Solid state electrochromic devices

• US 5,206,756 A
• Filed: 12/19/1990
• Issued: 04/27/1993
• Est. Priority Date: 12/20/1989
• Status: Expired due to Fees

• Current Assignee: Imperial Chemical Industries PLC (IMPERIAL CHEMICAL INDUSTRIES)
• Original Assignee: Imperial Chemical Industries PLC (IMPERIAL CHEMICAL INDUSTRIES)
• Inventors: Cheshire, Philip
• Primary Examiner(s): Hille, Rolf
• Assistant Examiner(s): Ho, Tan
• Application Number:
  US07/630,996
• Time in Patent Office: 860 Days
• Field of Search: 350/357, 252/62.2, 252/600, 429/192, 429/194, 359/265, 359/270, 204/14.1
• US Class Current: 359/270
• CPC Class Codes: G02F 1/1525 characterised by a particular ion transporting layer, e.g. electrolyte

Abstract

An electrochromic device which comprises two conductive electrodes separated by a solid electrolyte and an electrochromic material capable of reversible electrochromic interaction with activating electrons and/or ions furnished to it by, or by it to, the rest of the device under the influence of an electrical potential applied across the electrodes, characterized in that the solid electrolyte in the device comprises:

a) a matrix of optionally cross-linked main polymer chains, having side-chains linked to the main polymer chains, which side chains comprise polar groups,

b) an ionized ammonium or alkali metal salt dissolved in the matrix and/or liquid, and

c) an optional polar aprotic liquid dispersed in the matrix,

and a process for the preparation thereof.

Claims

1. In an electrochromic device which comprises a conductive second electrode and first electrode separated by a solid electrolyte and an electrochromic material capable of reversible electrochromic interaction with activating electrons or ions under the influence of an electrical potential applied across the electrodes, the improvement wherein the solid electrolyte in the device comprises:

a) a matrix of cross-linked main polymer chains, having side-chains linked to the main polymer chains, which side chains comprise polar groups,

b) a polar aprotic liquid dispersed in the matrix, and

c) an ionised ammonium or alkali metal salt dissolved in the matrix or liquid.

2. A device according to claim 1 wherein the solid electrolyte comprises the polar aprotic liquid 6.

3. A device according to claim 1 wherein the activating ions are those of lithium and the polar groups in the side chains in the matrix a) are free from active hydrogen ions.

4. A device according to claim 3, wherein the main chains are hydrocarbons or polyether cross-linked by C--C bonds or urethane functions between the main or side chains.

5. A device according to claim 1 wherein the main polymer chains in the matrix are essentially organic polymer chains, comprising sulphur, nitrogen, phosphorus or oxygen atoms;

or ones comprising silicon and oxygen atoms.

6. A device according to claim 1 which comprises an electrode capable of supplying or receiving atoms for electrochromic interaction with the electrochromic material.

7. A device according to claim 1 in the form of a number of laminated multiple thin layer components.

8. A device according to claim 1, wherein the matrix polymer main chains are cross-linked and essentially organic, and the sidechains comprise ester or ether linkages.

9. A process for preparing a device which comprises a conductive second electrode and first electrode separated by a solid electroyte and an electrochromic material capable of reversible electrochromic interaction with activating electrons or ions under the influence of an electrical potential applied across the electrodes, the solid electrolyte in the device comprising

a) a matrix of cross-linked main polymer chains, having side-chains linked to the main polymer chains, which side chains comprise polar groups,

b) a polar aprotic liquid dispersed in the matrix, and

c) an ionised ammonium or alkali metal salt dissolved in the matrix of liquid

said process comprising the steps of:

a) coating a electrochromic material which is capable of being activated by ions onto a first electrode as a thin film on a first support with the solid electrolyte,

b) coating a material which is a source of the activating ions onto a second electrode as a thin film on a second support,

c) contacting the solid electrolyte with the source material,

d) hot-press vacuum laminating all the foregoing integers together, and

e) converting any precursor to the solid electrolyte.