Sealant product, laminate thereof, and pneumatic tire constructed therewith

• US 4,913,209 A
• Filed: 08/03/1987
• Issued: 04/03/1990
• Est. Priority Date: 01/22/1985
• Status: Expired due to Term

• Current Assignee: Michelin Recherche et Technique SA (Compagnie Generale DES Etablissements Michelin SCA)
• Original Assignee: Uniroyal Goodrich Tire Co. (Compagnie Generale DES Etablissements Michelin SCA)
• Inventors: Hong, Sung W., Cangelosi, Philip J.
• Primary Examiner(s): Ball, Michael W.
• Assistant Examiner(s): Wilber, Gregory J.
• Application Number:
  US07/080,842
• Time in Patent Office: 974 Days
• Field of Search: 152/501-507, 152/510, 152/516, 152/521, 152/511, 152/512, 156/115, 428/912
• US Class Current: 152/504
• CPC Class Codes: B29C 73/163 Sealing compositions or agents, e.g. combined with propellant agents
• CPC Class Codes: B29C 73/20 the article material only consisting in part of a deformable sealing material
• CPC Class Codes: B29D 2030/0686 Incorporating sealants on or into tyres not otherwise provided for; auxiliary operations therefore, e.g. preparation of the tyre
• CPC Class Codes: B29D 2030/069 through the use of a cylindrical support, e.g. a drum
• CPC Class Codes: B29D 2030/0695 the sealant being in the form of one wide strip, e.g. a patch
• CPC Class Codes: B29D 30/0685 Incorporating auto-repairing or self-sealing arrangements or agents on or into tyres auto-repairing or self-sealing arrangements or agents B29C73/16; puncture preventing arrangements B60C19/12
• CPC Class Codes: B29L 2030/00 Pneumatic or solid tyres or parts thereof conveyor belts B29L2031/7092; drive belts B29L2031/7094; fourdrinier belts B29L2031/733
• CPC Class Codes: B60C 19/122 disposed inside of the inner liner
• CPC Class Codes: C08C 19/08 Depolymerisation
• CPC Class Codes: C08K 5/01 Hydrocarbons C08K5/0091 takes precedence
• CPC Class Codes: C08L 15/00 Compositions of rubber derivatives C08L11/00, C08L13/00 take precedence
• CPC Class Codes: C08L 21/00 Compositions of unspecified rubbers
• CPC Class Codes: C08L 2207/324 Liquid component is low molecular weight polymer
• CPC Class Codes: C08L 23/16 Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
• CPC Class Codes: C08L 23/22 Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefins
• CPC Class Codes: C08L 25/04 Homopolymers or copolymers of styrene
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 2666/08 Homopolymers or copolymers according to C08L7/00 - C08L21/00; Derivatives thereof
• CPC Class Codes: C08L 29/04 Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
• CPC Class Codes: C08L 7/00 Compositions of natural rubber
• CPC Class Codes: C09J 121/00 : Adhesives based on unspecified rubbers
• CPC Class Codes: C09J 123/16 : Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
• CPC Class Codes: C09J 123/22 : Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefines
• CPC Class Codes: C09J 7/241 : Polyolefin, e.g.rubber
• CPC Class Codes: C09J 7/383 : Natural or synthetic rubber
• CPC Class Codes: Y10T 152/10684 : On inner surface of tubeless tire

Abstract

A carcass for a self-sealing pneumatic tire is constructed by starting with an extruded thin flat strip of puncture sealant both surfaces of which are detackified. The strip is place on a building drum and its upper surface is wiped clean so that an inner liner may be adhered to it. Thereafter, the carcass is conventionally completed with superimposed successive layers of belts, and tread along with bead rings, etc. The carcass is then cured in a conventional curing press so that the sealant is cured by contact with the curing bladder. The curing sealant is not restrained in any way, but does not flow. Alternatively, a laminate of the sealant is formed with the inner liner, with only the exposed surface of the sealant detackified so that it adheres neither to the building drum nor to the curing bladder. The detackifier remains on the sealant. The recipe for this effective sealant product requires a ratio of high molecular weight elastomer to low molecular weight elastomer greater than 1; also, that there be at least as much, by weight processing aid as there is high mol wt elastomer. Such a recipe has a room temperature peak Mooney viscosity above 70, and, after curing, a peak Mooney viscosity at 150° F. in the range above 15 but below 30. A combination of homogenizer and tackifier facilitates maintaining the necessary viscosity of the uncured sealant recipe. The tire provides excellent self-sealing results.

