Devolatilization of liquid composition containing polymer and volatile constituents

• US 5,024,728 A
• Filed: 08/28/1989
• Issued: 06/18/1991
• Est. Priority Date: 08/29/1988
• Status: Expired due to Term

• Current Assignee: Dainippon Ink and Chemicals Incorporated
• Original Assignee: Dainippon Ink and Chemicals Incorporated
• Inventors: Furukawa, Masataka, Morita, Tsuyoshi, Shimazu, Kyotaro
• Primary Examiner(s): Manoharan, Virginia
• Application Number:
  US07/399,003
• Time in Patent Office: 659 Days
• Field of Search: 159/47.1, 159/DIG. 10, 159/43.1, 159/27.4, 159/DIG. 16, 202/265, 202/205, 202/175, 202/262, 203/91, 525/232, 528/501
• US Class Current: 159/27.4
• CPC Class Codes: B01D 1/06 Evaporators with vertical tubes
• CPC Class Codes: B01D 3/008 Liquid distribution
• CPC Class Codes: B01D 3/06 Flash distillation
• CPC Class Codes: C08F 6/003 from polymer solutions, suspensions, dispersions or emulsions without recovery of the polymer therefrom
• CPC Class Codes: Y10S 159/10 Organic
• CPC Class Codes: Y10S 159/16 Vacuum

Abstract

An apparatus for devolatilizing liquid composition containing polymer and volatile constituents including a heat exchanger, a volatilizer coupled to the underside of the heat exchanger and a vacuum connected to the volatilizer, the apparatus further comprising a distributor provided between the heat exchanger and the volatilizer; and a method of devolatilizing liquid composition containing polymer and volatile constitutents using a devolatilization apparatus, the devolatilization apparatus comprising a heat exchanger, a volatilizer coupled to the underside of said heat exchanger, a vacuum connected to the volatilizer and a distributor provided between the heat exchanger and volatilizer.

Claims

1. A method of devolatilizing a liquid composition containing a styrene-based polymer and volatile constituents which comprises

feeding the liquid composition to the inlet of a vertical multi-tube heat exchanger whereby a stream of the liquid composition flows downwardly through each of the tubes of said heat exchanger to thereby raise the temperature of said liquid composition in each said stream,

subdividing each of the heat exchanged liquid streams flowing from the outlet of each of said heat exchange tubes into a plurality of subdivided liquid streams by passing each liquid stream through an apertured distributor mounted directly to the outlet end of each respective heat exchanger tube,

and volatilizing the plurality of subdivided liquid streams flowing through the apertured distributors in a first volatilization zone located below the vertical multi-tube heat exchanger and apertured distributors.

2. The method of claim 1 which further comprises mixing the liquid composition stream in each of the vertical heat exchange tubes.

3. The method of claim 2 wherein the mixing is caused by flowing the liquid stream passed a plurality of non-moving static mixing elements provided in said vertical heat exchange tubes.

4. The method of claim 1 wherein said liquid composition contains less than about 1% by weight of volatile constituents.

5. The method of claim 1 wherein said liquid composition is a styrene-based polymer solution with a polymerization conversion of 80 to 95% by weight.

6. The method of claim 1 which further comprises passing the devolatilized liquid from the first volatilization zone into a second volatilization zone via a tubular mixer with a plurality of inner static mixing elements having no moving parts.

7. The method of claim 6 which further comprises adding a bubble-forming agent to the devolatilized liquid from the first volatilization zone prior to the inlet of said tubular mixer.

8. An apparatus for devolatilizing liquid composition containing polymer and volatile constituents comprising a vertical multi-tube heat exchanger, a volatilizer coupled to the underside of said heat exchanger and vacuum means connected to said volatilizer, and a distributor provided between said heat exchanger and said volatilizer, wherein said distributor is directly mounted on the outlet of each tube of said vertical multi-tube heat exchanger.

9. The apparatus according to claim 8, wherein a plurality of static mixing elements having no moving parts are provided in each tube of the vertical multi-tube heat exchanger.

10. The apparatus according to claim 8, wherein each said distributor has 4 to 10 circular holes with a diameter of 3 to 5 mm.

11. The apparatus according to claim 10, wherein each said distributor does not have any hole in a central portion.