Method of producing an elongated glass body, particularly a preform for optical waveguides

• US 4,867,774 A
• Filed: 09/25/1987
• Issued: 09/19/1989
• Est. Priority Date: 05/21/1985
• Status: Expired due to Fees

• Current Assignee: Alcatel NV (Nokia Corporation)
• Original Assignee: Alcatel NV (Nokia Corporation)
• Inventors: Dorn, Reimund
• Primary Examiner(s): Schor, Kenneth M.
• Application Number:
  US07/102,294
• Time in Patent Office: 725 Days
• Field of Search: 65/18.1, 65/3.11, 65/3.14, 65/3.2, 65/900, 65/2, 65/18.2, 65/DIG. 16, 65/144, 65/30.13, 65/30.1, 264/57, 264/60, 264/120, 264/1.5, 264/1.2, 264/56, 264/119, 264/314, 264/315, 264/2.2, 264/113, 264/125, 264/332
• US Class Current: 264/1.21
• CPC Class Codes: C03B 19/06 by sintering, e.g. by cold isostatic pressing of powders and subsequent sintering, by hot pressing of powders, by sintering slurries or dispersions not undergoing a liquid phase reaction
• CPC Class Codes: C03B 37/01282 by pressing or sintering, e.g. hot-pressing
• CPC Class Codes: Y10S 65/90 Drying, dehydration, minimizing oh groups

Abstract

A method is described of producing an elongated glass body, particularly a preform for SiO₂ -base optical waveguides, in which starting glass powder material is shaped to a porous body and the latter is sintered to form a glass body. In order to obtain uniform density throughout the porous body, the starting glass powder material is filled into and simultaneously compacted in a mold. Subsequently, the powder material compacted during the filling is consolidated by a heat treatment to result in the porous body. Molds of different design for the production of tubular or rod-shaped porous bodies are described.

Claims

1. A method of producing an elongated glass body for use as a preform for SiO₂ -base optical waveguides wherein a porous body is initially formed from a glass powder material and then sintered to form the glass body, said method comprising the steps of:

providing a supply vessel for glass powder material, said supply vessel including a tube extending therefrom, and a conveying means for conveying glass powder material from said vessel through said tube;

inserting said tube from said supply vessel into a first end of a rigid, hollow elongated mold, said tube having an open portion from which glass powder material is discharged into said mold and said tube and mold exhibiting selective relative motion along the lengths thereof, thereby enabling said mold to be displaced with respect to said tube as said mold receives glass powder material;

covering a second end of said mold with cover means for covering said second end of said mold;

applying a longitudinal force against the cover means so that the force acts upon the cover means and mold in a direction towards the first end;

conveying glass powder material from said supply vessel through said tube, said conveying means subjecting said glass powder material to a continuous filling pressure as said glass powder material is conveyed through said tube;

discharging glass powder material from said open portion of said tube into said mold thereby displacing said mold in a direction opposite to that of said longitudinal force applied to said cover means with respect to said tube as filling pressure on said glass powder material at said open portion of said tube acts against the longitudinal force applied to said cover means, whereby the glass powder material is compacted as it is discharged from the tube;

consolidating said compacted glass powder material within said mold by heat treating to form a porous body; and

sintering the porous body to form the glass body.

2. The method according to claim 1 wherein said mold is formed of silica glass.

3. The method according to claim 1 wherein said mold takes the form of a porous tube of glass material having a composition differing from said glass powder material, said method additionally comprising the step of simultaneously sintering said porous tube of glass material to form said glass body after said porous body has been formed therein by heat treating compacted glass powder material therein.

4. The method according to claim 1 wherein said mold takes the form of a tube having a plurality of parts, said method additionally comprising the steps of disassembling said tube and removing the porous body therefrom.

5. The method according to claim 1 wherein the step of sintering said porous body is performed within said mold and additionally comprising the step of removing the glass body formed from said mold.

6. The method according to claim 1 additionally comprising the step of inserting a portion of a silica glass rod into said glass powder material during said step of conveying and retaining said portion of said silica glass rod as a manipulating aid during subsequent method steps.

7. The method according to claim 1 wherein said step of conveying is accomplished by a screw conveyor under continuous controllable pressure and speed.

8. The method according to claim 1 wherein said step of conveying is achieved by means of an arrangement of coaxial screw conveyors whereby glass powder material having a first composition is conveyed into said mold in one area near an axis thereof and at least one material having a different composition is conveyed into said mold in at least another area coaxial with said one area, said step of conveying being conducted under continuous controllable pressure and speed.

9. The method according to claim 1 wherein glass powder materials having differing composition are conveyed successively in time into adjacent coaxial areas of said mold by separate screw conveyors under continuous controllable pressure and speed.

10. The method according to claim 1, wherein said filling pressure is produced by force generated by a screw conveyor and is limited to a maximum level determined by said longitudinal force.

11. The method according to claim 1 wherein said glass powder material is subjected to treatment prior to placement in said supply vessel said treatment taking the form of at least one of drying by vacuum annealing and purification by heat treating in a chlorine-containing atmosphere.

12. The method according to claim 1 additionally comprising the step of agglomerating said glass powder material in order to increase bulk density prior to the step of conveying.

13. The method according to claim 1 wherein said porous body formed in said mold is doped by a heat treatment wherein a dopant is diffused into said porous body.

14. The method according to claim 1 wherein a rod-shaped body is positioned in the center of said mold to extend from one end of said mold to the other prior to said step of conveying, whereby said glass powder material is conveyed to fill said mold with compacted glass powder surrounding said rod-shaped body.