Flavor substances for smoking articles

• US 5,038,802 A
• Filed: 11/13/1989
• Issued: 08/13/1991
• Est. Priority Date: 12/21/1988
• Status: Expired due to Fees

• Current Assignee: R J Reynolds Tobacco Company (R. J. Reynolds Tobacco)
• Original Assignee: R J Reynolds Tobacco Company (R. J. Reynolds Tobacco)
• Inventors: White, Jackie L., Shannon, Michael D., Blakley, Richard L., Shelar, Gary R., Bernasek, Edward, Hildebolt, William M.
• Primary Examiner(s): Millin, V.
• Application Number:
  US07/435,951
• Time in Patent Office: 638 Days
• Field of Search: 131/290, 131/275, 131/276, 131/297, 131/298
• US Class Current: 131/297
• CPC Class Codes: A24B 15/24 by extraction; Tobacco extracts

Abstract

The flavor substances of the present invention are prepared by toasting (heating) natural tobacco in an inert atmosphere at a temperature of at least about 225° C., fractionating the volatiles and collecting at least a portion of the fractionated materials as the flavor substances. This fractionating and/or collecting can be conducted by condensation, liquid-liquid extraction, sorption (adsorption and/or absorption) and the like, with either a solid or liquid sorbent medium. Either the sorbent medium containing the trapped volatiles or the volatiles themselves may be used as the flavor substances of the present invention.

Claims

1. A process for producing flavor substances from tobacco, comprising:

(a) heating tobacco in an inert atmosphere to a temperature of at least about 200°

C., thereby driving off volatile materials from the tobacco;

(b) fractionating the volatile materials driven off by heating the tobacco; and

(c) collecting at least a portion of the fractionated volatile materials as flavor substances.

2. The process of claim 1, wherein the tobacco is heated at a temperature of at least about 225°

C.

3. The process of claim 1, wherein the tobacco is heated at a temperature of from about 225°

C. to 450°

C.

4. The process of claim 1, wherein the tobacco is heated at a pressure above atmospheric.

5. The process of claim 1, wherein the tobacco is heated at a pressure below atmospheric.

6. The process of claim 1, which further comprises the use of an inert sweep gas to carry the volatile materials from step (a) through step (c).

7. The process of claim 1, wherein the fractionation is conducted via condensation within the temperature range of from about -50°

C. to about 20°

C.

8. The process of claim 1, wherein the fractionation conducted via condensation within the temperature range of from about -10°

to about 5°

C.

9. The process of claim 1, wherein the fractionation is conducted via condensation at a temperature of about 0°

C.

10. The process of claim 1, which further comprises the use of a sorbent medium to collect at least a portion of the uncondensed volatile materials.

11. The process of claim 1 or 10, wherein the tobacco is heated at a temperature of from about 300°

to about 500°

C.

12. The process of claim 10, wherein the sorbent medium comprises a solid sorbent.

13. The process of claim 12, wherein the sorbent medium comprises alpha alumina.

14. The process of claim 12, wherein the sorbent medium comprises carbon.

15. The process of claim 14, wherein the sorbent medium comprises activated carbon.

16. The process of claim 14, wherein the sorbent medium comprises deactivated carbon.

17. The process of claim 12, wherein the sorbent medium comprises tobacco.

18. The process of claim 10, wherein the sorbent medium comprises a liquid sorbent.

19. The process of claim 18, wherein the liquid sorbent medium comprises glycerin.

20. The process of claim 18, wherein the liquid sorbent medium comprises a vegetable oil.

21. The process of claim 18, wherein the liquid sorbent medium comprises triacetin.

31. A flavor substance made by the process of claim 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 12, 13, 14, 15, 16, 17, 18 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, or 30.

22. A process for producing flavor substances from tobacco, comprising:

(a) heating tobacco in an inert atmosphere to a temperature of at least about 200°

C., thereby driving off volatile materials from the tobacco;

(b) fractionating the volatile materials driven off by heating the tobacco via an organic--aqueous, liquid-liquid separation means; and

(c) collecting at least a portion of the fractionated volatile materials as flavor substances.

23. The process of claim 22, wherein the tobacco is heated at a temperature of at least about 225°

C.

24. The process of claim 22, wherein the tobacco is heated at a temperature of from about 225°

C. to 450°

C.

25. The process of claim 22, which further comprises the use of an inert sweep gas to carry the volatile materials from step (a) through step (c).

26. The process of claim 22, wherein the fractionation is conducted with a plurality liquid-liquid separation means, each maintained separately at a temperature within the range of from about -50°

C. to about +300°

C.

27. The process of claim 26, wherein the plurality of liquid-liquid separation means have temperatures within the range of from about -10°

to about +200°

C.

28. The process of claim 22, wherein the organic component of the liquid-liquid separation means is triacetin.

29. A process for producing flavor substances from tobacco, comprising:

(a) heating a first tobacco segment in an inert atmosphere at a temperature of about 475°

C., thereby driving off volatile materials from the tobacco;

(b) heating a second tobacco segment in an inert atmosphere at a temperature of about 475°

C., thereby driving off volatile materials from the tobacco;

(c) heating a third tobacco segment in an inert atmosphere at a temperature of about 325°

C., thereby driving off volatile materials from the tobacco;

(d) passing the volatile materials from the first tobacco segment into the second tobacco segment, thereafter passing the combined volatiles through the third tobacco segment, thus yielding volatiles which are a mixture of all three tobacco segments;

(e) fractionating the volatile materials combined in step (d) via an organic--aqueous, liquid-liquid separation means; and

(f) collecting at least a portion of the fractionated volatile materials as flavor substances.

30. A process for producing flavor substances from tobacco, comprising:

(a) heating a first tobacco segment in an inert atmosphere at a temperature of about 475°

C., thereby driving off volatile materials from the tobacco;

(b) heating a second tobacco segment in an inert atmosphere at a temperature of about 400°

C., thereby driving off volatile materials from the tobacco;

(c) heating a third tobacco segment in an inert atmosphere at a temperature of about 325°

C., thereby driving off volatile materials from the tobacco;

(d) independently collecting and combining the volatile materials from the three tobacco segments, thus yielding volatiles which are a mixture of all three tobacco segments;

(e) fractionating the volatile materials combined in step (d) via an organic--aqueous, liquid-liquid separation means; and

(f) collecting at least a portion of the fractionated volatile materials as flavor substances.