Linear polyether-containing electrochemichromic solutions and related devices

• US 5,145,609 A
• Filed: 11/07/1990
• Issued: 09/08/1992
• Est. Priority Date: 11/07/1990
• Status: Expired due to Fees

• Current Assignee: Donnelly Corporation (Magna International Incorporated)
• Original Assignee: Donnelly Corporation (Magna International Incorporated)
• Inventors: Varaprasad, Desaraju V., Lynam, Niall R., Habibi, Hamid R., Desaraju, Padma
• Primary Examiner(s): Stoll, Robert L.
• Assistant Examiner(s): TUCKER, PHILIP C
• Application Number:
  US07/610,409
• Time in Patent Office: 671 Days
• Field of Search: 252/583, 252/586, 252/582, 350/357, 359/265, 359/272
• US Class Current: 252/583
• CPC Class Codes: C09K 9/02 Organic tenebrescent materials
• CPC Class Codes: G02F 1/1503 caused by oxidation-reduction reactions in organic liquid solutions, e.g. viologen solutions
• CPC Class Codes: G02F 2001/1502 complementary cell
• CPC Class Codes: G02F 2001/15145 the electrochromic layer comprises a mixture of anodic and cathodic compounds

Abstract

The specification discloses electrochemichromic solutions and devices based on the use of from about 0.5 percent by volume of at least one linear polyether which is soluble in the electrochemichromic solution to reduce segregation without unduly affecting leakage current.

Claims

1. An electrochemichromic solution comprising:

a solvent;

a redox chemical pair in solution in said solvent which colors in the presence of an applied voltage and which bleaches to a colorless condition in the absence of an applied voltage;

said solvent thickened by addition of an effective amount of at least one linear polyether.

2. The electrochemichromic solution of claim 1 in which said linear polyether has a molecular weight in the range from 100,000 to 4,000,000.

3. The electrochemichromic solution of claim 1 in which the viscosity of said electrochemichromic solution is not greater than 600 centistokes at 25°

C.

4. The electrochemichromic solution of claim 1 in which said linear polyether comprises polyethylene oxide and said solvent is thickened by addition of 0.5 to 10 percent weight by volume of polyethylene oxide.

5. The electrochemichromic solution of claim 4 in which said solvent includes as a substantial component at least one material selected from the group consisting of 3-hydroxypropionitrile, 2-acetylbutyrolactone, glutaronitrile, 3,3'"'"'-oxydipropionitrile, 3-methylsulfolane, 2-methylglutaronitrile, propylene carbonate and mixtures thereof.

6. The electrochemichromic solution of claim 5 in which the viscosity of said electrochemichromic solution is not greater than 600 centistokes at 25°

C.

7. The electrochemichromic solution of claim 1 in which said solvent includes as a substantial component at least one material selected from the group consisting of 3-hydroxypropionitrile, 2-acetylbutyrolactone, glutaronitrile, 3,3'"'"'-oxydipropionitrile, 3-methylsulfolane, 2-methylglutaronitrile, propylene carbonate and mixtures thereof.

8. The electrochemichromic solution of claim 7 in which the viscosity of said electrochemichromic solution is not greater than 600 centistokes at 25°

C.

9. The electrochemichromic solution of claim 1 in which said redox chemical pair comprises 0.025 to 0.05 molar of one of methylviologen and ethylviologen and 0.025 to 0.05 molar 5,10-dihydro-5,10-dimethylphenazine.

10. An electrochemichromic cell comprising:

spaced plates, each having an inwardly facing conductive surface;

an electrochemichromic solution located in said cell between said inwardly facing conductive surfaces, said solution comprising;

a solvent;

a redox chemical pair in solution in said solvent which colors in the presence of an applied voltage and which bleaches to a colorless condition in the absence of an applied voltage;

said solvent thickened by addition of at least one linear polyether which is soluble in said solvent.

11. An electrochemichromic cell of claim 10 in which said linear polyether has a molecular weight in the range from 100,000 to 4,000,000.

12. An electrochemichromic cell of claim 10 in which the viscosity of said electrochemichromic solution is not greater than 600 centistokes at 25°

C.

13. An electrochemichromic cell of claim 10 in which said linear polyether comprises polyethylene oxide and said solvent is thickened by addition of 0.5 to 10 percent weight by volume of polyethylene oxide.

14. An electrochemichromic cell of claim 13 in which said solvent additionally comprises one of the group consisting of propylene carbonate, 3-hydroxypropionitrile, 2-acetylbutyrolactone, glutaronitrile, 3,3'"'"'-oxydipropionitrile, 3-methylsulfolane, 2-methylglutaronitrile and mixtures thereof.

15. An electrochemichromic cell in accordance with claim 14 wherein the viscosity of said electrochemichromic solution is not greater than 600 centistokes at 25°

C.

16. The electrochemichromic solution of claim 10 in which said redox chemical pair comprises 0.025 to 0.05 molar of one of methylviologen and ethylviologen and 0.025 to 0.05 molar 5,10-dihydro-5,10-dimethylphenazine.

17. An electrochemichromic solution comprising:

a solvent;

a redox chemical pair in solution in said solvent which colors in the presence of an applied voltage and which bleaches to a colorless condition in the absence of an applied voltage;

said solvent comprising at least 0.5 percent weight by volume of at least one linear polyether having a molecular weight in the range from 100,000 to 4,000,000.

18. The electrochemichromic solution of claim 17 in which the viscosity of said solution is not greater than 600 centistokes at 25°

C.

19. The electrochemichromic solution of claim 18 in which said solvent comprises one of the group consisting of propylene carbonate, 3-hydroxypropionitrile, 2-acetylbutyrolactone, glutaronitrile, 3,3'"'"'-oxydipropionitrile, 3-methylsulfolane, 2-methylglutaronitrile and mixtures thereof.

20. The electrochemichromic solution of claim 19 in which said redox chemical pair comprises 0.025 to 0.05 molar of one of methylviologen and ethylviologen and 0.025 to 0.05 molar 5,10-dihydro-5,10-dimethylphenazine.

21. An electrochemichromic cell comprising:

spaced plates, each having an inwardly facing conductive surface;

an electrochemichromic solution located in said cell between said inwardly facing conductive surfaces, said solution comprising;

a solvent;

a redox chemical pair in solution in said solvent which colors in the presence of an applied voltage and which bleaches to a colorless condition in the absence of an applied voltage;

said solvent thickened by addition of at least one linear polyether having a molecular weight in the range from 100,000 to 4,000,000.

22. The cell of claim 21 in which said linear polyether comprises polyethylene oxide and said solvent is thickened by the addition of 0.5 to 10 percent weight by volume polyethylene oxide.

23. The cell of claim 22 in which said solvent comprises one of the group consisting essentially of propylene carbonate, glutaronitrile, 3-hydroxypropionitrile, 2-acetylbutyrolactone, 3,3'"'"'-oxydipropionitrile, 3-methylsulfolane, 2-methylglutaronitrile and mixtures thereof.

24. The cell of claim 23 in which the viscosity of said solvent is not greater than 600 centistokes at 25°

C.

25. The electrochemichromic solution of claim 21 in which said redox chemical pair comprises 0.025 to 0.05 molar of one of methylviologen and ethylviologen and 0.025 to 0.05 molar 5,10-dihydro-5,10-dimethylphenazine.