Electrochromic devices comprising metal salts in an ion conductive material

• US 4,993,810 A
• Filed: 04/14/1989
• Issued: 02/19/1991
• Est. Priority Date: 04/14/1989
• Status: Expired due to Fees

• Current Assignee: Ford Motor Company
• Original Assignee: Ford Motor Company
• Inventors: Demiryont, Hulya
• Primary Examiner(s): LaRoche, Eugene R.
• Assistant Examiner(s): Lester, Evelyn A.
• Application Number:
  US07/338,261
• Time in Patent Office: 676 Days
• Field of Search: 350/357
• US Class Current: 359/265
• CPC Class Codes: G02F 1/1508 using a solid electrolyte
• CPC Class Codes: Y10S 359/90 Methods

Abstract

This invention is directed to an electrochromic device which comprises a colorable electrochromic matrix layer consisting essentially of certain metal salts and an ion conduction enhancer in an ion conductive material.

Claims

1. An electrochromic device comprising a substrate;

a first electrode layer provided on said substrate;

an electrochromic matrix material layer in contact with said first electrode member; and

a second electrode layer in contact with said electrochromic matrix material layer, at least one of said first and second electrode members being transparent, said electrochromic matrix material layer consisting essentially of a substantially uniform mixture of;

(i) a metal salt component selected from the group consisting essentially of halides, acetates, nitrates, sulfates, and phosphates of metals selected from the group consisting essentially of copper, cobalt, nickel, lead, rubidium, molybdenum and tin;

(ii) an ion conductive material component selected from a group consisting essentially of solid electrolytes and gel electrolytes; and

(iii) an ion conduction enhancer component selected from the group consisting essentially of lithium salts and sodium salts.

2. The device according to claim 1, wherein said metal salt is present in said electrochromic matrix material layer in an amount sufficient to provide a maximum thickness of between about 500 to 1000Å

of the metal of said metal salt on one of said first and second electrode members when a voltage is applied across said electrodes.

3. The device according to claim 1, wherein said first and second electrode members are individually selected from electrode material consisting essentially of doped or undoped (a) tin oxide, (b) indium oxide, (c) indium tin oxide, (d) zinc oxide, and (e) mixtures of any of them.

4. The device according to claim 1, wherein said solid ion conductive material is selected from polymeric electrolytes, and inorganic oxide electrolytes.

5. The device according to claim 1, wherein said lithium salt and said sodium salt are selected from compounds comprising nitrates and halides of these alkali metals.

6. The device according to claim 1, wherein said device further comprises a second substrate adjacent said second electrode member.

7. The device according to claim 6, wherein both of said substrates is transparent.

8. The device according to claim 1, wherein one of said first and second electrode members is a continuous layer and the other electrode member is a patterned layer.

9. The device according to claim 1, wherein one of said first and second electrode members is a continuous layer and the other electrode member is a sliding point or linear electrode.

10. The device according to claim 1, wherein said device further comprises a counter electrode positioned between one or said first and second electrode members and the adjacent surface of said electrochromic matrix material layer.

11. The device according to claim 1, utilized as a divider between interior portions of a vehicle.

12. The device according to claim 1, utilized as a sunroof or a moonroof.

13. The device according to claim 1, utilized as a vehicle window.

14. The device according to claim 1, utilized as an architectural window.

15. The device according to claim 1, utilized as a skylight or an interior building partition.

16. The device according to claim 1, utilized as a display device.

17. A method for making an electrochromic device, which method comprises:

providing a first electrode layer on a substrate;

Providing an electrochromic matrix material layer in contact with said first electrode member; and

providing a second electrode layer in contact with said electrochromic matrix material layer, at least one of said first and second electrode members being transparent, said electrochromic matrix material layer consisting essentially of a substantially uniform mixture of;

(i) a metal salt component selected from the group consisting essentially of halides, acetates, nitrates, sulfates, and phosphates of metals selected from the group consisting essentially of copper, cobalt, nickel, lead, rubidium, molybdenum and tin;

(ii) an ion conductive material component selected from a group consisting essentially of solid electrolytes and gel electrolytes; and

(iii) an ion conduction enhancer component selected from the group consisting essentially of lithium salts and sodium salts.