Claims

1. A self-sealing pneumatic tire having an inner liner and a substantially fully cured generally flat, bare layer of puncture sealant in which all of a curative is used up to cure the sealant having high molecular weight to low molecular weight elastomers present in a weight ratio from greater than 1, to 10, and more processing aid than there is high molecular weight elastomer, so as to have before curing a peak Mooney viscosity at room temperature in the range from above 70 to about 110, said tire and sealant cured in a curing process, said cured sealant being adhered to at least a portion of said inner liner with edges of said sealant smoothly blended into the sidewalls of said tire without the sealant being restrained by any external restraining means, said cured sealant having its radially inward surface coated with a detackifier which is not a self-supporting film but remains on said surface after it is contacted with a curing bladder, said cured sealant having a peak Mooney viscosity at 150°

F. in the range above 15 but below 30, which viscosity is high enough to negate flow of the sealant at a temperature up to 200°

F. and vehicle speeds up to 70 mph, on which vehicle the tire is mounted, yet low enough to permit a puncturing object when withdrawn, to draw sufficient sealant into the puncture it causes, so as to seal the puncture.

2. The tire of claim 1 wherein said cured sealant has a thickness in the range from about 0.1 inch to about 0.25 inch overlying the inner surface of the tread region of said tire.

3. The tire of claim 1 wherein said processing aid is selected from the group consisting of a tackifier and a homogenizer, and there is more homogenizer than tackifier.

4. The tire of claim 1 wherein said high molecular weight elastomer has a Mooney viscosity of from 20 to 160 ML-4 at 212°

F., the low molecular weight elastomer is a liquid rubber having a Brookfield viscosity at 150°

F. of from 20,000 to 2,000,000 cps, and the curing agent is selected from the following, present in the amounts recited;

from more than 0.5 to 2.0 parts of sulfur or sulfuryielding curative;

from more than 0.5 to 2.0 parts of quinoid curative;

from 0.1 to 1.0 part of a free radical generating curative; and

,

from 2 to 10 parts of polyisocyanate curative.

5. The tire of claim 4 wherein the liquid rubber is heat depolymerized natural rubber.

6. The tire of claim 4 wherein the low molecular weight elastomer is selected from the group consisting of liquid cis-isoprene, liquid polybutadiene, liquid polybutene, liquid ethylene-propylene-non-conjugated diene terpolymer rubber, and liquid isobutylene-isoprene copolymer rubber.

7. The tire of claim 4 wherein the high molecular weight elastomer is selected from the group consisting of conjugated diolefin homopolymer rubbers, copolymers of a major proportion of a conjugated diolefin with a minor proportion of a copolymerizable monoethylenically unsaturated monomer, copolymers of isobutylene with a small amount of isoprene, ethylene-propylene-nonconjugated diene terpolymers, and saturated elastomers.

8. The tire of claim 3 wherein said tackifier is selected from the group consisting of a rosin ester, aliphatic petroleum hydrocarbon resin, polyterpene resin derived from alpha-pinene, beta-pinene, resins made from styrene and related monomers, resins made from dicyclopentadiene, and, resins from the reaction of a mineral oil purification residue with formaldehyde and with nitric acid catalyst.

9. The tire of claim 4 wherein said free radical generating catalyst is an aromatic peroxide.

10. The tire of claim 1 wherein said detackifier is poly(vinyl alcohol).