Use of amorphous carbon to promote adhesion between electroactive polymer films and conductive substrates

• US 5,100,523 A
• Filed: 12/17/1990
• Issued: 03/31/1992
• Est. Priority Date: 12/17/1990
• Status: Expired due to Fees

• Current Assignee: Ford Motor Company
• Original Assignee: Ford Motor Company
• Inventors: Plummer, H. Kiel Jr., Tamor, Michael A., Helms, Jeffrey H.
• Primary Examiner(s): Niebling, John
• Assistant Examiner(s): MARQUIS, STEVEN
• Application Number:
  US07/628,034
• Time in Patent Office: 470 Days
• Field of Search: 204/59 R, 204/290 R, 429/213, 359/265, 359/273, 359/274
• US Class Current: 428/426
• CPC Class Codes: C25B 11/091 consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
• CPC Class Codes: G02F 1/15165 Polymers
• CPC Class Codes: H01M 4/60 of organic compounds
• CPC Class Codes: H01M 4/66 Selection of materials
• CPC Class Codes: H01M 4/663 containing carbon or carbonaceous materials as conductive part, e.g. graphite, carbon fibres
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

An interposed layer of amorphous carbon promotes the adhesion between conductive substrates and electrochemically deposited polymers. Such a carbon layer may be deposited directly onto the conductive substrate by conventional methods such as, for example, chemical vapor deposition. The subsequently applied electrochemically deposited polymer adheres more tenaciously to the amorphous carbon coating than if it had been electrodeposited directly onto the conductive substrate.

Claims

1. An electroactive laminate, comprising:

A) a conductive substrate;

B) a layer of amorphous carbon adhered to the conductive substrate; and

C) an electroactive polymer film adhered to the layer of amorphous carbon opposite the conductive substrate.

2. The electroactive laminate according to, claim 1, wherein the conductive substrate comprises a glass support having at least one layer of a metal oxide from about 100 Angstroms to about 10,000 Angstroms thick thereon.

3. The electroactive laminate according to claim 2, wherein the metal oxide comprises fluorine-doped tin oxide.

4. The electroactive laminate according to claim 1, wherein the layer of amorphous carbon is from about 40 Angstroms to about 1000 Angstroms thick.

5. The electroactive laminate according to claim 1, wherein the electroactive polymer is prepared from heterocycles selected from the group consisting of pyrrole, thiophene, aniline, carbazole, azulene, furan, and derivatives and mixtures thereof.

6. The electroactive laminate according to claim 5, wherein the electroactive polymer is prepared from heterocycles selected from the group consisting of pyrrole, N-methylpyrrole, thiophene, 3-methylthiophene, and mixtures thereof.

7. In an electrochemical cell, comprising an electrode, a counterelectrode, and an electrolyte in electrical communication therebetween, the improvement wherein the electrode is the electroactive laminate of claim 1.

8. An electrochromic display device, comprising:

A) an electroactive laminate, comprising;

i) a conductive substrate;

ii) a layer of amorphous carbon adhered to the conductive substrate; and

iii) an electroactive electrochromic polymer film adhered to the layer of amorphous carbon opposite the conductive substrate;

B) a counterelectrode;

C) an electrolyte medium in electrical communication with the electroactive laminate and the counterelectrode; and

D) means for supplying a polarity reversible voltage across the electroactive laminate and the counterelectrode.

9. The electrochromic display device according to claim 8, wherein the conductive substrate comprises a glass support having at least one layer of a metal oxide from about 100 Angstroms to about 5,000 Angstroms thick thereon.

10. The electrochromic display device according to claim 9, wherein the metal oxide comprises fluorine-doped tin oxide.

11. The electrochromic display device according to claim 8, wherein the layer of amorphous carbon is from about 40 Angstroms to about 250 Angstroms thick.

12. The electrochromic display device according to claim 8, wherein the electroactive polymer is prepared from heterocycles selected from the group consisting of pyrrole, thiophene, aniline, carbazole, azulene, furan, and derivatives and mixtures thereof.

13. The electrochromic display device according to claim 12, wherein the electroactive polymer is prepared from heterocycles selected from the group consisting of pyrrole, N-methylpyrrole, thiophene, 3-methylthiophene, and mixtures thereof.

14. The electrochromic display device according to claim 8, wherein the eletrolyte medium contains electrolyte selected from the group consisting of lithium tetrafluoroborate and lithium perchlorate, and mixtures

15. An electrochromic display device, comprising:

A) an electroactive laminate, comprising;

i) a conductive substrate, including a glass support having at least one layer of fluorine-doped tin oxide from about 100 Angstroms to about 5,000 Angstroms thick thereon;

ii) a layer of amorphous carbon, from about 40 Angstroms to about 250 Angstroms thick, adhered to the conductive substrate; and

iii) an electroactive electrochromic polymer film, prepared from heterocycles selected from the group consisting of pyrrole, thiophene, aniline, carbazole, azulene, furan, and derivatives and mixtures thereof, adhered to the layer of amorphous carbon opposite the conductive substrate;

B) a counterelectrode;

C) an electrolyte medium, containing electrolyte selected from the group consisting of lithium tetrafluoroborate and lithium perchlorate and mixtures thereof, in electrical communication with the electroactive laminate and the counterelectrode; and

D) means for applying a voltage across the electroactive laminate and the counterelectrode.