Process for continuous production of polyolefin material

• US 5,200,129 A
• Filed: 04/19/1991
• Issued: 04/06/1993
• Est. Priority Date: 04/20/1990
• Status: Expired due to Term

• Current Assignee: Nippon Mitsubshi Oil Corporation
• Original Assignee: Nippon Oil Corporation (ENEOS Holdings, Inc.)
• Inventors: Kobayashi, Seizo, Iwanami, Yoshimu, Mizoe, Takashi
• Primary Examiner(s): THEISEN, MARY LYNN F
• Application Number:
  US07/687,501
• Time in Patent Office: 718 Days
• Field of Search: 264/119, 264/120, 264/126, 425/371, 425/373
• US Class Current: 264/119
• CPC Class Codes: B29C 2043/483 cooperating with a second endless belt, i.e. double band presses
• CPC Class Codes: B29C 43/228 using endless belts feeding the material between non-rotating pressure members, e.g. vibrating pressure members
• CPC Class Codes: B29C 55/18 by squeezing between surfaces, e.g. rollers
• CPC Class Codes: B29K 2023/00 Use of polyalkenes or derivatives thereof as moulding material
• CPC Class Codes: B30B 5/067 using anti-friction roller means

Abstract

According to the present invention, a polyolefin sheet, film or fiber having a high strength and a high modulus can be continuously produced by:

feeding an ultra-high-molecular-weight polyolefin powder between a pair of upper and lower endless belts opposed to each other,

conveying the polyolefin powder between the endless belts under compression to compression-mold the polyolefin powder at a temperature lower than the melting point of the polyolefin powder, the compression being continuously and smoothly effected, via the endless belts, by a pressing means comprising two sets of rollers which are arranged at the back sides of the endless belts so that each one roller of the two roller sets faces each other and each of which rollers is rotatably supported at the shaft ends by a frame, and then

rolling and stretching the resultant compression-molded polyolefin in this order.

Claims

1. A process for continuously producing a high-strength and high-modulus polyolefin material, which comprises:

feeding a polyolefin powder between a pair of upper and lower endless belts having inner and outer surfaces opposed to each other,

conveying the polyolefin powder between the endless belts under compression to compression-mold the polyolefin powder at a temperature lower than the melting point of the polyolefin powder, the compression being effected, via the endless belts, by a pressing means comprising two opposing sets of a plurality of rollers, each set arranged at the outer surface of each endless belt so that each roller of one set faces a roller of the opposing set and each of which rollers is rotatably supported at the shaft ends by a frame, and then

rolling and stretching the resultant compression-molded polyolefin.

2. A process according to claim 1, wherein each set of rollers arranged at the outer surface of each endless belt is constituted by three or more rollers.

3. A process according to claim 1, wherein each one pair of rollers of the two sets of rollers arranged at the outer surfaces of the endless belts is arranged so as to face each other in a vertical plane intersecting the travelling direction of the endless belts.

4. A process according to claim 1, wherein back-up rolls are annexed to each roller set arranged at the outer surface of each endless belt.

5. A process according to claim 1, wherein the polyolefin powder receives an average pressure of 0.1-100 kgf/cm² when it is passed between the two endless belts under compression by the two opposing roller sets.

6. A process according to claim 1, wherein a heating means is arranged in the vicinity of each roller set.

7. A process according to claim 1, wherein a preheater for heating each endless belt right before each endless belt advances between the two roller sets, is arranged in the vicinity of each endless belt.

8. A process according to claim 1, wherein a heating means is arranged in the vicinity of each roller set and further a preheater for heating each endless belt right before each endless belt advances between the two roller sets, is arranged in the vicinity of each endless belt.

9. A process according to claim 1, wherein the endless belt is driven at a speed of 0.01-500 m/min.

10. A process according to claim 1, wherein the polyolefin is rolled by rolls of different rotating direction while the polyolefin is being maintained in a solid state without being melted.

11. A process according to claim 1, wherein the rolling is effected at a draw ratio of 1.2-20 when expressed as the length after rolling/the length before rolling.

12. A process according to claim 1, wherein the rolling is effected at a temperature of 20°

C. to lower than the melting point of the polyolefin.

13. A process according to claim 1, wherein the polyolefin powder is a powder of a homopolymer or copolymer of an α

-olefin of 2-8 carbon atoms.

14. A process according to claim 1, wherein the polyolefin powder is a powder of a polyethylene having a viscosity-average molecular weight of 500,000-12,000,000.

15. A process according to claim 1, wherein the polyolefin is a powder of a polypropylene having a number-average molecular weight of 1,000,000 or more.