Modified composite electrodes with renewable surface for electrochemical applications and method of making same

• US 4,933,062 A
• Filed: 03/07/1989
• Issued: 06/12/1990
• Est. Priority Date: 03/07/1989
• Status: Expired due to Fees

• Current Assignee: University of Connecticut (State of Connecticut)
• Original Assignee: University of Connecticut (State of Connecticut)
• Inventors: Creasy, Kenneth E., Shaw, Brenda R.
• Primary Examiner(s): Niebling, John F.
• Assistant Examiner(s): GORGOS, KATHRYN L
• Application Number:
  US07/320,233
• Time in Patent Office: 462 Days
• Field of Search: 204/290 R, 204/291, 204/292, 204/294, 204/280, 429/42, 429/43
• US Class Current: 204/291
• CPC Class Codes: G01N 27/30 Electrodes, e.g. test electrodes; Half-cells G01N27/414 takes precedence
• CPC Class Codes: G01N 27/38 Cleaning of electrodes

Abstract

Renewable modified composite electrodes for electrochemical application are provided by homogeneous structure of a conductive filler disposed in a polymeric matrix or binder containing a modifier in the polymer chain. The modifier provides distinctive characteristics of electroactivity, inclusion, acidic/basic, complexing/chelating or electrocatalysis to the surface of the electrode in a solution. After use, the electrode may be renewed by removing a surface portion and thereby exposing a fresh portion of the homogeneous structure.

Claims

1. A self-supporting renewable modified composite electrode for electrochemical applications comprising substantially homogeneous structure of a composition consisting of:

(a) 1-99 percent by weight of a non-conductive polymeric matrix having a polymer-chain in which a modifier is dispersed and

(b) 1-99 percent by weight of a conductive filler dispersed throughout said matrix and sufficient to provide electrical conductivity in the electrode, said modifier providing to said electrode distinctive properties selected from the group consisting of electroactivity, inclusion, acidic/basic, complexing/chelating, and electrocatalysis, said body being formed by polymerization of a resinous composition with said filler dispersed therein, said electrode being homogeneous throughout its cross section so that the electrode is renewable by removal of a surface portion to expose a fresh portion thereof.

2. The electrode in accordance with claim 1 wherein said modifier is copolymerizable with a polymerizable monomer to form said polymeric matrix.

3. The electrode in accordance with claim 1 wherein said modifier is a cross linking agent cross linked with a polymeric substrate to form said polymeric matrix.

4. The electrode in accordance with claim 1 wherein said modifier is non-conductive.

5. The electrode in accordance with claim 1 wherein said modifier exhibits such properties only upon application of a potential to said electrode.

6. The electrode in accordance with claim 1 wherein said modifier exhibits properties which will enable measurement of the potential of a solution in which immersed at zero current.

7. The electrode in accordance with claim 1 wherein said modifier exhibiting electroactive properties is selected from the group consisting of organic compounds polymers, and metallo-organic compounds.

8. The electrode in accordance with claim 1 wherein said modifier is one exhibiting inclusion properties and is adapted to incorporate species from a solution in which immersed and which is selected from the group which will produce polymers with ion exchange and coordinating agent properties.

9. The electrode in accordance with claim 1 wherein said modifier is non-conductive and enhances electroactivity upon application of a potential to the electrode in a solution.

10. The electrode in accordance with claim 1 wherein said polymeric matrix comprises 80-95 percent by weight of the composite electrode.