Preparation of finely divided, water-dispersable carotenoid formulations

• US 4,844,934 A
• Filed: 03/20/1987
• Issued: 07/04/1989
• Est. Priority Date: 03/26/1986
• Status: Expired due to Term

• Current Assignee: BASF AG (BASF SE)
• Original Assignee: BASF AG (BASF SE)
• Inventors: Horn, Dieter, Lueddecke, Erik
• Primary Examiner(s): BASCOMB JR, WILBUR
• Application Number:
  US07/028,545
• Time in Patent Office: 837 Days
• Field of Search: 426/540, 426/96, 426/98, 8/506, 514/772, 252/309, 252/314, 252/363.5
• US Class Current: 426/540
• CPC Class Codes: A23L 5/44 using carotenoids or xanthophylls
• CPC Class Codes: C07C 403/24 having side-chains substituted by six-membered non-aromatic rings, e.g. beta-carotene
• CPC Class Codes: C09B 61/00 Dyes of natural origin prepared from natural sources , e.g. vegetable sources

Abstract

Water-disperable carotenoid formulations are prepared by dissolving the carotenoid in a carrier oil at elevated temperatures until saturation is achieved, rapidly emulsifying the solution with an aqueous protective colloid and then removing the water, by a process in which the protective colloid used is a mixture of an ester of a long-chain fatty acid with ascorbic acid and a starch product which is soluble in cold water.

The produce can be used for coloring foods and is stable to creaming.

Claims

1. A process for the preparation of a water-dispersible carotenoid formulation by dissolving the carotenoid in a carrier oil at elevated temperatures until saturation is achieved to form a carotenoid solution, rapidly emulsifying the carotenoid solution with an aqueous protective colloid and then removing the water, wherein the protective colloid is a solution having a pH in the acidic range and consists essentially of a combination of a long-chain fatty acid ester of ascorbic acid and a cold water soluble starch product.

3. The process of claim 1, wherein ascorbyl palmitate is the long-chain fatty acid ester of ascorbic acid.

4. The process of claim 1, wherein dextrin or chemically modified starch is the cold water soluble starch product.

5. The process of claim 6, wherein the starch product is starch octenyl succinate.

6. The process of claim 1, wherein the starch product is dextrin.

7. The process of claim 3, wherein lecithin and tocopherol are also added to the carotenoid solution.

8. The process of claim 3, wherein lecithin and tocopherol are also added to the carotenoid solution, wherein the carotenoid is β

-carotene and wherein the starch product is dextrin.

9. The process of claim 3, wherein lecithin and tocopherol are also added to the carotenoid solution, wherein the carotenoid is β

-carotene and wherein the starch product is starch octenyl succinate.

2. A process for the preparation of a water-dispersible carotenoid formulation by dissolving the carotenoid in a carrier oil at elevated temperature until saturation is achieved to form a carotenoid solution, rapidly emulsifying the carotenoid solution with an aqueous protective colloid and then removing the water, wherein the protective colloid is a solution having a pH in the acidic range and consists essentially of a combination of (A) an ascorbyl ester of a fatty acid of 18 carbon atoms and (B) a cold water soluble starch product selected from the group consisting of chemically modified starch and dextrin with a dextrose equivalent of less than 20, the weight ratio of (A) to (B) being from 1:

100 to 1;

1.