Method and apparatus for operating a fuel cell in combination with an electrochemical cell to produce a chemical product

• US 4,780,187 A
• Filed: 03/20/1987
• Issued: 10/25/1988
• Est. Priority Date: 06/03/1983
• Status: Expired due to Fees

• Current Assignee: Alexander H. Levy, Kenneth Lipman
• Original Assignee: Alexander H. Levy, Kenneth Lipman
• Inventors: Lipman, Kenneth, Levy, Alexander H.
• Primary Examiner(s): NOT, DEFINED
• Application Number:
  US07/027,039
• Time in Patent Office: 585 Days
• Field of Search: 429/3, 429/7, 429/13, 429/21, 429/23, 429/50, 429/17, 429/19, 204/129, 204/220, 204/DIG. 4, 204/247
• US Class Current: 204/242
• CPC Class Codes: C25B 15/00 Operating or servicing cells
• CPC Class Codes: H01M 8/04597 of auxiliary devices, e.g. batteries, capacitors
• CPC Class Codes: H01M 8/04619 of fuel cell stacks
• CPC Class Codes: H01M 8/04626 of auxiliary devices, e.g. batteries, capacitors
• CPC Class Codes: H01M 8/0488 of fuel cell stacks
• CPC Class Codes: H01M 8/0491 of fuel cell stacks
• CPC Class Codes: H01M 8/0494 of fuel cell stacks
• CPC Class Codes: H01M 8/04947 of auxiliary devices, e.g. batteries, capacitors
• CPC Class Codes: H01M 8/0656 by electrochemical means H01M8/065 takes precedence
• CPC Class Codes: Y02E 60/50 Fuel cells
• CPC Class Codes: Y10S 204/04 Electrolysis cell combined with fuel cell

Abstract

A method and apparatus is disclosed for operating a fuel cell 14 which produces electrical energy using hydrogen in combination with a chlorate electrolysis cell which uses electrical energy to produce a chlorate product and hydrogen. A regulator means employs a direct current converter 16 having a gated switch means, such as thyristor 98, to intermittently pass electrical power from the fuel cell to the chlorate electrolysis cell such that the voltage drop across the direct current converter is equal to the difference in voltage between the fuel cell and the electrolysis cell.

Claims

1. An apparatus for carrying out an electrochemical process which comprises:

a chlorate electrolysis cell which uses input electrical power at a first voltage and a first current to produce a chlorate product and hydrogen;

at least one fuel cell which utilizes hydrogen to produce output electrical power at a second voltage which is independent of the voltage of the electrochemical cell and a second current;

means for supplying the hydrogen produced by the electrolysis cell to the fuel cell for comsumption of at least a portion of the hydrogen by the fuel cell; and

,

regulator means responsive to the power produced by the fuel cell and responsive to the hydrogen available to the fuel cell for supplying output power received from the fuel cell as input power at the first voltage to the electrolysis cell, said means being electrically connected to the fuel cell and the electrolysis cell and said means employing gated switch means which intermittently passes current for regulating the electrical power received from the fuel cell to adjust the current and voltage supplied by the fuel cell so that the voltage change across said regulator means is equal to the difference between the first voltage and the second voltage.

2. The apparatus as claimed in claim 1 wherein the electrolysis cell is a first source of hydrogen and wherein the apparatus includes a second source of hydrogen for supplying additional hydrogen to the fuel cell.

3. The apparatus as claimed in claim 1 wherein the fuel cell supplies a portion of the power to the electricalchemical cell and wherein the apparatus further includes means for supplying additional power to the electrolysis cell.

4. The apparatus as claimed in claim 3 wherein the fuel cell has a schedule of desired operating voltages and wherein the fuel cell includes a means for controlling the fuel cell voltage such that the voltage of the fuel cell lies within said schedule of desired operating voltages.

5. The apparatus as claimed in claim 4 wherein said gated switch means responsive to a gate signal which has a conducting position and a nonconducting position and wherein said regulator means includes an inductor connected to said gated switch means for resisting changes in current through the inductor and generating a voltage change across the inductor, wherein said regulator means includes pulse means for creating a current pulse to deenergize said gated switch means, said pulse means being connected to the gated switch means at a point between the gated switch means and the inductor, and includes means to enable the flow of current to the electrolysis cell during the period of time said switch is in the nonconducting position through said inductor and to oppose the diversion of the flow of current from the electrolysis cell to ground through a point between said gated switch means and said inductor.

6. The apparatus as claimed in claim 5 wherein the gated switch means is a first gated switch means and wherein said pulse means includes a second gated switch means responsive to a second gate signal and a means for developing a current pulse which is in series with said second gated switch means, wherein said second gated switch means passes a current to the means for developing a current pulse in response to a gate signal.

7. The invention as claimed in claim 6 wherein said means for developing a current pulse includes a capacitor for storing charge and further includes a third gated switch means responsive to a third gate signal which is connected to the capacitor and the first gated switch means, wherein the third gated switch means conducts the current pulse to the first gated switch as the capacitor discharges through the third gated switch means.

8. The invention as claimed in claim 7 wherein said regulator means is a bucking regulator having a first circuit and a second circuit, the first circuit having a first leg extending between the fuel cell and the electrolysis cell and a second leg extending between the fuel cell and the electrolysis cell, wherein the first leg includes

said first gated switch, wherein said first gated switch is a first thyristor having an anode and a cathode,

said inductor wherein the inductor is connected to the cathode of the first thyristor and in series with the first thyristor between the first thyristor and the electrolysis cell, and

said means to enable the flow of current to the electrolysis cell, wherein said means to enable the flow of current is a second diode having a cathode and an anode, the diode being connected to a point between the first thyristor and the inductor in the first leg, the diode being connected to the second leg such that the cathode of the second diode is joined to the cathode of the first thyristor;

wherein the second circuit includes the pulse means for creating a current, the second circuit including

a first leg having a first parallel diode extending in parallel across the first thyristor of the first circuit, the anode of the parallel diode being connected to the cathode of the first thyristor for conducting a portion of the current pulse to said capacitor,

a second leg extending in parallel across the first thyristor, the second leg having said second gated switch means, said second switch means being a second thyristor in series with said third gated switch means, wherein the cathode side of the third switch means is connected to the cathode side of the first thyristor and the anode side of the second thyristor being connected to the anode side of the first thyristor, and

a third leg connected in parallel from the anode side of the first thyristor to the cathode side of the second thyristor, the third leg including said capacitor and a second inductor, the capacitor having one side connected to the anode side of the first thyristor and a second side connectec to the inductor and through the inductor to the cathode side of the second thyristor.

9. The invention as claimed in claim 8 wherein a resistor extends from a point between the capacitor and the second inductor in the third leg of the second circuit to the second leg of the first circuit.