In situ soil decontamination method and apparatus

• US 5,011,329 A
• Filed: 02/05/1990
• Issued: 04/30/1991
• Est. Priority Date: 02/05/1990
• Status: Expired due to Fees

• Current Assignee: Hrubetz Environmental Services Incorporated
• Original Assignee: Hrubetz Exploration Company
• Inventors: Nelson, Joseph M., Rau, Garland R.
• Primary Examiner(s): CORBIN, DAVID
• Application Number:
  US07/458,084
• Time in Patent Office: 449 Days
• Field of Search: 405/128, 405/129, 405/131, 405/258, 405/263, 166/250, 166/302, 166/303, 210/170, 210/747, 210/901
• US Class Current: 405/128.65
• CPC Class Codes: B09C 1/06 thermally
• CPC Class Codes: B09C 2101/00 In situ
• CPC Class Codes: E21B 36/008 using chemical heat generating means
• CPC Class Codes: E21B 43/086 Screens with preformed openings, e.g. slotted liners comprising porous materials E21B43/082
• CPC Class Codes: E21B 43/295 Gasification of minerals, e.g. for producing mixtures of combustible gases E21B43/243 takes precedence
• CPC Class Codes: E21B 43/30 Specific pattern of wells, e.g. optimising the spacing of wells
• CPC Class Codes: F23G 7/14 of contaminated soil, e.g. by oil
• CPC Class Codes: Y02E 20/12 Heat utilisation in combustion or incineration of waste

Abstract

Disclosed is in situ decontamination methods and apparatus for injecting a hot gas into boreholes formed in a contaminated soil area to vaporize the soil moisture and contaminants, and for collecting the vaporized contaminants at the surface of the soil. A burner heats pressurized gases and mixes the same with combustion gases for injection into the contaminated zone. A central collection system recovers the vaporized contaminants and couples such vapors to an on-site incinerator for disposal. Controlled heating of the injection gas is effective to sequentially remove different types of contaminants, as well as to provide in situ oxidation of other contaminants, while minimizing recondensation of the soil vapors. Wellbore casings are especially adapted for injecting the gas in predetermined patterns. In addition, a heater and incinerator assembly utilizes a single burner for both heating the dry gas and for incinerating the vapor contaminants.

Claims

1. A method for in situ decontamination of an earth site, comprising the steps of:

forming one or more wells in the contaminated site;

heating a gas;

pumping the heated gas down said well so that said gas permeates earth materials at the site and vaporizes earth moisture and contaminants therefrom;

controlling the gas temperature and injection rate to control recondensation of liquid ahead of a heat front; and

recovering vaporized contaminants at the surface of the site.

2. The method of claim 1, further including heating the gas in stages to first vaporize volatile components, and then raising the temperature of the gas to vaporize less volatile compounds.

3. The method of claim 1, further including reducing the temperature of the gas after the contaminants have been substantially removed to thereby cool the earth materials

4. The method of claim 3, further including injecting moisture into the well to restore moisture previously removed from the earth material at the site.

5. The method of claim 1, further including injecting the heated gas at a low pressure of less than an overburden pressure.

6. The method of claim 1, further including forcing the heated gas outwardly from at least one well in a predetermined pattern which is less than 360°

.

7. The method of claim 1, further including incinerating the recovered contaminants at the site.

8. The method of claim 7, further including employing a single heat source to heat the gas and to incinerate the contaminants.

9. The method of claim 1, further including forming between the wells a trench network having a common point for recovering the vaporized contaminants therefrom.

10. The method of claim 9, further including covering the contaminated site with an impervious material.

11. The method of claim 1, further including drilling the wells spaced apart a distance about the same as the depth of the wells.

12. The method of claim 1, further including pumping the gas into each well at substantially a constant rate, and monitoring a pressure of the gas to detect condensation of liquid in the earth material.

13. The method of claim 1, further including pumping the gas into each well at substantially a constant pressure, and monitoring the flow rate of the gas to detect condensation of liquid in the earth material.

14. The method of claim 1, further including initially pumping a low temperature gas into the earth material until a steady state flow rate is achieved, and then increasing the temperature of the gas to increase the porosity of the earth material.

15. The method of claim 14, further including increasing the temperature of the gas in increments over a period of time.

16. The method of claim 14, further including increasing the temperature of the gas by amounts which allow substantial gas flow through the earth material without substantial condensation of vapors in the earth material.

17. The method of claim 1, further including pumping a gas into the earth material, said gas being of the type which is not readily condensable.

18. The method of claim 1, further including monitoring the temperature at various areas of the earth site, and flooding surface areas of higher temperature with a liquid so that subsurface permeation of the heated gas is made more uniform.

19. A method for in situ decontamination of an earth material, comprising the steps of:

forming one or more wells in a contaminated site;

installing a casing in each said well so that a gas can be injected into the earth material from a bottom portion of the casing;

forming a surface trench network between each said well so that at least one central trench collection point is defined;

covering the contaminated site with an impervious material;

pumping a heated gas down each said casing so that the heated gas is injected outwardly therefrom into the earth material at the bottom portion of the casing;

forming a negative pressure at said central trench collection point for drawing vaporized contaminants from the surface of the contaminated site; and

disposing of the contaminants.

20. The method of claim 19, further including disposing of the contaminants by incinerating the contaminants at the site.

21. The method of claim 19, further including employing a heater-incinerator with a common flame to heat the gas and to incinerate the contaminants.

22. The method of claim 21, further including directing the incinerated contaminants upwardly in a chamber with a flue gas, and directing the compressed gas in an annulus surrounding the chamber downwardly in a counterflow manner.

