of Nd and/or Pr, 4-24 percent B, at least one additional element M selected from the group given below in the amounts of no more than the atomic percentages specified below, wherein the sum of M is no more than the maximum value of any one of the values specified below for M actually added and the balance being at least 56 percent Fe,:
space="preserve" listing-type="tabular">______________________________________ 3.3% Ti, 4.5% Ni, 5.0% Bi, 6.6% V, 10.0% Nb, 8.4% Ta, 5.6% Cr, 6.2% Mo, 5.9% W, 3.5% Mn, 6.4% Al, 1.4% Sb, 4.5% Ge, 1.8% Sn, 3.7% Zr, and 3.7% Hf. ______________________________________- View Dependent Claims (16, 17, 18, 19, 20, 21, 22, 25, 26, 28, 31)
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14. A sintered anisotropic permanent magnet having a mean crystal grain size of at least about 1 micron and consisting essentially of, by atomic percent, 12-20 percent R wherein R is at least one element selected from the group consisting of Nd, Pr, La, Ce, Tb, Dy, Ho, Er, Eu, Sm, Gd, Pm, Tm, Yb, Lu and Y and wherein at least 50% of R consists of Nd and/or Pr, 4-24 percent B, at least one additional element M selected from the group given below in the amounts no more than the atomic percentages specified below, wherein the sum of M is no more than the maximum value of any one of the values specified below for M actually added and the balance being at least 56 percent Fe:
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space="preserve" listing-type="tabular">______________________________________ 3.3% Ti, 4.5% Ni, 5.0% Bi, 6.6% V, 10.0% Nb, 8.4% Ta, 5.6% Cr, 6.2% Mo, 5.9% W, 3.5% Mn, 6.4% Al, 1.4% Sb, 4.5% Ge, 1.8% Sn, 3.7% Zr, and 3.7% Hf ______________________________________in which a crystal phase of a ferromagnetic compound having a Fe--B--R type tetragonal crystal structure occupies at least 50 vol % of the entire magnet, said permanent magnet having a maximum energy product of at least 10 MGOe. - View Dependent Claims (15, 24)
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29. A powdery magnetic material capable of uniaxial alignment upon orientation in a magnetic field to provide magnetic anisotropy, and having a maximum energy product of at least 10 MGOe and an intrinsic coercivity of at least 1 kOe upon sintering, said material having a mean crystal grain size of at least about 1 micron, and consisting essentially of, by atomic percent, 12-20 percent R wherein R is at least one element selected from the group consisting of Nd, Pr, La, Ce, Tb, Dy, Ho, Er, Eu, Sm, Gd, Pm, Tm, Yb, Lu and Y and wherein at least 50% of R consists of Nd and/or Pr, 4-24 percent B and the balance being at least 56 percent Fe, in which at least 50 vol % of the entire material is occupied by a ferromagnetic compound having a Fe--B--R type tetragonal crystal structure.
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30. A powdery magnetic material capable of uniaxial alignment upon orientation in a magnetic field to provide magnetic anisotropy, and having a maximum energy product of at least 10 MGOe and an intrinsic coercivity of at least 1 kOe upon sintering, said material having a mean crystal grain size of at least about 1 micron, and consisting essentially of, by atomic percent, 12-20 percent R wherein R is at least one element selected from the group consisting of Nd, Pr, La, Ce, Tb, Dy, Ho, Er, Eu, Sm, Gd, Pm, Tm, Yb, Lu and Y and wherein at least 50% of R consists of Nd and/or Pr, 4--24 percent B, at least one additional element M selected from the group given below in the amounts of no more than the atomic percentages specified below wherein the sum of M is no more than the maximum value of any one of the values specified below for M actually added and the balance being at least 56 percent Fe, in which crystal phase of a ferromagnetic compound having a Fe--B--R type tetragonal crystal structure occupies at least 50 vol % of the entire material:
space="preserve" listing-type="tabular">______________________________________ 3.3% Ti, 4.5% Ni, 5.0% Bi, 6.6% V, 10.0% Nb, 8.4% Ta, 5.6% Cr, 6.2% Mo, 5.9% W, 3.5% Mn, 6.4% Al, 1.4% Sb, 4.5% Ge, 1.8% Sn, 3.7% Zr, and 3.7% Hf. ______________________________________
Specification