Oxygen absorbent

• US 4,908,151 A
• Filed: 02/12/1988
• Issued: 03/13/1990
• Est. Priority Date: 02/14/1987
• Status: Expired due to Term

• Current Assignee: Mitsubishi Gas Chemical Company Incorporated (Mitsubishi Electric Corporation)
• Original Assignee: Mitsubishi Gas Chemical Company Incorporated (Mitsubishi Electric Corporation)
• Inventors: Inoue, Yoshiaki, Komatsu, Toshio
• Primary Examiner(s): Hunt, Brooks H.
• Assistant Examiner(s): NOT, DEFINED
• Application Number:
  US07/155,283
• Time in Patent Office: 760 Days
• Field of Search: 252/188.28
• US Class Current: 252/188.28
• CPC Class Codes: A23L 3/3427 in which an absorbent is placed or used packages for foodstuffs with provision for absorbing fluids B65D81/26
• CPC Class Codes: A23L 3/3436 Oxygen absorbent
• CPC Class Codes: B01J 20/3204 Inorganic carriers, supports or substrates
• CPC Class Codes: B01J 20/3248 the functional group or the linking, spacer or anchoring group as a whole comprising at least one type of heteroatom selected from a nitrogen, oxygen or sulfur, these atoms not being part of the carrier as such

Abstract

The present invention relates to an oxygen absorbent, and more particularly to an oxygen absorbent applicable to preservation of dry foodstuffs and medical drugs and to the rust prevention of metallic articles. Thus, the invention provides an oxygen absorbent comprising:

(A₁) an unsaturated fatty acid and/or a fatty oil containing unsaturated fatty acid,

(B₁) a transition metal and/or a transition metal compound, and

(C₁) a basic substance,

and an oxygen absorbent comprising:

(A₂) one member or a mixture of two or more members selected from unsaturated fatty acid compounds including unsaturated fatty acids, esters of unsaturated fatty acid and metallic salts of unsaturated fatty acid,

(B₂) a basic substance, and

(C₂) an adsorbent.

Claims

1. An oxygen absorbent comprising:

(A₁) an unsaturated fatty acid and/or a fatty oil containing unsaturated fatty acid,

(B₁) a transition metal and/or a transition metal compound, and

(C₁) a basic substance which is an alkaline earth metal compound of at least one of an an oxide, hydroxide, carbonate, bicarbonate, silicate, phosphate or organic acid.

2. An oxygen absorbent according to claim 1, wherein said (B₁) transition metal and/or transition metal compound is at least one transition metal selected from the group consisting of V, Cr, Mn, Co, Fe, Ni, Cu and Zn and/or at least one transition metal compound selected from the group consisting of V compound, Cr compound, Mn compound, Co compound, Fe compound, Ni compound, Cu compound and Zn compound.

3. An oxygen absorbent according to claim 1, wherein said (A₁) unsaturated fatty acid and/or fatty oil containing unsaturated fatty acid, (B₁) transition metal and/or transition metal compound and (C₁) basic substance are so compounded that 0.01 part by weight or more of (B₁) and 0.1 part by weight or more of (C₁) are compounded with 100 parts by weight of (A₁).

8. An oxygen absorbent according to claim 1 wherein said unsaturated fatty acid contains at least 10 carbon atoms.

10. An oxygen absorbent according to claim 1 wherein said unsaturated fatty acid is at least one compound selected from the group consisting of Tohaku acid, linderic acid, tsuzuic acid, oleic acid, linoleic acid, linolenic acid, arachidonic acid, parinaric acid, dimer acid, ricinoleic acid, and the like.

13. An oxygen absorbent according to claim 1 wherein said oxygen absorbent includes a solid material resulting from the reaction of said unsaturated fatty acid and said basic substance.

4. An oxygen absorbent comprising:

(A₂) one member or a mixture of two or more members selected from unsaturated fatty acid compounds including unsaturated fatty acids, esters of unsaturated fatty acids and metallic salts of unsaturated fatty acids,

(B₂) a basic substance which is an alkaline earth metal compound of at least one of an oxide, hydroxide, carbonate, bicarbonate, silicate, phosphate or organic acid, and

(C₂) an adsorbent.

5. An oxygen absorbent according to claim 4, wherein said unsaturated fatty acid compound is a metallic salt of an unsaturated fatty acid.

7. An oxygen absorbent according to claim 4, wherein (A₂) one member or a mixture of two or more members selected from unsaturated fatty acid compounds including unsaturated fatty acids, esters of unsaturated fatty acid and metallic salts of unsaturated fatty acid, (B₂) basic substance and (C₂) adsorbent are so compounded that 0.1 to 1,000 parts by weight of (B₂) and 50 to 2,000 parts by weight of (C₂) are compounded with 100 parts by weight of (A₂).

9. An oxygen absorbent according to claim 4 wherein said unsaturated fatty acid contains at least 10 carbon atoms.

11. An oxygen absorbent according to claim 4 wherein said unsaturated fatty acid compound is at least one unsaturated fatty acid or metal salt thereof selected from the group consisting of Tohaku acid, linderic acid, tsuzuic acid, oleic acid, linoleic acid, linolenic acid, arachidonic acid, parinaric acid, dimer acid, ricinoleic acid, and the like.

12. An oxygen absorbent according to claim 4 wherein said at least one unsaturated fatty acid compound is at least one unsaturated fatty acid, an ester thereof, or a metal salt thereof obtained from the group consisting of linseed oil, soybean oil, tung oil, rice bran oil, sesame oil, tall oil, cotton seed oil, rape seed oil, and the like.

14. An oxygen absorbent according to claim 4 wherein said oxygen absorbent includes a solid material resulting from the reaction of said unsaturated fatty acid and said basic substance.

15. An oxygen absorbent according to claim 4 wherein said absorbent (C₂) comprises silica gel, activated alumina, or active charcoal.

6. An oxygen absorbent according to claim 6, wherein said metallic salt of an unsaturated fatty acid is an alkaline earth metal salt, alkali metal salt, transition metal salt or aluminum salt of an unsaturated fatty acid derived from an animal or vegetable oil.