23. The method of claim 19, further including heating a dry gas.

24. The method of claim 19, further including heating the gas to a temperature greater than about 212°

F.

25. The method of claim 19, further including forming a vertical pressure differential in the earth material for defining a vertical flow path for vapor contaminants.

26. The method of claim 19, further including driving plural temperature probes into the earth material to monitor the temperature at different areas, and wetting surface areas of higher temperature so that subsurface permeation of the heated gas is made more uniform.

27. A method for in situ decontamination of an earth material, comprising the steps of:

pumping a gas down a borehole formed in a contaminated site, with a first pressure sufficient to purge the borehole of earth material liquid;

reducing the pressure of the gas;

pumping a heated gas down the borehole for an extended period of time to vaporize volatile contaminants in the earth material of the site;

increasing the temperature of the heated gas after the volatile contaminants have been vaporized to vaporize less volatile contaminants; and

collecting the vaporized contaminants at the surface of the site for disposal thereof.

28. The method of claim 27, further including increasing the temperature of the gas as the earth material liquid is removed.

29. The method of claim 28, further including raising the temperature of the gas to provide slow oxidation of the in situ contaminants.

30. The method of claim 27, further including lowering the temperature of the gas after removal of the contaminants to thereby lower the temperature of the site earth material.

31. The method of claim 30 further including injecting moisture in the earth material after contamination removal by injecting cool moist air into the borehole.

32. A method for in situ decontamination of an earth material, comprising the steps of:

defining a circumferential boundary of a contaminated site;

forming wells at spaced apart locations proximate said boundary; and

installing a gas directional casing in each said boundary well so that when a gas is injected into said casing, the gas substantially permeates the contaminated site defined by the boundary and is not substantially permeated in an area external to the boundary.

33. The method of claim 32, further including forming at least one well within the boundary which allows permeation of gas in the earth material in a 360°

pattern therearound.

34. The method of claim 32, further including forming ones of said boundary wells so as to allow permeation of the gas in the earth material substantially in a 180°

pattern, or less, around said ones of wells.

35. The method of claim 32, further including forming ones of said boundary wells for allowing the permeation of gas in the earth material substantially in a pattern of about b 90°

around said ones of wells.

36. The method of claim 32, further including injecting a hot dry gas down each well.

37. A method for in situ decontamination of an earth material, comprising the steps of:

forming a gas injection well in a contaminated zone of the earth material;

injecting a gas in the well and slowly raising the pressure to displace liquid water occluded in the earth pore space surrounding the well; and

increasing the temperature of the gas injected into the well to evaporate the occluded water and increase the permeability of the earth material, said temperature increase being carried out slowly so that evaporated water is not recondensed in an area defined by a heat front to an extent that recondensed liquid substantially reduces the permeation of the gas therethrough.

38. The method of claim 37, further including monitoring the injection rate of the gas to determine if flooding in the heat front is occurring.

39. The method of claim 37, further including monitoring the pressure of the injected gas to determine if flooding in the heat front is occurring.

40. The method of claim 37, further including increasing the temperature of the gas once a substantial amount of the liquid has been removed from the earth material vaporize contaminants in the earth material.

41. The method of claim 37, further including gravity draining liquid from the well prior to injection of the gas.

42. The method of claim 37, further including increasing the gas temperature after a steady state gas flow has been established and the occluded water substantially removed.

43. The method of claim 37, further including monitoring the temperature of the earth material, and for higher temperature areas, decreasing the earth material permeability by surface irrigating the higher temperature earth material area so that horizontal permeation below the irrigated area is facilitated.

44. A system for use in decontamination of an earth site having at least one borehole, comprising in combination:

a burner for heating a gas;

a compressor for forcing the gas through said burner so as to be heated and injected into the borehole;

a vapor collection system for collecting vapor contaminants from the surface of the site; and

an incinerator fired by said burner and connected to said vapor collection system for incinerating the contaminants.

45. The decontamination system of claim 44, wherein said incinerator includes a thermal conducting chamber for carrying incinerated contaminants, and an annulus around said chamber for circulating said gas around said conduit and heating said gas.

46. The decontamination system of claim 45, further including a compressor for forcing said gas in said chamber annulus in a direction opposite to the flow of incinerated contaminants in said chamber.

47. The decontamination system of claim 44, further including means for supplying a gas to the burner for combustion, and for injecting the combusted gas in the borehole.

48. The decontamination system of claim 44, further including means for a fuel to the vapor contaminants for incineration in said burner.

49. The decontamination system of claim 44, wherein said burner is adapted for heating a pressurized gas.

50. The decontamination system of claim 44, further including means for monitoring the temperature at various areas of the earth site, and an irrigation system for selectively irrigating areas of temperature higher than other areas of the earth site.

51. The decontamination system of claim 50, wherein said irrigation system is of a surface wetting type.

52. A system for use in decontamination of an earth site having at least one borehole, comprising in combination:

a burner for heating a pressurized gas;

a compressor for supplying a compressed gas to said burner;

an inlet to said burner for supplying vapor contaminants to said burner for combustion thereof;

said burner having a mixing chamber for mixing heated and pressurized gases with combustion gases;

an outlet of said burner, said outlet being coupled to said borehole for injecting therein heated combustion gases; and

a recovery system for recovering contaminants vaporized by said injected gases, said recovery system being coupled to said burner inlet.

53. The system of claim 52, wherein said burner includes a single flame unit for heating said gases and for incinerating the recovered contaminants.