Scale control in phosphoric acid manufacture

• US 5,120,519 A
• Filed: 11/04/1991
• Issued: 06/09/1992
• Est. Priority Date: 11/04/1991
• Status: Expired due to Term

• Current Assignee: Ecolab USA Incorporated (Ecolab, Inc.)
• Original Assignee: Nalco Chemical Company (Ecolab, Inc.)
• Inventors: Gross, Anthony E.
• Primary Examiner(s): HELLER, GREGORY
• Application Number:
  US07/787,197
• Time in Patent Office: 218 Days
• Field of Search: 423/321 R, 423/321 S, 423/320
• US Class Current: 423/321.1
• CPC Class Codes: C01B 25/223 only one form of calcium sulfate being formed
• CPC Class Codes: C01B 25/2346 Concentration

Abstract

High molecular weight copolymers of acrylamide which contain between 5-100 mole % of acrylic acid and have a molecular weight of at least 1,000,000 prevent scale adhering to surfaces in contact with digested phosphate rock and/or phosphoric acid produced from digestion.

Claims

1. A method of preventing sodium fluosilicate containing scales from forming on surface in contact with either digested phosphate rock or phosphoric acid, or both, produced from the digestion which comprises treating either the digested phosphate rock or the phosphoric acid, or both with a scale inhibiting amount of anionic water soluble vinyl addition polymer which has a molecular weight of at least 1,000,000 which polymer contains between 5 to 100 mole % of mer units of an anionic vinyl monomer from the group consisting of acrylic acid, methacrylic acid, ethacrylic acid and 2-acrylamido-2 methyl propane sulfonic acid, and their alkali metal salts.

2. The method of claim 1 where the anionic water soluble vinyl addition polymer has a molecular weight of at least 5,000,000.

3. The method of claim 1 where anionic water soluble vinyl addition polymer has a molecular weight of 5,000,000-10,000,000 and contains at least 30 mole % of mer units of the anionic vinyl addition monomer.

4. The method of claim 1 wherein the anionic water soluble vinyl addition polymer is a copolymer of acrylic acid and acrylamide.

5. The method of claim 4 wherein the copolymer of acrylic acid and acrylamide contains greater than 30% mer units derived from acrylic acid.