Lamination of semi-rigid material between glass

• US 5,208,080 A
• Filed: 07/01/1992
• Issued: 05/04/1993
• Est. Priority Date: 10/29/1990
• Status: Expired due to Term

• Current Assignee: Automotive Components Holdings LLC (Ford Motor Company)
• Original Assignee: Ford Motor Company
• Inventors: Meyer, John H., Gajewski, Kenneth J.
• Primary Examiner(s): CANNON, JAMES
• Application Number:
  US07/907,350
• Time in Patent Office: 307 Days
• Field of Search: 428/1, 428/46, 428/48, 428/56, 428/61, 428/76, 428/78, 428/119, 428/189, 428/412, 428/437, 428/483, 428/520, 428/213, 428/203, 428/917
• US Class Current: 428/1.54
• CPC Class Codes: B32B 17/10005 laminated safety glass or glazing
• CPC Class Codes: B32B 17/10036 comprising two outer glass sheets
• CPC Class Codes: B32B 17/10761 containing vinyl acetal
• CPC Class Codes: B32B 17/10834 using a fluid
• CPC Class Codes: B32B 17/10853 the membrane being bag-shaped
• CPC Class Codes: B32B 17/10981 Pre-treatment of the layers
• CPC Class Codes: B32B 2367/00 Polyesters, e.g. PET, i.e. polyethylene terephthalate
• CPC Class Codes: B32B 29/06 specially treated, e.g. surfaced, parchmentised
• CPC Class Codes: B32B 37/02 characterised by a sequence of laminating steps, e.g. by adding new layers at consecutive laminating stations
• CPC Class Codes: B32B 37/1018 using only vacuum
• CPC Class Codes: C09K 2323/057 Ester polymer, e.g. polycarbonate, polyacrylate or polyester
• CPC Class Codes: Y10S 428/917 Electroluminescent
• CPC Class Codes: Y10T 428/162 Transparent or translucent layer or section
• CPC Class Codes: Y10T 428/164 Continuous two dimensionally sectional layer
• CPC Class Codes: Y10T 428/187 Continuous sectional layer
• CPC Class Codes: Y10T 428/197 with noncoplanar reinforcement
• CPC Class Codes: Y10T 428/239 Complete cover or casing
• CPC Class Codes: Y10T 428/24174 including sheet or component perpendicular to plane of web or sheet
• CPC Class Codes: Y10T 428/24752 Laterally noncoextensive components
• CPC Class Codes: Y10T 428/24868 Translucent outer layer
• CPC Class Codes: Y10T 428/2495 : Thickness [relative or absolute]
• CPC Class Codes: Y10T 428/31507 : Of polycarbonate
• CPC Class Codes: Y10T 428/3163 : Next to acetal of polymerized unsaturated alcohol [e.g., formal butyral, etc.]
• CPC Class Codes: Y10T 428/31797 : Next to addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31928 : Ester, halide or nitrile of addition polymer

Abstract

A method is disclosed for producing superior optically clear laminates having a sheet of semi-rigid material encapsulated in a thermoplastic interlayer between layers of rigid material such as glass. Pre-cooled laminate elements are assembled at reduced temperature, allowing positioning of the sheet of semi-rigid material in the interlayer of the assembly with minimal wrinkling, formation of air bubbles or entrapment of moisture. Thereafter, the laminate assembly is maintained under vacuum for an extended period of time, substantially eliminating wrinkling, air bubbles and moisture from between the laminate elements as well as pre-forming the semi-rigid sheet. Bonding heat and pressure is then applied, first heating the assembly to "tack" the laminate elements together, and next applying heat and pressure for bonding the laminate elements. Superior optically clear laminates which result from the method are disclosed wherein a semi-rigid sheet of material is encapsulated in thermoplastic laminating material within an interlayer between sheets of rigid material such as glass.

Claims

1. A safety laminate having encapsulated semi-rigid material, said laminate comprising:

first and second layers of thermoplastic laminating material;

an interlayer including at least one sheet of semi-rigid material, said semi-rigid material capable of bending and flexing and tending to crease and fold thereby, said semi-rigid material encapsulated within said first and second layers of said thermoplastic laminating material substantially without creasing and folding; and

first and second rigid transparent layers bonded to said first and second layers of laminating material, respectively, whereby one surface of each of said rigid transparent layers is an outer surface of said laminate.

