Deposition of electroactive polymers

• US 5,128,013 A
• Filed: 12/17/1990
• Issued: 07/07/1992
• Est. Priority Date: 12/17/1990
• Status: Expired due to Fees

• Current Assignee: Ford Global Technologies, LLC (Ford Motor Company)
• Original Assignee: Ford Motor Company
• Inventors: Helms, Jeffrey H.
• Primary Examiner(s): Marquis, Steven
• Application Number:
  US07/628,033
• Time in Patent Office: 568 Days
• Field of Search: 204/59 R, 204/290 R, 359/265, 359/273, 359/274, 429/213
• US Class Current: 428/426
• CPC Class Codes: C03C 17/42 at least one coating of an organic material and at least one non-metal coating
• CPC Class Codes: C08G 61/122 derived from five- or six-membered heterocyclic compounds, other than imides
• CPC Class Codes: G02F 1/15165 Polymers

Abstract

A uniform, topographically planar layer of an electroactive polymer is electrodeposited onto a conductive substrate by first electrodepositing onto the conductive substrate a thin initiating layer of a different electroactive polymer prepared from monomer having a lower oxidation potential.

Claims

1. An electroactive laminate comprising:

A) a conductive substrate;

B) a first layer of an electroactive polymer, prepared from a first monomer having an oxidation potential, said first layer being adhered to the conductive substrate; and

C) a second layer of an electroactive polymer prepared substantially from a second monomer having an oxidation potential greater than the oxidation potential of the first monomer, having copolymerized therein a small amount of the first monomer, said second layer being adhered to the first layer.

2. The electroactive laminate according to claim 1, wherein the first and second monomers are each, independently selected from the group consisting of pyrrole, thiophene, aniline, carbazole, azulene, and furan, and derivatives and mixtures thereof.

3. The electroactive laminate according to claim 2, wherein the first monomer is selected from the group consisting of pyrrole and N-methylpyrrole, and mixtures thereof, and the second monomer is selected from the group consisting of thiophene and 3-methylthiophene, and mixtures thereof.

4. The electroactive laminate according to claim 1, wherein the conductive substrate comprises:

A) a glass support;

B) at least one layer of metal oxide from about 100 Angstroms to about 10,000 Angstroms thick adhered to the glass support; and

C) a layer of amorphous carbon from about 40 Angstroms to about 1,000 Angstroms thick adhered to the metal oxide.

5. The electroactive laminate according to claim 4, wherein the metal oxide comprises fluorine-doped tin oxide.

6. An electroactive laminate comprising:

A) a glass support;

B) at least one layer of metal oxide from about 100 Angstroms to about 10,000 Angstroms thick adhered to the glass support;

C) a layer of amorphous carbon from about 40 Angstroms to about 1,000 Angstroms thick adhered to the metal oxide;

D) a first layer of an electroactive polymer, prepared from a first monomer having an oxidation potential, said first layer being adhered to the layer of amorphous carbon; and

E) a second layer of an electroactive polymer, prepared substantially from a second monomer having an oxidation potential greater than the oxidation potential of the first monomer, said second layer being adhered to the first layer.

7. The electroactive laminate according to claim 6, wherein the metal oxide comprises fluorine-doped tin oxide.

8. The electroactive laminate according to claim 6, wherein the first and second monomers are each, independently selected from the group consisting of pyrrole, thiophene, aniline, carbazole, azulene, and furan, and derivatives and mixtures thereof.

9. The electroactive laminate according to claim 8, wherein the first monomer is selected from the group consisting of pyrrole and N-methylpyrrole, and mixtures thereof, and the second monomer is selected from the group consisting of thiophene and 3-methylthiophene, and mixtures thereof.

10. An electroactive laminate, comprising:

A) a conductive substrate, comprising;

i) a glass support;

ii) at least one layer of a metal oxide from about 100 Angstroms to about 10,000 Angstroms thick adhered to the glass support; and

iii) a layer of amorphous carbon from about 40 Angstroms to about 1,000 Angstroms thick adhered to the metal oxide;

B) a first layer of an electroactive polymer prepared from a first monomer selected from the group consisting of pyrrole and N-methylpyrrole, and mixtures thereof, said first layer being adhered to the conductive substrate; and

C) a second layer of an electroactive polymer prepared substantially from a second monomer selected from the group consisting of thiophene and 3-methylthiophene, and mixtures thereof, said second layer being adhered to the first layer.

11. An electrochromic display device, comprising:

A) an electroactive laminate, comprising;

i) a conductive substrate;

ii) a first layer of an electroactive polymer, prepared from a first monomer having an oxidation potential, said first layer being adhered to the conductive substrate; and

iii) a second layer of an electroactive polymer, prepared substantially from a second monomer having an oxidation potential greater than the oxidation potential of the first monomer, having copolymerized therein a small amount of the first monomer, said second layer being adhered to the first layer;

B) a counterelectrode;

C) an electrolyte medium is electrical communication with the electroactive laminate and the counterelectrode; and

D) means for supplying a polarity reversible voltage across the electroactive laminate and counterelectrode.

12. The electrochromic display device according to claim 11, wherein the conductive substrate comprises:

A) a glass support;

B) at least one layer of a metal oxide from about 100 Angstroms to about 10,000 Angstroms thick adhered to the glass support; and

C) A layer of amorphous carbon from about 40 Angstroms to about 1,000 Angstroms thick adhered to the metal oxide.

13. The electrochromic display device according to claim 12, wherein the metal oxide comprises fluorine-doped tin oxide.

14. The electrochromic display device according to claim 11, wherein the first and second monomers are each, independently selected from the group consisting of pyrrole, thiophene, aniline, carbazole, azulene, and furan, and derivatives and mixtures thereof.

15. The electrochromic display device according to claim 14, wherein the first monomer is selected from the group consisting of pyrrole and N-methylpyrrole, and mixtures thereof, and the second monomer is selected from the group consisting of thiophene and 3 -methylthiophene, and mixtures thereof.