Method of forming a coextruded foam composite

• US 5,215,691 A
• Filed: 09/05/1990
• Issued: 06/01/1993
• Est. Priority Date: 09/05/1990
• Status: Expired due to Term

• Current Assignee: The Dow Chemical Company (Dow, Inc.)
• Original Assignee: The Dow Chemical Company (Dow, Inc.)
• Inventors: Moeller, Susan K., Bland, David G., Conte, Joseph J.
• Primary Examiner(s): Kuhns, Allan R.
• Application Number:
  US07/577,723
• Time in Patent Office: 1,000 Days
• Field of Search: 264/45.9, 264/46.1, 264/50, 264/51, 264/53, 264/54, 264/DIG. 14
• US Class Current: 264/45.9
• CPC Class Codes: B29C 2948/92704 Temperature
• CPC Class Codes: B29C 2948/92904 Die; Nozzle zone
• CPC Class Codes: B29C 2948/92961 Auxiliary unit, e.g. for external melt filtering, re-combining or transfer between units
• CPC Class Codes: B29C 44/22 consisting of at least two parts of chemically or physically different materials, e.g. having different densities
• CPC Class Codes: B29C 44/505 extruding the compound through a flat die in general B29C48/03
• CPC Class Codes: B29C 48/07 Flat, e.g. panels
• CPC Class Codes: B29C 48/08 flexible, e.g. films
• CPC Class Codes: B29C 48/21 the layers being joined at their surfaces
• CPC Class Codes: B29C 48/307 specially adapted for bringing together components, e.g. melts within the die
• CPC Class Codes: B29C 48/495 Feed-blocks extrusion moulding of multi-component articles B29C48/16
• CPC Class Codes: B29C 48/92 Measuring, controlling or regulating
• CPC Class Codes: B29K 2105/04 cellular or porous

Abstract

A method for preparing composite foam articles by the coextrusion of at least two interdigitated layers in abutting relationship to each other, wherein at least one layer of composite article comprises at least one expanded thermoplastic resinous material. At least one physical expansion agent is incorporated into at least one of the layers under a pressure sufficient to keep the expansion agent quiescent and the individual melt streams are combined and interdigitated into a composite layered stream. The composite layered stream is expressed while the operating pressures and temperatures of individual melt streams are controlled to provide a coextrusion product having a stable foam structure.

Claims

1. A method for preparing a foam structure comprising at least two individual layers, at least one of said layers comprising an expanded cellular thermoplastic material, said layers being fused to, interdigitated with and in generally parallel relationship to each other, said method comprising:

providing at least two separate melt streams, each of said melt streams comprising thermoplastic resinous material, each of said thermoplastic resinous material melt streams containing no expansion agent;

incorporating, subsequent to the formation of said melt streams, into at least one of said separate melt streams at least one expansion agent, under a pressure which is sufficient to inhibit expansion of said melt stream;

combining said separate melt streams to form a composite stream of interdigitated layers;

expressing said composite stream and causing said melt stream having expansion agent incorporated therein to expand;

controlling the process pressure and controlling process temperature of each individual melt stream during the expressing of said composite stream, (1) to prevent foam expansion prior to the expression of the composite stream, (2) to obtain a stable foam structure, and (3) to control the temperature of the interface of any two adjacent layers, at least one of said adjacent layers comprising a foam layer, so that it will neither be so hot immediately adjacent said interface as to collapse the foam cells immediately adjacent said interface, not so cold as to inhibit expansion of said at least one foam layer;

said process temperature for said melt stream containing said expansion agent being in the range from 1.1 to 2.75 times, on the centigrade scale, the melt temperature of said melt stream containing said expansion agent, and said process temperature for said other of said melt streams being in the range from 0.75 to 2 times, on the centigrade scale, said processing temperature of said melt stream containing said expansion agent; and

recovering an expanded cellular thermoplastic body comprising at least two interdigitated layers fused to and in generally parallel relationship to each other.

