Method of preparing UV absorbant and abrasion-resistant transparent plastic articles

• US 5,156,882 A
• Filed: 12/30/1991
• Issued: 10/20/1992
• Est. Priority Date: 12/30/1991
• Status: Expired due to Term

• Current Assignee: Sabic Innovative Plastics IP BV (Government of Saudi Arabia)
• Original Assignee: General Electric Company
• Inventors: Conley, Douglas J., Reed, Clive W., Rzad, Stefan J.
• Primary Examiner(s): PIANALTO, BERNARD D
• Application Number:
  US07/814,172
• Time in Patent Office: 295 Days
• Field of Search: 427/38, 427/44, 427/412.1, 427/419.3, 427/419.5, 427/419.7
• US Class Current: 427/489
• CPC Class Codes: B05D 1/62 Plasma-deposition of organic layers plasma deposition in general C23C14/00, C23C16/00
• CPC Class Codes: B05D 2201/02 Polymeric substrate
• CPC Class Codes: B05D 7/24 for applying particular liquids or other fluent materials
• CPC Class Codes: C08G 77/04 Polysiloxanes
• CPC Class Codes: C08J 7/123 Treatment by wave energy or particle radiation C08J7/18 takes precedence
• CPC Class Codes: C09D 4/00 Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16

Abstract

A method of preparing transparent plastic articles having an improved protective stratum thereon. The protective stratum provides protection from UV light and abrasion. The article includes a polycarbonate substrate and multi-layered coating applied by plasma enhanced chemical vapor deposition on surface of the substrate.

Claims

1. A method of forming a transparent, abrasion resistant and ultraviolet light absorbant article comprising:

plasma enhanced chemical vapor deposition of an interfacial layer of an adherent resinous composition on the surfaces of said article;

plasma enhanced chemical vapor deposition of a layer of an ultraviolet light absorbant composition selected from the group consisting of zinc oxide, titanium dioxide, cerium dioxide and vanadium pentoxide on said interfacial layer of said adherent resinous composition; and

plasma enhanced chemical vapor deposition of a layer of an abrasion resistant composition on top of said layer of said ultraviolet light absorbant composition, said layer of said abrasion resistant composition exhibiting increase in haze of less than 15% after 1000 cycles under The Taber Abrasion Test, designated by American Society for Testing and Materials, as ASTM D1044 or its equivalent.

2. The method according to claim 1 wherein said article is made of polycarbonate or polymethyl methacrylate.

3. The method according to claim 1 wherein said adherent resinous composition is plasma polymerized during said plasma enhanced chemical vapor deposition.

4. The method according to claim 1 wherein said adherent resinous composition comprises an interfacial material selected from the group consisting of organosilicon, organometallic, acrylic, and polyolefin materials.

5. The method according to claim 4 wherein said interfacial material is formed by polymerizing an olefinic monomer in the plasma.

6. The method according to claim 4 wherein said interfacial material is formed by polymerizing an acrylic monomer in the plasma.

7. The method according to claim 4 wherein said interfacial material is formed by polymerizing an organosilicon monomer in the plasma.

8. The method according to claim 7 wherein said organosilicon monomer is selected from the group consisting of hexamethyldisilazane, hexamethyldisiloxane, vinyl trimethylsilane, and octamethylcyclotetrasiloxane.

9. The method according to claim 1 wherein said abrasion resistant composition is selected from the group consisting of silicon carbide, silicon dioxide, silicon nitride, silicon oxynitride, boron oxide, boron nitride, aluminum oxide, aluminum nitride, and mixtures thereof.

10. The transparent, abrasion resistant and ultraviolet light absorbant article produced according to the method of claim 1 on a transparent plastic substrate.

11. A method of forming a transparent, abrasion resistant and ultraviolet light absorbant polycarbonate article comprising:

plasma enhanced chemical vapor deposition of an interfacial layer having thickness of about 100 Å

to about 10,000 Å

of an adherent resinous composition of hexamethyldisiloxane on the surfaces of said polycarbonate article;

plasma enhanced chemical vapor deposition of a layer having thickness of about 1000 Å

to about 10,000 Å

of an ultraviolet light absorbant composition of titanium dioxide on top of said layer of said adherent resinous composition; and

plasma enhanced chemical vapor deposition of a layer having thickness of about 20,000 Å

to about 90,000 Å

of an abrasion resistant composition of silicon dioxide on top of said layer of said ultraviolet light absorbant composition, said layer of said abrasion resistant composition exhibiting increase in haze of less than 15% after 1000 cycles under The Taber Abrasion Test, designated by American Society for Testing and Materials, as ASTM D1044 or its equivalent.