Coextruded multilayer foamed film for plastic container closures and process for manufacture

• US 5,000,992 A
• Filed: 06/01/1989
• Issued: 03/19/1991
• Est. Priority Date: 06/01/1989
• Status: Expired due to Fees

• Current Assignee: The Dow Chemical Company (Dow, Inc.)
• Original Assignee: The Dow Chemical Company (Dow, Inc.)
• Inventors: Kelch, Robert H.
• Primary Examiner(s): Seidleck, James
• Application Number:
  US07/359,826
• Time in Patent Office: 656 Days
• Field of Search: 428/36.6, 428/318.6, 428/318.8, 428/319.9, 428/213, 428/220, 428/516, 428/458, 215/347, 215/348, 215/224, 215/243
• US Class Current: 428/36.5
• CPC Class Codes: B29C 2791/007 Using fluid under pressure
• CPC Class Codes: B29C 48/08 flexible, e.g. films
• CPC Class Codes: B29C 48/09 Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels
• CPC Class Codes: B29C 48/10 flexible, e.g. blown foils
• CPC Class Codes: B29C 48/1472 at the die nozzle exit zone
• CPC Class Codes: B29C 48/21 the layers being joined at their surfaces
• CPC Class Codes: B29C 48/307 specially adapted for bringing together components, e.g. melts within the die
• CPC Class Codes: B29C 48/335 Multiple annular extrusion nozzles in coaxial arrangement, e.g. for making multi-layered tubular articles
• CPC Class Codes: B32B 2266/025 Polyolefin vinyl or acrylic copolymers B32B2266/0221, B32B2266/0242
• CPC Class Codes: B32B 2323/046 LDPE, i.e. low density polyethylene
• CPC Class Codes: B32B 2435/02 for containers
• CPC Class Codes: B32B 27/065 of foam
• CPC Class Codes: B32B 27/32 comprising polyolefins comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30
• CPC Class Codes: B32B 5/18 characterised by features of a layer of foamed material
• CPC Class Codes: Y10T 428/1376 Foam or porous material containing
• CPC Class Codes: Y10T 428/2495 Thickness [relative or absolute]
• CPC Class Codes: Y10T 428/249988 Of about the same composition as, and adjacent to, the void-containing component
• CPC Class Codes: Y10T 428/249993 Hydrocarbon polymer
• CPC Class Codes: Y10T 428/31681 Next to polyester, polyamide or polyimide [e.g., alkyd, glue, or nylon, etc.]
• CPC Class Codes: Y10T 428/31913 Monoolefin polymer

Abstract

A plastic container closure, such as a bottle cap liner or tamper evident seal, is formed from a coextruded multilayer foamed film. The coextruded multilayer foamed film has at least one solid film layer of a first polyolefin blend containing linear low density polyethylene, low density polyethylene, and, optionally high density polyethylene, and at least one foamed layer of a second polyolefin blend containing linear low density polyethylene, low density polyethylene, and optionally ethylene vinyl acetate. The multilayer foamed film may be coextruded using a blown film or cast film extrusion process under defined conditions. the coextruded multilayer foamed film may be laminated to other materials such as polyester film, thermoplastic adhesive films or metallic films and used as a plastic container closure, or may be applied as a liner to a plastic bottle cap.

Claims

1. A plastic container closure comprising a threaded or snap-on bottle cap and a liner of a 3-10 mil thick coextruded multilayer foamed film having at least one solid polyolefin film layer and at least one foamed polyolefin layer having an average cell size of less than 0.6 millimeters in length.

2. The plastic container closure of claim 1 wherein said solid polyolefin film layer is a first polyolefin blend containing linear low density polyethylene and low density polyethylene.

3. The plastic container closure of claim 2 wherein said first polyolefin blend comprises about 10-80% linear low density polyethylene, 10-60% low density polyethylene, and 0-50% high density polyethylene.

4. The plastic container closure of claim 3 wherein said foamed polyolefin layer is a second polyolefin blend containing linear low density polyethylene and low density polyethylene.

5. The plastic container closure of claim 4 wherein said second polyolefin blend comprises about 10-90% linear low density polyethylene, 10-90% low density polyethylene, 0-50% ethylene vinyl acetate, and 0-30% high density polyethylene.

6. A plastic container closure comprising a laminate of a 3-10 mil thick coextruded multilayer foamed film having at least one solid polyolefin film layer and at least one foamed polyolefin layer having an average cell size of less than 0.6 millimeters in length, the multilayer foamed film having a first and second surface and an adhesive joining said first surface of said multilayer foamed film to a polyester film and a metallic foil.

7. The plastic container closure of claim 6 further including a polyester film joined to said second surface of said multilayer foamed film with an adhesive.

8. A 3-10 mil thick coextruded multilayer foamed film suitable for use for a plastic container closure, said multilayer foamed film having at least one solid polyolefin film layer and at least one foamed polyolefin layer having an average cell size of less than 0.6 millimeters in length.

9. The multilayer foamed film of claim 8 wherein said solid polyolefin film layer is a first polyolefin blend containing linear low density polyethylene and low density polyethylene.

10. The multilayer foamed film of claim 9 wherein said first polyolefin blend comprises about 10-90% linear low density polyethylene, 10-60% low density polyethylene, and 0-50% high density polyethylene.

11. The multilayer foamed film of claim 10 wherein said foamed polyolefin layer is a second polyolefin blend containing linear low density polyethylene and low density polyethylene.

12. The multilayer foamed film of claim 11 wherein said second polyolefin blend comprises about 10-90% linear low density polyethylene, 10-90% low density polyethylene, 0-50% ethylene vinyl acetate, and 0-30% high density polyethylene.

13. The multilayer foamed film of claim 12 wherein said first polyolefin blend comprises about 10-80% linear low density polyethylene, 10-60% low density polyethylene, and 0-50% high density polyethylene and said second polyolefin blend comprises about 40-75% linear low density polyethylene, 20-60% low density polyethylene, and 2-10% ethylene vinyl acetate.

14. The multilayer foamed film of claim 8 wherein said film is a two-ply one having one solid polyolefin film layer and one foamed polyolefin layer.

15. The multilayer foamed film of claim 14 wherein said solid polyolefin film layer comprises about 10-40% and said foamed polyolefin layer comprises about 90-60% of the total film thickness.

16. The multilayer foamed film of claim 8 wherein said film is a three-ply one having two outer solid polyolefin film layers and a middle foamed polyolefin layer.

17. The multilayer foamed film of claim 16 wherein each of said solid polyolefin film layers comprises about 5-20% and said foamed polyolefin layer comprises about 90-60% of the total film thickness.