2. A method in accordance with claim 1 wherein said separate melts comprise dissimilar thermoplastic resinous materials.

3. A method in accordance with claim 1 wherein said separate melts comprise the same thermoplastic resinous material.

4. A method in accordance with claim 1 wherein each of said separate melt streams is divided into a plurality of substreams and said substreams are combined and interdigitated to form a composite stream.

5. A method in accordance with claim 1 wherein at least one expansion agent is incorporated into each of said separate melt streams.

6. A method in accordance with claim 1 wherein said thermoplastic resinous material has a glass transition temperature which is less than the process temperature of its respective melt stream.

7. A process according to claim 1 wherein at least one of said separate melt streams has incorporated therein at least one plasticizer for the thermoplastic resinous material.

8. A process according to claim 1 wherein the process pressure under which said expansion agent is incorporated into said at least one melt stream is at least 500 psig.

9. A process according to claim 8 wherein said process pressure is at least 500 psig.

10. A process according to claim 1 wherein the foaming temperature of said melt stream having incorporated therein at least one foaming agent is greater than the melt temperature of the other of said at least two separate melt streams.

11. A process according to claim 5 wherein the foaming temperature of each of said melt streams having blowing agent incorporated therein is greater than the melt temperature of its respective stream.

12. A method according to claim 1 wherein said expansion agent which is incorporated into at least one of said separate melt streams comprises a physical expansion agent.

13. A method according to claim 1 wherein said expansion agent which is incorporated into at least one of said separate melt streams comprises a chemical expansion agent.

14. A method according to claim 1 wherein at least one of said at least two separate melt streams has incorporated therein from 0.1 to 2.5 weight percent of carbon black.

15. A method for preparing a foam structure comprising at least two individual layers, at least one of said layers comprising an expanded cellular thermoplastic material, said layers being fused to, interdigitated with and in generally parallel relationship to each other, said method comprising:

providing at least two separate melt streams, each of said melt streams comprising thermoplastic resinous material, each of said thermoplastic resinous material melt streams containing no expansion agent;

incorporating, subsequent to the formation of said melt streams, into at least one of said separate melt streams from 1 to 100 parts by weight of at least one expansion agent per 100 parts of thermoplastic resinous material, under a pressure which is sufficient to inhibit expansion of said melt stream;

incorporating into at least one other of said separate melt streams from 0.1 to 1 part by weight of at least one expansion agent per 100 parts of thermoplastic resinous material, under a pressure which is sufficient to inhibit expansion of said melt stream;

combining said separate melt streams to form a composite stream of interdigitated layers;

expressing said composite stream and causing said melt stream having said 1 to 100 parts by weight of expansion agent incorporated therein to expand;

controlling the process pressure and controlling process temperature of each individual melt stream during the expressing of said composite stream (1) to prevent foam expansion prior to the expression of the composite stream, (2) to obtain a stable foam structure, and (3) to control the temperature at the interface of any two adjacent layers, at least one of said adjacent layers comprising a foam layer, so that it will neither be so hot immediately adjacent said interface as to collapse the foam cells immediately adjacent said interface nor so cold as to inhibit expansion of said at least one foam layer;

said process temperature for said melt stream containing said expansion agent being in the range from 1.1 to 2.75 times, on the centigrade scale, the melt temperature of said melt stream containing said expansion agent, and said process temperature for said other of said melt streams being in the range from 0.75 to 2 times, on the centigrade scale, said processing temperature of said melt stream containing said expansion agent; and

recovering an expanded cellular thermoplastic body comprising at least two interdigitated layers fused to and in generally parallel relationship to each other.

16. A method according to claim 15 wherein said other of said separate melt streams has incorporated therein from 0.1 to 25 weight percent of carbon black.

17. A method according to claim 15 wherein at least one of said expansion agents comprises a physical expansion agent.

18. A method according to claim 15 wherein at least one of said expansion agents comprises a chemical expansion agent.