Battery separator with integral thermal fuse

• US 4,973,532 A
• Filed: 04/05/1989
• Issued: 11/27/1990
• Est. Priority Date: 04/05/1989
• Status: Expired due to Term

• Current Assignee: Celgard LLC (Asahi Kasei Corporation)
• Original Assignee: Hoechst Celanese Corporation (Sanofi )
• Inventors: Fleming, Robert J., Langford, Ellen A., Taskier, Henry T., Mullins, Steven M.
• Primary Examiner(s): NOT, DEFINED
• Application Number:
  US07/333,662
• Time in Patent Office: 601 Days
• Field of Search: 429/62, 429/145
• US Class Current: 429/62
• CPC Class Codes: H01M 10/4235 Safety or regulating additives or arrangements in electrodes, separators or electrolyte H01M10/4242 takes precedence
• CPC Class Codes: H01M 2200/00 Safety devices for primary or secondary batteries
• CPC Class Codes: H01M 2200/10 Temperature sensitive devices
• CPC Class Codes: H01M 50/489 Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

A battery separator includes a porous substrate and a thermal fuse material adhered to at least one surface of said porous substrate. The thermal fuse material is adhered to the substrate surface in a predetermined geometric array thereupon so as to establish open areas of the at least one substrate surface to thereby allow ionic migration therethrough. The thermal fuse material forming the geometric array on the substrate surface may itself define open pores to further facilitate such ionic migration. The thermal fuse material melts at or near a predetermined threshold temperature so that the substrate'"'"'s permeability irreversibly becomes significantly decreased and thus interrupts the chemical reaction in an electrochemical battery. In such a manner, batteries of improved safety may be provided using the separators of this invention.

Claims

1. A battery separator comprising a porous substrate and a thermal fuse material adhered to at least one surface of said porous substrate in a predetermined geometric array thereupon so as to establish open areas of said at least one surface.

2. A battery separator as in claim 1, wherein said geometric array of thermal fuse material is porous.

3. A battery separator as in claim 1, wherein said predetermined geometric array is a plurality of discrete regions each consisting essentially of said thermal fuse material and aligned in a number of rows.

4. A battery separator as in claim 3, wherein said regions of one of said rows are staggered with respect to said regions of adjacent ones of said rows.

5. A battery separator as in claim 1, wherein said open areas established by said predetermined geometric array of thermal fuse material are at least about 30 percent of said substrate surface.

6. A battery separator as in claim 1, wherein said porous substrate is a film or a fabric.

7. A battery separator as in claim 1, wherein said porous substrate is an open-celled, microporous polymeric film.

8. A battery separator as in claim 7, wherein said film is a polyolefin.

9. A battery separator as in claim 8, wherein said polyolefin is polyethylene or polypropylene.

10. A battery separator as in claim 1, wherein said thermal fuse material is selected from the group consisting of waxes and thermoplastics.

11. A battery separator as in claim 10, wherein said thermoplastics are particulate.

12. A battery separator comprising a porous substrate, and thermal fuse means integrally associated with said porous substrate for significantly decreasing permeability of said porous substrate in response to exposure to a predetermined threshold temperature below a melting temperature of said substrate, wherein said thermal fuse means includes a material meltable substantially at said threshold temperature and adhered to at least one surface of said substrate in the form of a geometric pattern which establishes regions on said at least one surface covered by said meltable material, and open areas on said substrate surface uncovered by said meltable material.

13. A battery separator as in claim 12, wherein said meltable material in the form of said geometric array is porous.

14. A battery separator as in claim 12 or 13, wherein said predetermined geometric array is a plurality of discrete regions each consisting essentially of said thermal fuse material and aligned in a number of rows.

15. A battery separator as in claim 14, wherein said regions of one of said rows are staggered with respect to said regions of adjacent ones of said rows.

16. A battery separator as in claim 12, wherein said open areas are at least about 30 percent of said at least one substrate surface.

