Solar control layered coating for glass windows

• US 4,965,121 A
• Filed: 09/01/1988
• Issued: 10/23/1990
• Est. Priority Date: 09/01/1988
• Status: Expired due to Term

• Current Assignee: Applied Films Corp. (Applied Materials Incorporated)
• Original Assignee: BOC Group Pty Limited (Linde Plc)
• Inventors: Young, Paul I., Wolfe, Jesse D.
• Primary Examiner(s): Robinson, Ellis P.
• Assistant Examiner(s): Turner, Archene A.
• Application Number:
  US07/239,590
• Time in Patent Office: 782 Days
• Field of Search: 428/426, 428/432, 428/689, 428/701, 428/212, 428/213, 428/220, 350/1.6, 350/1.7, 350/164, 350/166
• US Class Current: 428/213
• CPC Class Codes: B32B 17/10174 Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
• CPC Class Codes: B32B 2307/40 having particular optical properties light or UV resistant B32B2307/71
• CPC Class Codes: B32B 2605/006 Transparent parts other than made from inorganic glass, e.g. polycarbonate glazings
• CPC Class Codes: B32B 7/023 Optical properties
• CPC Class Codes: C03C 17/36 at least one coating being a metal
• CPC Class Codes: C03C 17/3613 Coatings of type glass/inorganic compound/metal/inorganic compound/metal/other
• CPC Class Codes: C03C 17/3626 one layer at least containing a nitride, oxynitride, boronitride or carbonitride
• CPC Class Codes: C03C 17/3639 Multilayers containing at least two functional metal layers
• CPC Class Codes: C03C 17/3642 the multilayer coating containing a metal layer
• CPC Class Codes: C03C 17/366 Low-emissivity or solar control coatings
• CPC Class Codes: C03C 17/3681 the multilayer coating being used in glazing, e.g. windows or windscreens
• CPC Class Codes: G02B 1/10 Optical coatings produced by application to, or surface treatment of, optical elements G02B1/08 takes precedence
• CPC Class Codes: G02B 5/282 reflecting for infrared and transparent for visible light, e.g. heat reflectors, laser protection
• CPC Class Codes: Y10T 428/24942 including components having same physical characteristic in differing degree
• CPC Class Codes: Y10T 428/2495 Thickness [relative or absolute]

Abstract

A five-layer coating, commonly called a "stack", for glass windows in order to control the proportion of solar radiation permitted to pass through the window, the remainder being reflected by the coating, while maintaining a desired visible light characteristic transmission. Particularly, the technique is applied to vehicle glass windows, such as truck and automobile windshields, where the amount of solar radiation allowed to pass into the vehicle through the window is minimized within the constraints of maintaining visible light transmission above a certain legal level. The characteristics of the coating are also selected for visible light reflected from the window to the outside to be a substantially neutral color, highly desirable for the overall appearance of trucks and automobiles.

Claims

1. A solar control glass coating having a substantially neutral visible reflected color, comprising:

a first layer of dielectric material,

a second layer, of partially reflective metallic material,

a third layer, of dielectric material,

a fourth layer, of partially reflective metallic material.

a fifth layer, of dielectric material, and

each of said first, third and fifth dielectric layers consisting of a substantially transparent dielectric material having a refractive index within a range of from 1.7 to 2.7, said first and firth layers having substantially the same optical thickness that is substantially within a range of 33-45 percent of the optical thickness of said third layer, one of said second or fourth layers has a thickness substantially within the range of from 75 to less than 100 percent of the other of the second or fourth layer.

8. The combination according to any one of claim 1-4, 5, 6, inclusive, wherein one of the second or fourth layers has a thickness that is less than substantially 80 percent of the thickness of the other.

9. The combination according to any one of claims 1-4, 5, 6, inclusive, wherein the dielectric materials of said first, third and fifth layers are selected from the group of oxides of zinc, titanium, tantalum, tin, indium, bismuth, magnesium, an alloy of any of the foregoing materials, and nitrides of silicon.

10. The combination according to any one of claims 1-4, 5, 6, inclusive, wherein the second and fourth layers are made of reflective metallic materials chosen from the group of silver, palladium, and platinum.

11. The combination according to any of claims 1-4, 5, 6, inclusive, wherein each of the first and fifth coating layers has an optical thickness lying substantially within the range of from 600 to 1,000 Angstroms and said third layer has a thickness substantially within the range of from 1700 to 2200 Angstroms.

12. The combination according to claim 1 wherein said coating is provided on a piece of glass that is part of a moving vehicle.

15. A combination according to any one of claims 1-4, 15-17, inclusive, where in use the solar control coating is oriented so that the fourth layer is positioned further from the sun than the second layer and the thickness of the fourth layer is less than that of the second layer.

