Light control films and method of making

• US 5,104,210 A
• Filed: 04/24/1989
• Issued: 04/14/1992
• Est. Priority Date: 04/24/1989
• Status: Expired due to Fees

• Current Assignee: Monsanto Company (Bayer AG)
• Original Assignee: Monsanto Company (Bayer AG)
• Inventors: Tokas, Edward F.
• Primary Examiner(s): LaRoche, Eugene R.
• Assistant Examiner(s): Lester, Evelyn A.
• Application Number:
  US07/342,258
• Time in Patent Office: 1,086 Days
• Field of Search: 350/355, 350/362, 350/276 R, 427/47, 427/128, 427/130, 427/372.2
• US Class Current: 359/296
• CPC Class Codes: G02B 1/10 Optical coatings produced by application to, or surface treatment of, optical elements G02B1/08 takes precedence
• CPC Class Codes: G02B 5/00 Optical elements other than lenses light guides G02B6/00; optical logic elements G02F3/00

Abstract

Radiation transmission control films comprising closely spaced agglomerates of small particles, e.g. in linear, side-by-side louvers, in a solid matrix where the agglomerates exhibit different radiation permeability than the matrix. Methods of making such films include magnetically aligning particles into louvers in an uncured matrix then curing the matrix to provide louvered film. Such films are useful to control the transmission of light, other electromagnetic radiation and particle radiation.

Claims

1. A film for controlling the transmission of radiation between surfaces thereof comprising a continuous, solid matrix and disposed in said matrix a set of linear, side-by-side louvers composed of agglomerates of particles of a magnetically-alignable material which differs in permeability relative to the matrix material with respect to at least some selected radiation, wherein said louvers are aligned at a essentially a common angle to the surface of said film and are randomly disposed between said surfaces at a spacing between said louvers of less than 50 microns;

and wherein, when radiation impinges on one of said surfaces of said film, said radiation is transmitted through said film so that the angle of maximum transmission through said film is essentially parallel to said common angle of alignment of said louvers and the transmission of radiation is reduced at angles divergent from said common angle.

2. The film of claim 1 in which the particle material is relatively radiation limiting with respect to at least some selected radiation.

3. The film of claim 1 in which the matrix is an optically clear material and the particles are optically limiting material.

4. The film of claim 1 in which the louvers are less than 10 microns apart and of average height at least as great as the average distance between louvers.

5. The film of claim 2 in which the louvers are disposed at an angle of approximately 90°

to the upper surface of the film so that a high proportion of radiation impinging perpendicularly upon the film can be transmitted between the louvers and through the film.

6. The film of claim 2 in which the louvers are disposed at an angle other than 90°

to the surface of the film.

7. The film of claim 1 in which the louvers are about 5 to about 20 microns apart, and the film is no more than about 50 microns thick.

8. The film of claim 1 in which the particles are ferromagnetic or ferrimagnetic materials.

9. The film of claim 1 in which the particles are magnetite.

10. The film of claim 1 in which the particles are iron.

11. The film of claim 1 in which the matrix is selected from an organic polymer resin.

12. The film of claim 1 in which the matrix is selected from acrylic and urethane resins.

13. The film of claim 3 in which the particles are of sizes having a minimum dimension in the range of about 0.005 to 2 microns, and of concentration about 0.2% to about 11.5% by volume of the matrix material.

14. The film of claim 3 in which the concentration is about 1% to about 5% by volume.

15. A process of preparing radiation control materials which comprises subjecting a viscous, film matrix material containing a small concentration of magnetically alignable particles, to a magnetic field to align the particles into agglomerates in the shape of walls of appreciable thickness and curing the matrix material to fix the agglomerates, wherein the film is subjected to relative movement with respect to magnetic fields to align the particles into agglomerates in louver shape.

16. The process of claim 15 in which the film is subjected to a static magnetic field to form generally cylindrical shaped agglomerates oriented to the magnetic field and substantially normal to the film surface.

17. The process of claim 15 in which the viscous film material has a viscosity in the range of about 15,000 to about 150,000 cps.

18. The process of claim 15 in which the viscosity is at least 10,000 cps.

19. The process of claim 15 in which the viscous film is subjected to a magnetic field in the range of 150 to 4000 gauss.

20. The process of claim 15 in which the concentration of alignable particles is in the range of about 0.2% to about 11.5% by volume of the matrix material.

21. The process of claim 15 in which the concentration of alignable particles is in the range of 1% to 5% by volume of the matrix material.

22. The process of claim 15 in which the viscous film material is passed through a magnetic field a number of times, thereby obtaining sufficient total field exposure.

23. The process of claim 15 in which the viscous film material is moved through the magnetic field at a rate between about 1.5 and 9.7 meters/minute.

24. The process of claim 15 in which the total field exposure is more than 12 seconds.

25. The process of claim 15 in which the particles are of size in the range of 0.005 to 2 microns.

26. The process of claim 15 in which the average particle size is less than 1 micron.

27. The process of claim 15 in which the particles are selected from ferrimagnetic and ferromagnetic materials.

28. The process of claim 15 in which the matrix is an optically clear material.

29. The process of claim 15 in which the matrix material comprises a polymerizable monomer or oligomer.

30. The process of claim 15 in which the matrix is selected from acrylic and urethane materials.

31. A method of affecting the transmission of radiation by employing a film having a solid matrix permeable to at least some radiant energy rays and having disposed therein a set of agglomerates of radiation limiting particles, which individual agglomerates have on the average a minimum dimension no less than about 0.7 micron, and with distances between adjacent agglomerates being on the average at least about 3 microns, and controlling the direction from which radiant rays pass through the film, or the direction of rays emerging from the film, or both.

32. The method of claim 31 in which the agglomerates are disposed as louvers in side-by-side relationship.

33. The method of claim 31 in which the film is employed to selectively shield against some microwaves.

34. The method of claim 31 in which the particles are optically limiting and light rays are permitted to strike the film at a number of angles and there is greater transmission of light striking at some angles than that striking at other angles.

35. The method of claim 34 in which the film comprises a composite structure including a transparent glass layer.

36. The method of claim 35 in which the film is employed in a building window to favor transmission of external ambient light over direct sunlight.

37. The method of claim 34 in which the particles are magnetically alignable and selected from ferromagnetic and ferrimagnetic materials, and the solid matrix is an organic polymer.

38. A method of affecting the transmission of light which comprises permitting light rays to impinge upon a film which is composed of a light-transmitting solid monolithic matrix having disposed therein linear louvers in side-by-side relationship, which louvers are composed of agglomerates of aligned optically limiting particles, and in which the louvers are no more than about 75 microns apart.

39. The method of claim 38 in which the louvers are aligned at an angle of approximately 90°

with the surface of the film upon which light impinges so that light rays impinging perpendicularly upon the surface can readily pass between the louvers, while light rays impinging at angles other than perpendicular, but not parallel to the louvers, are to a substantial extent prevented from passing through the film, thereby making it possible to filter out selectively some of the rays of light striking the film.

40. The method of claim 38 in which the louvers are no more than about 50 microns apart on the average and the height of the louvers is at least about equal to the space between louvers, so that light rays striking the film at an angle greater than 45°

from perpendicular, and in a direction perpendicular to the louvers, will tend to be filtered out.

41. The method of claim 38 in which the louvers are angled at an angle other than perpendicular to the film surface, thereby favoring transmission of light impinging upon such surface at such other selected angle, over that impinging at perpendicular.

42. The method of claim 38 in which the particles are magnetically alignable.