17. A battery separator as in claim 12, wherein said porous substrate is a film or a fabric.

18. A battery separator as in claim 12, wherein said porous substrate is an open-celled, microporous polymeric film.

19. A battery separator as in claim 18, wherein said film is a polyolefin.

20. A battery separator as in claim 19, wherein said polyolefin is polyethylene or polypropylene.

21. A battery separator as in claim 12, wherein said thermal fuse material is selected from the group consisting of waxes and thermoplastics.

22. A battery separator as in claim 21, wherein said thermoplastics are particulate.

23. In a battery comprising an anode, a cathode, and a separator interposed between said anode and cathode, the improvement wherein said separator includes a porous substrate and a thermal fuse material adhered to at least one surface of said porous substrate in a predetermined geometric array thereupon so as to establish open areas of said at least one substrate surface.

24. In a battery as in claim 23, wherein said open areas established by said predetermined geometric array of thermal fuse material are at least about 30 percent of said substrate surface.

25. In a battery as in claim 23, wherein said thermal fuse material adhered to said substrate in said predetermined geometric array is porous.

26. In a battery as in claim 23 or 25, wherein said predetermined geometric array is a plurality of discrete regions each consisting essentially of said thermal fuse material and aligned in a number of rows.

27. In a battery as in claim 26, wherein said regions of one of said rows are staggered with respect to said regions of adjacent ones of said rows.

28. In a battery as in claim 23, wherein said thermal fuse material is selected from the group consisting of waxes and particulate thermoplastics.

29. In a battery as in claim 23, wherein said porous substrate is a film or a fabric.

30. In a battery as in claim 23, wherein said porous substrate is an open-celled, microporous polymeric film.

31. In a battery as in claim 30, wherein said film is a polyolefin.

32. In a battery as in claim 31, wherein said polyolefin is polyethylene or polypropylene.

33. A method of fabricating a battery separator comprising applying a meltable thermal fuse material in a predetermined geometric pattern onto at least one surface of a porous substrate.

34. A method as in claim 33, wherein said meltable thermal fuse material is applied in the form of a plurality of discrete regions each consisting essentially of said thermal fuse material and aligned in a number of roWs.

35. A method as in claim 34, wherein said thermal fuse material is applied so that the regions of one of said rows are staggered with respect to the regions of adjacent ones of said rows.

36. A method as in claim 33, wherein said thermal fuse material is applied by supplying liquid thermal fuse material to a surface of a pattern roll, and then bringing said substrate into contact with said pattern roll so that said liquid thermal fuse material is transferred onto the substrate surface in the form of said geometric pattern.

37. A method as in claim 33, wherein said thermal fuse material is applied by overlaying said at least one surface with an apertured member which defines said predetermined geometric pattern, and then forcing liquid thermal fuse material through the apertures of said member so that the thermal fuse material is deposited onto said at least one surface in said predetermined geometric pattern.

38. A method as in claim 36 or 37, wherein said thermal fuse material is applied in the form of a liquid paste consisting essentially of particulate thermoplastic material in an inert carrier liquid.

39. A method as in claim 38, which further comprises removing the carrier liquid so that the particulate thermoplastic remains as a residue on said at least one surface.

40. A method as in claim 39, which further comprises drying the applied paste by subjecting the substrate with the applied paste thereon to elevated temperature sufficient to remove the carrier liquid so that the thermoplastic material remains as a residue on the substrate surface.

41. A method as in claim 40, wherein said step of drying the applied paste includes subjecting the separator to elevated temperature at least about 2°

C. below the melting point of the thermoplastic material for less than about one hour.

42. A method as in claim 40, wherein said step of drying the applied paste is practiced at a temperature which partially melts said particulate thermoplastic material.

43. A method as in claim 41, wherein the thermal fuse material is applied as an aqueous mixture which further consists essentially of at least one additive selected from surfactants, thickeners, and adhesive agents.

44. A method as in claim 36 or 37, wherein said thermal fuse material is applied in the form of a melt, the method further comprising allowing the melt to solidify on said at least one substrate surface.