Method for permanganate bleaching of fabric and garments
First Claim
1. In a process for preparing bleached fabrics wherein the fabric is treated with a permanganate oxidizing agent which is subsequently reduced, the improvement comprising reducing the permanganate with a reducing composition comprising sodium metabisulfite and sodium sulfite in amounts wherein the metabisulfite and sulfite are present in a mole ratio of between about 0.6 and about 3.2 such that substantially no sulfur dioxide odor is detectable during the reduction step.
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Abstract
Permanganate based fabric bleaching processes, such as stone-washing processes, are substantially improved by utilizing a reducing composition comprising a metabisulfite and a sulfite in the washing step. The relative amounts of metabisulfite and sulfite in the reducing composition are selected so as to substantially eliminate the odor of sulfur dioxide during the washing step at the particular temperature selected. For washing temperatures of 100°-140 ° F. the preferred weight ratio of sodium metabisulfite to sodium sulfite is 7:3, which produces a reducing composition having a pH of 6.2 (in a 5% by weight solution). Such a composition not only allows operation at elevated temperatures without an odor of SO2, it also allows a reduction in the washing time and in the amount of reducing composition used.
20 Citations
5 Claims
- 1. In a process for preparing bleached fabrics wherein the fabric is treated with a permanganate oxidizing agent which is subsequently reduced, the improvement comprising reducing the permanganate with a reducing composition comprising sodium metabisulfite and sodium sulfite in amounts wherein the metabisulfite and sulfite are present in a mole ratio of between about 0.6 and about 3.2 such that substantially no sulfur dioxide odor is detectable during the reduction step.
Specification