2. A vehicle windshield made of at least one sheet of glass with a solar control coating attached to it, wherein the entire structure has a visible transmission of from 70 to 73 percent of light incident upon it within a weighted Illuminant A weighted visible wavelength distribution and has a substantially neutral reflective visible light color, said coating comprising:

a first layer, of dielectric material,

a second layer, of partially reflective metallic material,

a third layer, of dielectric material,

a fourth layer, of partially reflective metallic material,

a fifth layer, of dielectric material,

each of said first, third and fifth dielectric layers being made of a substantially transparent dielectric material having a refractive index within a range of from 1.7 to 2.7, said first and fifth layers having substantially the same optical thickness that is substantially within a range of 33-45 percent of the optical thickness of said third layer, and

said fourth layer being substantially within the range of from 65 to 85 percent of the thickness of said second layer.

13. The combination according to claim 2 wherein the windshield is characterized by having a ratio of the amount of solar radiation reflected to that transmitted through the windshield being substantially within the range of 0.8 to 1.0.

3. A vehicle windshield made of at least one sheet of glass with a solar control coating attached to it, wherein the entire structure has a visible transmission of from 75 to 77 percent of light incident upon it within a weighted Illuminate A weighted visible wavelength distribution and has a substantially neutral reflective visible light color, said coating comprising:

a first layer, of dielectric material,

a second layer, of partially reflective metallic material,

a third layer, of dielectric material.

a fourth layer, of partially reflective metallic material,

a fifth layer, of dielectric material, and

each of said first, third and fifth dielectric layers being made of a substantially transparent dielectric material having a refractive index within a range of from 1.7 to 2.7, said first and fifth layers having substantially the same optical thickness that is substantially within a range of 33-45 percent of the optical thickness of said third layer, one of said second or fourth layers has a thickness substantially within the range of from 75 to less than 100 percent of the other second or fourth layer.

4. A laminated vehicle windshield structure, comprising:

a first sheet of glass, forming an outside of the windshield structure,

a solar control coating, including,

a first layer of dielectric material,

a second layer, of partially reflective metallic material,

a third layer, of dielectric material,

a fourth layer, of partially reflective metallic material,

a fifth layer, of dielectric material,

each of said first, third and fifth dielectric layers being made of a substantially transparent dielectric material having a refractive index within a range of from 1.7 to 2.7, said first and fifth layers having substantially the same optical thickness that is substantially within a range of 33-45 percent of the optical thickness of said third layer, and

either of the second or fourth layers being substantially within the range of from 65 to 85 percent of the thickness of the other,

a laminant material layer, and

a second glass sheet forming an inside of the windshield structure.

5. A solar control glass coating having a substantially neutral visible reflected color, comprising:

a first layer, of dielectric material,

a second layer, of partially reflective metallic material,

a third layer, of dielectric material,

a fourth layer, of partially reflective metallic material,

a fifth layer, of dielectric material, and

each of said first, third and fifth dielectric layers consisting of a substantially transparent dielectric material having a refractive index within the range of from 1.7 to 2.7, said first and fifth layers having substantially the same optical thickness that is substantially within the range of 33-45 percent of the optical thickness of said third layer, one of said second or fourth layers has a thickness substantially within the range of from 65 to 85 percent of the other of the second or fourth layer.

6. A vehicle windshield made of at least one sheet of glass with a solar control coating attached to it, wherein the entire structure has a visible transmission of from 75 to 77 percent of light incident upon it within a weighted Illuminant A weighted visible wavelength distribution and has a substantially neutral reflective visible light color, said coating comprising:

a first layer, of dielectric material,

a second layer, of partially reflective metallic material,

a third layer, of dielectric material,

a fourth layer, of partially reflective metallic material,

a fifth layer, of dielectric material, and

each of said first, third and fifth dielectric layers consisting of a substantially transparent dielectric material having a refractive index within the range of from 1.7 to 2.7, said first and fifth layers having substantially the same optical thickness that is substantially within the range of 33-45 percent of the optical thickness of said third layer, one of said second or fourth layers has a thickness substantially within the range of from 65 to 85 percent of the other of the second or fourth layer.

7. The combination according to any one of claims wherein the optical thickness of the first and fifth layers is less than 40 percent of the optical thickness of said third layer.

14. A combination of window glass and a solar control coating, said coating comprising:

a first layer, of substantially optically transparent dielectric material,

a second layer, of partially reflective metallic material,

a third layer, of substantially optically transparent dielectric material,

a fourth layer, of partially reflective metallic material,

a fifth layer, of substantially optically transparent dielectric material, and

said first and fifth layers each having an optical thickness that is less than about forty percent of the optical thickness of said third layer, and one of said second and fourth layers having a thickness that is one of said second or fourth layers has a thickness substantially within the range of from 65 to 85 percent than that of the other of the second or fourth layer, said layer thicknesses being adjusted to result in the combination having a transmission of about seventy percent or more of light within an Illuminant A weighted visible wavelength distribution and a substantially neutral reflective visible light color.