Near-field scanning optical microscope using a fluorescent probe

• US 5,105,305 A
• Filed: 01/10/1991
• Issued: 04/14/1992
• Est. Priority Date: 01/10/1991
• Status: Expired due to Term

• Current Assignee: Lucent Technologies, Inc. (Nokia Corporation)
• Original Assignee: AT&T, Inc.
• Inventors: Trautman, Jay K., Betzig, Robert E.
• Primary Examiner(s): Lee, John D.
• Application Number:
  US07/639,629
• Time in Patent Office: 460 Days
• Field of Search: 350/96.10, 350/96.15, 350/96.18, 350/96.24-96.26, 350/96.29-96.34, 128/634, 606/2, 606/15, 606/16, 250/227.14, 250/227.18, 250/458.1
• US Class Current: 359/368
• CPC Class Codes: G01Q 60/20 Fluorescence

Abstract

A novel probe, useful for near-field optical scanning microscopy, is provided. The probe has a fine tip which includes fluorescent material. In one embodiment, the invention is an apparatus which includes such a probe, means for exciting and detecting fluorescence in the probe tip, means for positioning the probe tip near the surface of a sample, and means for displacing the probe tip relative to the sample. In a second embodiment, the invention is a manufacturing method in which the novel probe is used to measure a characteristic dimension of a patterned workpiece.

Claims

1. In a near-field scanning optical microscope, apparatus comprising:

a probe, the probe having a tip capable of emitting light at least at a given wavelength;

means for detecting at least a portion of the light emitted by the probe tip;

means for positioning the probe adjacent a sample such that the distance between the probe tip and the sample is smaller than about five times the given wavelength; and

means for displacing the probe tip relative to the sample,

CHARACTERIZED IN THAT

the probe tip comprises fluorescent material capable of emitting light at least at the given wavelength when the fluorescent material is appropriately excited; and

the apparatus further comprises means for exciting the fluorescent material.

2. Apparatus of claim 1, wherein:

the probe comprises a glass pipette having a tapered end and an aperture in the tapered end; and

the probe tip comprises a fluorescent body adherent to the pipette adjacent the aperture, the body comprising fluorescent material and having maximum lateral dimensions smaller than the given wavelength.

3. Apparatus of claim 1, wherein:

the probe comprises a glass pipette having a tapered end and an aperture in the tapered end, there being an inner diameter associated with the aperture; and

the probe tip comprises a spheroidal body having a diameter greater than the aperture inner diameter, the body adherent to the pipette such that a first portion of the body lies within the aperture and a second portion of the body lies outside the aperture, at least the second portion of the body comprising fluorescent material, and the body diameter being smaller than the given wavelength.

4. Apparatus of claim 1, wherein:

the probe comprises a single-mode optical fiber having a tapered terminal portion and an end flat at the end of the tapered portion; and

the probe tip comprises a fluorescent body adherent to the end flat, the body comprising fluorescent material and having maximum lateral dimensions smaller than the given wavelength.

5. Apparatus of claim 1, wherein:

the probe comprises a single-mode optical fiber having a tapered terminal portion and an end flat at the end of the tapered portion; and

the probe tip comprises a spheroidal body having a diameter smaller than the given wavelength, the body adherent to the end flat, at least a portion of the body comprising fluorescent material.

6. Apparatus of claim 1, wherein:

the probe comprises a single-mode optical fiber having a tapered terminal portion (to be referred to as the "taper") and an end flat at the end of the tapered portion, the end flat having a diameter smaller than the given wavelength;

the probe tip coincides with a terminal portion of the taper, including the end flat; and

the probe tip comprises implanted, fluorescent ions.

7. Apparatus of claim 1, wherein:

the probe comprises a single-mode optical fiber having a tapered terminal portion (to be referred to as the "taper") and an end flat at the end of the tapered portion, a borehole being defined in the end flat, a diameter being associated with the borehole; and

the probe tip comprises a spheroidal body having a diameter greater than the borehole diameter, the body adherent to the fiber such that a first portion of the body lies within the borehole and a second portion of the body lies outside the borehole, at least the second portion of the body comprising fluorescent material, and the body diameter being smaller than the given wavelength.

8. Apparatus of claim 1, wherein the exciting means comprise a light source optically coupled to the fluorescent material.

9. Apparatus of claim 8, wherein the exciting means further comprise means for transmitting electromagnetic radiation from the light source, through the sample, to the fluorescent material.

10. Apparatus of claim 8, further comprising means for transmitting light emitted by the fluorescent material through the sample to the detecting means.

11. Method for manufacturing an article, comprising the steps of:

a) providing a multiplicity of semiconductor wafers, each wafer having a surface to be patterned by means of a patterning process;

b) setting at least one parameter of the patterning process;

c) processing at least a first wafer according to the process parameter, such that a pattern is formed on the surface of the wafer, the pattern having a characteristic dimension;

d) measuring the characteristic dimension in at least one of the multiplicity of semiconductor wafers;

e) comparing the characteristic dimension to a predetermined range of values;

f) if the characteristic dimension lies outside the predetermined range of values, changing the process parameter to bring the characteristic dimension within the predetermined range of values;

g) after (f), processing at least a second wafer according to the process parameter; and

h) performing, on at least the second wafer, at least one additional step toward completion of the article,

CHARACTERIZED IN THAT

the measuring step comprises;

i) providing a probe having a tip, the probe tip comprising fluorescent material capable of emitting light at least at a given wavelength when the fluorescent material is appropriately excited;

j) positioning the probe relative to the wafer such that the distance between the probe tip and at least a portion of the pattern is smaller than the given wavelength;

k) displacing the probe tip relative to the wafer;

l) during the displacing step, exciting fluorescence in the probe tip; and

m) detecting fluorescent light emitted by the probe tip.