2. A laminate as recited in claim 1 wherein at least one of said first and second rigid transparent layers is glass.

3. A safety laminate as recited in claim 1 wherein at least one of said first and second rigid transparent layers is polycarbonate.

4. A laminate as recited in claim 1 wherein said thermoplastic laminating material is polyvinyl acetate.

5. A laminate as recited in claim 1 wherein said thermoplastic laminating material is polyvinyl butyral.

6. A laminate as recited in claim 1 wherein said semi-rigid material is polyester.

7. A laminate as recited in claim 1 wherein said semi-rigid material includes electroluminescent material.

8. A laminate as recited in claim 1 wherein said semi-rigid material includes liquid crystal material.

9. A laminate as recited in claim 1 wherein said semi-rigid material is bonded to said layers of thermoplastic laminating material.

10. A laminate as recited in claim 1 wherein said rigid transparent layers and said layers of thermoplastic laminating material are of substantially the same size.

11. A laminate as recited in claim 1 comprising:

a plurality of layers of thermoplastic laminating material; and

a plurality of interlayers including at least one sheet of semi-rigid material encapsulated within one or more of said plurality of layers of said thermoplastic laminating material.

12. A laminate as recited in claim 11 wherein at least one of said rigid transparent layers, said layers of thermoplastic laminating material and said interlayers is translucent.

13. A laminated as recited in claim 11 wherein at least one of said rigid transparent layers, said layers of thermoplastic laminating material and said interlayers is opaque.

14. A laminate as recited in claim 1 wherein at least one of said first or second layers of said thermoplastic laminating material is thicker than said semi-rigid material.

15. A laminate as recited in claim 1 wherein the shape of said laminate defines an outer perimeter and said laminate further comprises a coating on at least one of said layers of thermoplastic laminating material, said rigid transparent layers and said interlayer near the perimeter of said laminate.

16. A laminate as recited in claim 1 further comprising at least one electrical connection adhering to the surface of at least one of said layers near the perimeter of said laminate.

17. A laminate as recited in claim 1 wherein at least one of said rigid transparent layers, said layers of thermoplastic laminating material and said interlayer is translucent.

18. A laminate as recited in claim 1 wherein at least one of said rigid transparent layers, said layers of thermoplastic laminating material and said interlayer is opaque.

19. A safety laminate having encapsulated semi-rigid material, said laminate comprising:

a first rigid transparent layer;

a second rigid transparent layer;

an interlayer between said first and second rigid transparent layers including

a sheet of extruded plastic having a layer of semi-rigid material sandwiched between at least two layers of thermoplastic laminating material, said sheet of extruded plastic having a length and width less than said first and second rigid transparent layers, said semi-rigid material capable of bending and flexing and tending to crease and fold thereby, and said semi-rigid material sandwiched between said at least two layers of thermoplastic laminating material substantially without creasing and folding, and

one or more spacers of said thermoplastic laminating material surrounding the periphery of said sheet of extruded plastic between said first and second rigid transparent layers; and

wherein one surface of each said first and second rigid transparent layers is bonded to said interlayer, and one surface of each of said first and second rigid transparent layers is an outer surface of said laminate.

20. A laminate as recited in claim 19 wherein at least one of said first and second transparent layers is glass.

21. A laminate as recited in claim 19 wherein said thermoplastic laminating material is polyvinyl acetal.

22. A laminate as recited in claim 19 wherein said semi-rigid material is polyester.

23. A laminate as recited in claim 19 wherein said one or more spacers of thermoplastic laminating material in said interlayer is at least as thick as said sheet of extruded plastic.

24. A safety laminate having encapsulated semi-rigid material, said laminate comprising:

a first rigid transparent layer;

a second rigid transparent layer; and

one or more interlayers positioned between said first and second rigid transparent layers, each of said interlayers including;

layers of thermoplastic laminating material alternating with layers which are comprised of a sheet of semi-rigid material surrounded on its periphery by one or more spacers of thermoplastic laminating material, said semi-rigid material capable of bending and flexing and tending to crease and fold thereby;

said first and second rigid transparent layers bonded to adjacent layers of said thermoplastic laminating material respectively, and

said semi-rigid material positioned to be encapsulated in said laminating material substantially without creasing and folding.