Method for producing black colored steel strip

• US 4,935,111 A
• Filed: 04/25/1989
• Issued: 06/19/1990
• Est. Priority Date: 04/28/1988
• Status: Expired due to Fees

• Current Assignee: Kawasaki Steel Corporation (JFE Holdings Incorporated)
• Original Assignee: Kawasaki Steel Corporation (JFE Holdings Incorporated)
• Inventors: Suzuki, Sachiko, Totsuka, Nobuo, Kikuchi, Katsuhei, Kurisu, Takao
• Primary Examiner(s): TUFARIELLO, THOMAS
• Application Number:
  US07/343,074
• Time in Patent Office: 420 Days
• Field of Search: 204/28, 204/35.1, 204/42, 204/56.1
• US Class Current: 205/141
• CPC Class Codes: C25D 11/00 Electrolytic coating by surface reaction, i.e. forming conversion layers
• CPC Class Codes: C25D 11/34 of metals or alloys not provided for in groups C25D11/04 - C25D11/32
• CPC Class Codes: C25D 5/48 After-treatment of electroplated surfaces

Abstract

A black colored steel strip having improved degree of blackness and uniform appearance is prepared by subjecting a Zn-Ni alloy plated steel substrate to anodic electrolysis or alternating current electrolysis in an electrolyte solution containing at least one member selected from the group consisting of hydroxide, sulfate, and chloride of sodium, potassium, or nickel; nitrate ion; and at least one member selected from an inhibitor and a complexing agent.

Claims

1. A method for producing a black colored strip wherein a Zn-Ni plated steel strip is subjected to an electrolysis in an electrolyte solution containing 75 to 200 g/l of at least one member selected from the group consisting of hydroxide, sulfate, and chloride of sodium, potassium, or nickel;

2 to 100 g/l of nitrate ion; and

at least one member selected from an inhibitor and a complexing agent in an amount sufficient to prevent corrosion products from being deposited on the steel strip.

2. The method according to claim 1 wherein said electrolysis is anodic electrolysis.

3. The method according to claim 1 wherein said electrolysis is alternating current electrolysis.

4. The method according to claim 1 wherein said inhibitor is at least one member selected from the group consisting of inhibitors primarily comprising a nitrogen compound, a sulfur compound, an amine, or a halogen compound.

5. The method according to claim 1 wherein said complexing agent is at least one member selected from the group consisting of citric acid, EDTA, oxalic acid, and tartaric acid.

6. The method according to claim 1 wherein said inhibitor and/or said complexing agent is added to said electrolyte solution to a total amount of about 0.001 to 100 g/l.