Coating composition containing a hydrolyzable silyl group containing vinylic polymer

• US 5,223,495 A
• Filed: 11/09/1990
• Issued: 06/29/1993
• Est. Priority Date: 11/10/1989
• Status: Expired due to Fees

• Current Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
• Original Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
• Inventors: Kato, Yasushi, Furukawa, Hisao, Inoue, Masaharu, Isayama, Katsuhiko
• Primary Examiner(s): Schofer, Joseph L.
• Assistant Examiner(s): SMITH, JEFFREY
• Application Number:
  US07/610,897
• Time in Patent Office: 963 Days
• Field of Search: 524/188, 524/261, 524/262, 524/263, 525/100, 525/102
• US Class Current: 524/188
• CPC Class Codes: C08L 2205/02 containing two or more polymers of the same C08L -group
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 43/04 Homopolymers or copolymers of monomers containing silicon
• CPC Class Codes: C08L 83/04 Polysiloxanes
• CPC Class Codes: C09D 143/04 Homopolymers or copolymers of monomers containing silicon
• CPC Class Codes: C09D 183/04 Polysiloxanes

Abstract

A curable coating composition comprising

(A) from 10 to 99 parts by weight of a silyl group-containing vinylic polymer having a number average molecular weight of at least 3,000, the main chain thereof being substantially composed of a vinylic polymer chain and having at least one silicon atom bonded to a hydrolyzable group at a terminal of the main chain and/or at a side chain in each molecule,

(B) from 1 to 90 parts by weight of an organic compound having a number average molecular weight of not larger than 3,000 and having at least one silicon atom bonded to a hydrolyzable group at a terminal in each molecule, and

(C) from 1 to 500 parts by weight of silanol-containing organopolysiloxane having, on an average, at least one sianol group in one molecule to 100 parts by weight of the total amount of the component (A) and the component (B).

Claims

1. A curable coating composition comprising

(A) from 10 to 99 parts by weight of a first component which is a silyl group-containing vinylic polymer having a number average molecular weight of at least 3,000, wherein at least about 60% of the units constituting the main chain of the silyl group-containing vinylic polymer are vinylic units, said polymer having at least one hydrolyzable silyl group at a terminal of the main chain or at a side chain in each molecule,

(B) from 1 to 90 parts by weight of a second component which is different from said first component, said second component being an organic compound having a number average molecular weight of not larger than 3,000 and having at least two hydrolyzable silyl groups at terminals in each molecule, and

(C) from 1 to 500 parts by weight of a silanol-containing organopolysiloxane having an average of at least one silanol group per molecule to 100 parts by weight of the total amount of the component (A) and the component (B).

2. The coating composition of claim 1, wherein the hydrolyzable silyl-containing vinylic polymer (A) is a copolymer of a macromonomer (D) and a vinylic monomer (E), said macromonomer having a carbon-carbon double bond and a hydrolyzable silyl group in each molecule and having a number average molecular weight of from 400 to 5,000.

3. The coating composition of claim 1, wherein the silanol-containing organopolysiloxane (C) has an average of from 2 to 6 silanol groups in each molecule and has a number average molecular weight of from 200 to 3,000.

4. The coating composition of claim 1, wherein the silanol-containing organopolysiloxane (C) is a phenyl-substituted cyclic organopolysiloxane.

5. The coating composition of claim 1, wherein the composition further contains a hydrolyzable ester compound (F) as a dehydrating agent and an alkyl alcohol (G) as a solvent.

6. The coating composition of claim 1, wherein the composition further contains a curing catalyst (H).

7. The coating composition of claim 1, wherein the composition further contains at least one number selected from the group consisting of an ultraviolet absorbent (I) and a light stabilizer (J).

8. The coating composition of claim 2, wherein the macromonomer (D) contains ##STR20## in the molecule.

9. The coating composition of claim 2, wherein the macromonomer (D) contains a urethane bond in the molecule.

10. The coating composition of claim 2, wherein the hydrolyzable silyl group-containing organic compound (B) has a number average molecular weight from 300 to 2,000.