Process for preparing polyimide composites

• US 5,059,273 A
• Filed: 10/26/1989
• Issued: 10/22/1991
• Est. Priority Date: 10/26/1989
• Status: Expired due to Term

• Current Assignee: Fiberite, Inc.
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Gannett, Thomas P., Boyce, Richard J.
• Primary Examiner(s): Gallagher, John J.
• Application Number:
  US07/426,932
• Time in Patent Office: 726 Days
• Field of Search: 156/307.4, 156/331.1, 156/286, 428/473.5, 528/348, 427/375
• US Class Current: 156/307.4
• CPC Class Codes: C08G 73/1014 in the form of (mono)anhydrid
• CPC Class Codes: C08G 73/1028 characterised by the process itself, e.g. steps, continuous
• CPC Class Codes: C08J 2379/08 Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
• CPC Class Codes: C08J 5/243 using carbon fibres
• CPC Class Codes: Y10T 428/31721 Of polyimide

Abstract

Low void composites with high Tg polyimide matrices are prepared from stoichiometrically unbalanced precursors.

Claims

1. A process for preparing high quality fiber reinforced polyimide matrix composites having a void content of less than 1%, at moderate melt-consolidation pressures comprising

a) forming a prepreg by combining fiber with a molecular weight limiting polyimide precursor solution of i) at least one aromatic diamine and a molar excess of at least one aromatic dianhydride or functional equivalent thereof;

ii) at least one aromatic diamine and at least one aromatic dianhydride or functional equivalent thereof in stoichiometric proportions and an aromatic monoanhydride or functional equivalent thereof;

or iii) at least one aromatic dianhydride or functional equivalent thereof and a molar excess of at least one aromatic diamine and an aromatic monoanhydride or functional equivalent thereof in amount sufficient to end-cap the molar excess of diamine;

b) polymerizing the precursors and devolatilizing the product by heating until the volatiles are substantially removed;

c) heating the devolatilized product to a temperature above the glass transition temperature until the melt viscosity of the polymer is sufficiently low to permit melt-consolidating without substantial degradation at a pressure of under 650 pounds per square inch;

d) melt-consolidating the product to reduce void content below 1%; and

e) heating the product until the glass transition temperature of the resulting product is equal to or greater than that of the polymer prepared from stoichiometric proportions of the same polyimide precursors.

2. The process according to claim 1 wherein the polyimide precursor is selected from i) and consists essentially of a mixture of meta- and para-phenylene diamines and a molar excess of 2,2-bis(3'"'"', 4'"'"'-dicarboxyphenyl)hexafluoropropane.

3. The process according to claim 1 wherein the polyimide precursor is selected from iii) and consists essentially of pyromellitic diethylester diacid and a molar excess of 4,4'"'"'-[(1, 1'"'"'-biphenyl)-2,5-diylbis(oxy)]bisbenzeneamine, the excess amine being end-capped with phthalic anhydride.

4. The process according to claim 1 wherein a plurality of prepregs formed in step a) are stacked before proceeding with step b).