Heat insulating glass with dielectric multilayer coating

• US 5,073,451 A
• Filed: 07/31/1990
• Issued: 12/17/1991
• Est. Priority Date: 07/31/1989
• Status: Expired due to Fees

• Current Assignee: Central Glass Company Limited
• Original Assignee: Central Glass Company Limited
• Inventors: Nakamura, Masato, Nakashima, Hiroshi, Takeuchi, Nobuyuki, Itoh, Toshiaki, Iida, Yasunobu, Furuya, Koichi
• Primary Examiner(s): Robinson, Ellis P.
• Assistant Examiner(s): Turner, Archene A.
• Application Number:
  US07/560,816
• Time in Patent Office: 504 Days
• Field of Search: 428/426, 428/432, 428/698, 428/697, 428/212, 428/699, 428/701, 428/702, 428/704, 428/913, 428/336, 350/164, 350/166, 350/1.6
• US Class Current: 428/336
• CPC Class Codes: B32B 17/10036 comprising two outer glass sheets
• CPC Class Codes: B32B 17/10174 Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
• CPC Class Codes: C03C 17/3417 all coatings being oxide coatings
• CPC Class Codes: C03C 17/3435 comprising a nitride, oxynitride, boronitride or carbonitride
• CPC Class Codes: C03C 17/36 at least one coating being a metal
• CPC Class Codes: C03C 17/3618 Coatings of type glass/inorganic compound/other inorganic layers, at least one layer being metallic
• CPC Class Codes: C03C 17/3626 one layer at least containing a nitride, oxynitride, boronitride or carbonitride
• CPC Class Codes: C03C 17/3644 the metal being silver
• CPC Class Codes: C03C 17/3652 the coating stack containing at least one sacrificial layer to protect the metal from oxidation
• CPC Class Codes: C03C 2217/734 comprising an alternation of high and low refractive indexes
• CPC Class Codes: C03C 2217/78 Coatings specially designed to be durable, e.g. scratch-resistant
• CPC Class Codes: Y10T 428/24942 including components having same physical characteristic in differing degree
• CPC Class Codes: Y10T 428/265 1 mil or less

Abstract

The invention provides a heat insulating glass plate with a multilayer coating which is fairly low in transmittance for solar radiation and fairly high in transmittance for the visible light and also for radio waves. The multilayer coating is a lamination of transparent and dielectric layers and has three essential layers in which the middle layer is higher or lower in refractivity than the inner and outer layers. The coating may have five layers in which the second and fourth layers are higher or lower in refractivity than the remaining three layers. Each layer of the multilayer coating is a metal compound film deposited by sputtering or CVD. In a first embodiment of the three-layer coating each of the inner and outer layers is formed of SnO_x, ZrO_x, TaO_x or AlN_x having a refractive index of 1.8-2.1 and the middle layer is formed of TiO_x having a refractive index of 2.2-2.5. In a second embodiment, each of the inner and outer layers is formed of SnO_x, TiO_x, ZrO_x, TaO_x, ZnO_x, AlN_x or SiN_x having a refractive index of 1.8-2.5 and the middle layer is formed of SiO_x, AlO_x or Si.AlO_x having a refractive index of 1.4-1.7. The heat insulating glass plates are useful as vehicle window glasses, and the second embodiment of the multilayer coating is very suitable for use in laminated glass.

Claims

1. A heat insulating glass plate particularly suitable as a vehicle window glass, having a transparent glass plate and a multilayer coating formed on one side of the glass plate, the multilayer coating comprising:

a first layer which is a transparent and dielectric film of a aluminum nitride having a refractive index in the range from 1.8 to 2.1 deposited on a surface of the glass plate;

a second layer which is a transparent and dielectric film of a titanium oxide having a refractive index in the range from 2.2 to 2.5 deposited on said first layer; and

a third layer which is a transparent and dielectric film of a aluminum nitride having a refractive index in the range from 1.8 to 2.1 deposited on said second layer;

each of said first, second and third layers being formed by a sputtering process or a chemical vapor deposition process and having a thickness in the range from 100 to 2000 Å and

a surface resistivity not lower than 10 kΩ

/□

, the multilayer coating being formed such that the heat insulating glass plate is not lower than 65% in transmittance for the visible light, not higher than 15% in reflectance for the visible light and not higher than 65% in transmittance for solar radiation and such that the heat insulating glass plate is lower than the glass plate itself in transmittance for solar radiation by at least 5%.

2. A heat insulating glass plate according to claim 1, further comprising a protective coating layer which is a film of an oxide of at least one metal selected from the group consisting of Si and Al deposited on said third layer and has a thickness in the range from 100 to 2000 Å

.

3. A heat insulating glass plate according to claim 2, wherein said protective coating layer has a refractive index in the range from 1.4 to 1.7.

4. A heat insulating glass plate according to claim 1, further comprising a fourth layer which is a transparent and dielectric film of a metal compound having a refractive index in the range from 2.2 to 2.5 deposited on said third layer, and a fifth layer which is a transparent and dielectric film of a metal compound having a refractive index in the range from 1.8 to 2.1 deposited on said fourth layer, each of said fourth and fifth layers being formed by a sputtering process or a chemical vapor deposition process and having a thickness in the range from 100 to 2000 Å

.

5. A heat insulating glass plate according to claim 4, wherein said metal compound of said fifth layer is aluminum nitride, and said metal compound of fourth layer is an oxide of Ti.

6. A heat insulating glass plate according to claim 4, further comprising a protective coating layer which is a film of an oxide of at least one metal selected from the group consisting of Si and Al deposited on said fifth layer and has a thickness in the range from 100 to 2000 Å

.

7. A heat insulating glass plate according to claim 6, wherein said protective coating layer has a refractive index in the range from 1.4 to 1.7.

8. A heat insulating glass plate according to claim 1, wherein the glass plate is a color glass plate.

9. A heat insulating glass plate particularly suitable as a vehicle window glass, having a transparent glass plate and a multilayer coating formed on one side of the glass plate, the multilayer coating consisting essentially of:

a first layer which is a transparent and dielectric film of a tin oxide having a refractive index in the range from 1.8 to 2.1 deposited on a surface of the glass plate;

a second layer which is a transparent and dielectric film of a titanium oxide having a refractive index in the range from 2.2 to 2.5 deposited on said first layer; and

a third layer which is a transparent and dielectric film of a tin oxide having a refractive index in the range from 1.8 to 2.1 deposited on said second layer;

each of said first, second and third layers being formed by a sputtering process or a chemical vapor deposition process and having a thickness in the range from about 400 to about 600 Å and

a surface resistivity not lower than 10 kΩ

/□

, the multilayer coating being formed such that the heat insulating glass plate is not lower than 65% in transmittance for the visible light, not higher than 15% in reflectance for the visible light and not higher than 65% in transmittance for solar radiation and such that the heat insulating glass plate is lower than the glass plate itself in transmittance for solar radiation by at least 5%.

10. The heat insulating glass plate of claim 9, further consisting essentially of a protective coating layer which is a film of an oxide of at least one metal selected from the group consisting of Si and Al deposited on said third layer and has a thickness in the range from 100 to 2000 Å

.

11. The heat insulating glass plate of claim 10, wherein said protective coating has a refractive index in the range from 1.4 to 1.7.

12. The heat insulating glass plate of claim 9, wherein the glass plate is a color glass plate.